Concentrated inverse latex, process for preparing it and industrial use thereof
View Patent ↗The invention relates to a composition in the form of a positive latex comprising a) between 50 wt. % and 80 wt. % of at least one cross-linked, branched, or linear organic polymer (P), b) between 5 wt. % and 10 wt. % of a water-in-oil (W/O) emulsifying system (S 1 ), c) between 5 wt. % and 45 wt. % of at least one oil, and d) between 0 wt. % and 5 wt. % of water. The inventive composition is characterized in that between 0.01 mol. % and 10 mol. % of the monomeric patterns of said monomer P comprise at least one neutral monomer of formula (I): C(R 1 )(R 3 )═C(R 2 )—C(=0)-0-(CH 2 —CH 2 —O) n —R 4 (I) wherein the radicals R 1 , R 2 and R 3 , which are the same or different, independently represent a hydrogen atom or a linear or branched alkyl radical comprising between 1 and 4 carbon atoms, the radical R 4 represents a linear or branched, saturated or unsaturated, aliphatic radical comprising between 6 and 30 carbon atoms, and n represents a number between 1 and 50. The invention also relates to a method for the production of said composition and the use of the same.
1. A composition in the form of an inverse latex comprising:
a) from 50% by weight to 80% of at least one linear, branched or crosslinked organic polymer (P),
b) from 5% by weight to 10% of an emulsifying system (S 1 ) which is a water-in-oil (W/O) emulsion,
c) from 5% by weight to 45% by weight of at least one oil, and
d) from 0% to 5% of water,
wherein from 0.01% to 10% in molar proportions of monomer units of said polymer P include at least one neutral monomer of formula (I′):
CH 2 ═CH—C(=0)-0-(CH 2 —CH 2 —O) n′ —R′ 4 (I′)
radical R′ 4 is an aliphatic radical selected from the group consisting of octyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl, docosyl and tetracosyl radicals, and
n′ is a number between 4 and 25; or
said polymer (P) is a copolymer in which each of the monomers, which are different from formula (I′), is independently of each other selected from the group consisting of a monomer containing a partially or totally salified strong acid function, a monomer containing a partially or totally salified weak acid function and from neutral a monomer.
2. The composition as defined in claim 1 , in which from 0.05 mol % to 5 mol % of the monomer units that said polymer P comprises include at least one neutral monomer of formula (I′).
3. The composition as defined in claim 1 , wherein the polymer (P) is crosslinked with a diethylenic or polyethylenic compound in a molar proportion, expressed relative to the monomers used, of less than or equal to 0.25%.
4. The composition as defined in claim 3 , wherein the crosslinking agent is selected from the group consisting of ethylene glycol dimethacrylate, diethylene glycol diacrylate, sodium diallyloxyacetate, ethylene glycol diacrylate, diallyl urea, triallylamine, trimethylolpropane triacrylate and methylenebis(acrylamide), or a mixture of these compounds.
5. The composition as defined in claim 1 , wherein the monomer containing a strong acid function, which the polymer (P) comprises, is partially or totally salified 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid.
6. The composition as defined in claim 1 , wherein the monomer containing a weak acid function, which the polymer (P) comprises, is selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acid and partially or totally salified 3-methyl-3-[(1-oxo-2-propenyl)amino]butanoic acid.
7. The composition as defined in claim 1 , wherein the neutral monomer other than the compound of formula (I′), which the polymer (P) comprises, is selected from the group consisting of acrylamide, methacrylamide, diacetoneacrylamide, dimethylacrylamide, N-isopropylacrylamide, N-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]propenamide, (2-hydroxyethyl) acrylate, (2,3-dihydroxypropyl) acrylate, (2-hydroxyethyl) methacrylate, (2,3-dihydroxypropyl) meth-acrylate, and an ethoxylated derivative with a molecular weight of between 400 and 1000, of each of these esters, or vinylpyrrolidone.
8. The composition as defined in claim 1 , in which the polymer (P) is selected from the group consisting of:
crosslinked copolymers of acrylic acid partially salified in the form of the sodium salt or of the ammonium salt, of acrylamide and of tetraethoxylated lauryl acrylate;
crosslinked copolymers of 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid partially salified in the form of the sodium salt, of acrylamide and of tetraethoxylated lauryl acryate;
crosslinked copolymers of 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid and of acrylic acid, which are partially salified in the form of the sodium salt, and of tetraethoxylated lauryl acrylate;
crosslinked copolymers of 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid partially salified in the form of the sodium salt, of 2-hydroxyethyl acrylate and of tetraethoxylated lauryl acrylate;
crosslinked copolymers of 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid partially salified in the form of the sodium salt, and of tetraethoxylated lauryl acrylate;
crosslinked copolymers of acrylic acid partially salified in the form of the ammonium salt or of the monoethanolamine salt, and of tetraethoxylated lauryl acrylate;
crosslinked copolymers of acrylamide, of 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid and of acrylic acid, which are partially salified in the form of the sodium salt, and of tetraethoxylated lauryl acrylate; and
copolymers of 2-methyl-2-[(1-oxo-2-propenyl)-amino]-1-propanesulfonic acid partially salified in the form of the sodium salt, of acrylamide, of vinylpyrrolidone and of tetraethoxylated lauryl acrylate.
9. The composition as defined in claim 1 , comprising from 60% by weight to 70% by weight of polymer (P).
10. The composition as defined in claim 1 , further comprising up to 5% of its weight of an emulsifying system (S 2 ) which is a water-in-oil (W/O) emulsion.