IP Library Granted Patent US 8,642,675
Granted Patent B2
US 8,642,675 · App. 11/790,046 · Granted Feb 4, 2014

Actinic ray curable composition, actinic ray curable ink-jet ink, image forming method and ink-jet recording apparatus utilizing said actinic ray curable ink-jet ink

Inventor: Nobumasa Sasa (Sayama, JP)
Assignee: Konica Minolta Medical & Graphic, Inc.
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Quick Facts
Patent No.
US 8,642,675
App. No.
11/790,046
Granted
Feb 4, 2014
Kind
B2
Abstract

An actinic ray curable composition comprising a photo-polymerizable compound and a photo-polymerization initiator, wherein the photo-polymerizable compound is a cationic polymerizable compound and a terminal polyether-modified silicone surfactant is further incorporated in the actinic ray curable composition.

Claims (18)

1. An image forming method comprising the steps of:

1) ejecting an actinic ray curable ink-jet ink from a metal nozzle installed in an ink-jet recording head onto a recording medium, the actinic ray curable ink-jet ink comprising an actinic ray curable composition comprising a photo-polymerizable compound, a photo-polymerization initiator, and a silicone surfactant, wherein the terminal positions of the silicone surfactant are modified with a polyether and the photo-polymerizable compound is a cationic polymerizable compound, and

2) irradiating actinic rays to the ejected actinic ray curable ink-jet ink on the recording medium,

wherein the actinic ray curable ink-jet ink comprises at least one kind of pigment, and

wherein a maximum particle size of the at least one kind of pigment ranges from 0.3 μm to 10 μm.

2. The image forming method of claim 1 , wherein an HLB value of the silicone surfactant is 9-30, and an amount of the terminal polyether-modified silicone surfactant is 0.001-10 weight % based on a total weight of the actinic ray curable composition.

3. The image forming method of claim 1 , further comprising transferring the recording medium on or above a platen portion, the platen portion having a function to absorb ultraviolet rays.

4. The image forming method of claim 1 , wherein an HLB value of silicone surfactant is 9-30.

5. The image forming method of claim 4 , wherein the HLB value of the silicone surfactant is 12-25.

6. The image forming method of claim 1 , wherein the cationic polymerizable compound comprises a compound having an oxetane ring or an epoxy compound.

7. The image forming method of claim 1 , wherein an amount of the silicone surfactant is 0.001-10 weight % based on a total weight of the actinic ray curable composition.

8. The image forming method of claim 1 , wherein a maximum particle size of the pigment is 0.3-3 μm.

9. The image forming method of claim 1 , wherein the actinic ray curable ink-jet ink further comprises a pigment dispersant having a basic anchor portion.

10. The image forming method of claim 1 , wherein the actinic ray curable ink-jet ink further comprises a basic compound of 10-1,000 weight ppm of the total photo-polymerizable compound.

11. The image forming method of claim 1 , wherein irradiating actinic rays to the ejected actinic ray curable ink-jet ink is carried out during 0.001-1.0 second after landing of the actinic ray curable ink-jet ink on the recording medium.

12. The image forming method of claim 1 , wherein a minimum amount of ink droplets, which is ejected from a nozzle of the ink-jet recording head, is 2-15 pl.

13. The image forming method of claim 1 , wherein actinic ray curable ink-jet ink is ejected from the recording head after the actinic ray curable ink and the recording head are heated to 35-100° C.

14. The image forming method of claim 1 , wherein the actinic ray curable ink is ejected onto a recording medium which is heated to 35-60° C.

Assignments (3)
MERGER Recorded Feb 13, 2014
From: KONICA MINOLTA MEDICAL & GRAPHIC, INC.
To: KONICA MINOLTA HOLDINGS, INC.
Reel/Frame 032211/0818 →
CHANGE OF NAME Recorded Feb 13, 2014
From: KONICA MINOLTA HOLDINGS, INC.
To: KONICA MINOLTA, INC.
Reel/Frame 032211/0946 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 23, 2007
From: SASA, NOBUMASA
To: KONICA MINOLTA MEDICAL & GRAPHIC, INC
Reel/Frame 019291/0539 →
Priority Claims (1)
JP 2006-123269 · Apr 27, 2006 · national
Continuity (1)
Related Publication 20070254977A1 · Nov 1, 2007