Polyurea compound

1. A polyurea compound sag control agent obtainable by reacting one or more polyisocyanates with one or more non-chiral mono-amines (I) and one or more chiral mono-amines (II) and co-precipitating the reaction products to form the polyurea compound, wherein 2-98 mole % of the mono-amines in the polyurea compound are chiral mono-amines (II) provided in an enantiomeric excess of at least 20%.

2. The polyurea compound according to claim 1 obtainable by reacting one or more polyisocyanates with a mixture of non-chiral mono-amines of the formula (I) and chiral mono-amines of the formula (II),

wherein the mixture comprises 2-98 mole % of chiral mono-amine II, wherein R 1 is selected from the group consisting of linear or branched, saturated or unsaturated hydrocarbyl and, each of R 2 to R 3 are independently selected from the group consisting of linear or branched, saturated or unsaturated hydrocarbyl or a heteroatom containing group, whereby R 2 and R 3 of each chiral mono-amine II is different such that the carbon atom in monoamine II is a chiral center.

3. The polyurea compound according to claim 1 , wherein the polyisocyanates are selected from the group consisting of substituted or unsubstituted linear aliphatic polyisocyanates and substituted or unsubstituted arylene, aralkylene, and cyclohexylene polyisocyanates.

4. The polyurea compound to according to claim 2 , wherein R 1 of mono-amine I is isomorphous with R 3 of monoamine II and R 2 is an alkyl, aryl or heteroatom containing group.

5. The polyurea compound to according to claim 2 , wherein R 2 is a methyl group.

6. The polyurea compound according to claim 2 , wherein R 1 of mono-amine I and R 3 of mono-amine II comprise the same number of atoms plus or minus two atoms or plus or minus 25%.

7. The polyurea compound according to claim 2 , wherein R 1 of mono-amine I and R 3 of mono-amine II both comprise an aryl group, an alkyl or hetero alkyl group having the same number of atoms plus or minus two atoms or plus or minus 25%.

8. The polyurea compound according to claim 2 , wherein R 1 of mono-amine I and R 3 of chiral mono-amine II comprise the same basic aryl, alkyl or heteroatom containing group optionally with different substituents.

9. The polyurea compound according to claim 2 , wherein R 1 of mono-amine I and R 3 of chiral mono-amine II are identical.

10. The polyurea compound according to claim 1 , wherein chiral mono-amine II is alpha-methylbenzylamine (AMBA).

11. The polyurea compound according to claim 1 , wherein chiral mono-amine II is an aminoacid, optionally esterified.

12. The polyurea compound according to claim 1 , wherein mono-amine I is benzyl amine (BA) and chiral mono-amine II is alpha-methylbenzylamine (AMBA).

13. The polyurea compound according to claim 1 , wherein R 1 in mono-amine I and/or R 3 in chiral mono-amine II is a pyridyl group.

14. The polyurea compound according to claim 1 , wherein mono-amine I is 3-(aminomethyl)pyridine (AMP) and chiral mono-amine II is alpha-methylbenzylamine (AMBA).

15. The polyurea compound according to claim 2 , wherein the mixture comprises between 10 and 55 mole % of chiral mono-amine II.

16. A blended polyurea compound comprising a physical blend of two or more different polyurea compounds having different melting temperatures, wherein at least one of the polyurea compounds is a polyurea compound according to claim 1 .

17. The blended polyurea compound according to claim 16 , comprising two polyurea compounds with different melting temperatures.

18. The blended polyurea compound according to claim 17 , wherein the two polyurea compounds differ in having a different chiral amine content.

19. A composition rheologically modified by the compound of claim 1 or blend of claim 16 .

20. An adhesive, printing ink, detergent, paper, paperboard, textile construction material, engineered plastic, pigment, mining fluid or cosmetic comprising the polyurea compound of claim 1 or blend of claim 16 as a rehology modification agent.

21. A coating composition comprising the polyurea compound according to claim 1 or the blend of claim 16 as a sag control agent.

22. Sag control agent composition comprising a polyurea compound according to claim 1 dispersed in a binder material.

23. Sag control agent composition according to claim 22 for use as a master batch in the preparation of a coating composition, wherein the composition comprises a binder, a solvent and 0.5 to 7 wt % (relative to the total weight of the composition) of the polyurea compound.

24. A coating composition comprising a binder and, as a sag control agent, a polyurea compound according to claim 1 or a sag control agent composition according to claim 22 .

25. The coating composition according to claim 24 comprising between 0.05 and 10 wt percent of the polyurea compound (based on the total weight of the coating composition).

26. A coating prepared from a coating composition according to claim 24 .

27. A process for the preparation of a polyurea compound according to claim 1 , wherein one or more polyisocyanates are reacted with a mixture of one or more non-chiral monoamines and one or more chiral mono-amines followed by precipitating the reaction products forming a solid co-precipitate polyurea compound.

28. A process for the preparation of a polyurea compound according to claim 1 , wherein one or more polyamines are reacted with a mixture of one or more non-chiral monoisocyanates and one or more chiral mono-isocyanates followed by precipitating the reaction products forming a solid coprecipitate polyurea compound.

29. A process for the preparation of a polyurea compound according to claim 1 , wherein one or more polyisocyanates are reacted with one or more non-chiral mono-amines in step A and wherein, in a separate step B, one or more polyisocyanates are reacted with one or more chiral mono-amines followed by combining the reaction products of step A and step B and precipitating the combined reaction products to form the solid coprecipitate polyurea compound.

30. The process according to claim 27 or 28 , wherein the reaction step and the precipitation step are done in separate stages, wherein in a first stage, after the reaction step, a separate intermediate polyurea product is produced and wherein the intermediate polyurea product, in a later stage is compounded with other compounds to precipitate the polyurea compound.

31. A polyurea product sag control agent comprising polyurea compounds obtainable by reacting one or more polyisocyanates with one or more non-chiral mono-amines (I) and one or more chiral mono-amines (II) and co-precipitating the reaction products to form the polyurea compound, wherein 10-55 mole % of the mono-amines in the polyurea compound are chiral mono-amines provided in an enantiomeric excess of at least 20%, wherein the polyurea compounds are in a dissolved state for use in an application in which the dissolved polyurea compounds co-crystallize.

32. The polyurea compound to according to claim 2 , wherein R 2 comprises 1-6 carbon atoms.

33. A polyurea compound sag control agent according to claim 1 wherein the non chiral amine (I) is an amine covalently bonded to a carbon atom, which carbon atom has two identical substituents such that it is not chiral and a substituent R 1 selected from the group consisting of linear or branched, saturated or unsaturated hydrocarbyl.

34. The polyurea compound to according to claim 33 , wherein R 2 is a methyl group.

35. The polyurea compound according to claim 33 , wherein R 1 of mono-amine I and R 3 of mono-amine II comprise the same number of atoms plus or minus two atoms or plus or minus 25%.

36. The polyurea compound according to claim 33 , wherein R1 of mono-amine I and R3 of mono-amine II both comprise an aryl group, an alkyl or hetero alkyl group having the same number of atoms plus or minus two atoms or plus or minus 25%.

37. The polyurea compound according to claim 33 , wherein R1 of mono-amine I and R3 of chiral mono-amine II comprise the same aryl, alkyl or heteroatom containing group, optionally with different substituents.

38. The polyurea compound according to claim 33 , wherein R1 of mono-amine I and R3 of chiral mono-amine II are identical.

39. The polyurea compound according to claim 33 , wherein the mixture comprises between 10 and 55 mole % of chiral mono-amine II.