Device for dispensing bark beetle pheromone in a controlled manner
The present invention relates to a device in the form of a container made of a polymer material, which container has one or more sealed chambers, each of which comprise a liquid pheromone comprising 2-ethyl-1,6-dioxaspiro[4,4]nonane, methyl 2,4-decadiene-carboxylate and at least one alcohol selected among 2-methylbut-3-en-2-ol and 2-methylbut-3-yn-2-ol, where at least 50% of the area of the walls forming the chambers have a wall thickness in the range of from 0.1 to 1 mm and the polymer material which forms the chamber is at least in those areas an uncoated vinyl acetate/ethylene copolymer with a vinyl acetate content in the range of from 10 to 17% by weight. The invention also relates to a method of combating and for monitoring the swarming behavior of the species Pityogenes chalcographus , generally also referred to as spruce wood engraver or six-dentated bark beetle.
1. A device in the form of a container made of a permeable plastic material which is exclusively an uncolored vinyl acetate/ethylene copolymer, which container comprises at least two sealed chambers, each of which comprises a liquid pheromone comprising 2-ethyl-1,6-dioxaspiro[4,4]nonane, methyl 2,4-decadienecarboxylate and at least one alcohol selected from the group consisting of 2-methylbut-3-en-2-ol and 2-methylbut-3-yn-2-ol, the liquid pheromone being completely enclosed within the interior of each chamber, where at least 70% of the area of the walls forming the chambers have a wall thickness in the range of from 0.1 to 1 mm and the plastic material which forms the chambers is an uncoated, uncolored vinyl acetate/ethylene copolymer with a vinyl acetate content in the range of from 10 to 17% by weight, where the ratio of the area of the walls forming the chambers to the internal volume of the chamber is in the range of from 1 to 10 cm −1 .
2. The device of claim 1 , wherein the vinyl acetate/ethylene copolymer has a melt flow index in the range of from 1.8 to 3.2 g/10 min, as determined by the American Society for Testing and Materials' Standard Test Method for Melt Flow Rates of Thermoplastics by Extrusion Plastometer at 190° C. and 2.16 kg.
3. The device of claim 1 , wherein the ratio of the area of the walls forming the chambers to the internal volume of the chamber is in the range of from 1 to 10 cm −1 .
4. The device of claim 1 , wherein the chamber(s) has/have a tubular geometry with an internal diameter in the range of from 5 to 20 mm and a length in the range of from 20 to 40 mm.
5. The device of claim 1 with two separate chambers.
6. The device of claim 1 , wherein the pheromone comprises
2 to 10% by weight of 2-ethyl-1,6-dioxaspiro[4,4]nonane;
0.5 to 5% by weight of methyl 2,4-decadienecarboxylate and
90 to 97.5% by weight of 2-methylbut-3-yn-2-ol and/or 2-methylbut-3-en-2-ol based on total weight of said pheromone.
7. The device of claim 1 , comprising the pheromone in an amount of from 1 to 5 ml per chamber.
8. A method for combating the six-dentated bark beetle ( Pityogenes chalcographus ), which comprises providing one or more devices of claim 1 in conjunction with one or more trapping devices wherein said beetle is combated.
9. A method of monitoring the swarming of the six-dentated bark beetle comprising,
providing one or more devices of claim 1 in conjunction with one or more trapping devices and
checking said trapping device(s) for said beetle.
10. The method of claim 8 , wherein said trapping devices are selected from the group consisting of trap wood piles, trap poles, trap brushwood piles and trap trees.
11. The method of claim 9 , wherein said trapping devices are selected from the group consisting of trap wood piles, trap poles, trap brushwood piles and trap trees.