Low viscosity UV curable ink formulations

1 . A low viscosity ink formulation comprising a vinyl ether component, a mono-acrylate component, a photocation polymerization initiator, and a free-radical photoinitiator, wherein the low viscosity ink formulation is free of epoxy functional monomer.

2 . The low viscosity ink formulation of claim 1 in which the vinyl ether component is selected from the group consisting of ethylene glycol divinyl ether, triethylene glycol divinyl ether, trimethylolpropane trivinyl ether, triethylene glycol monobutyl ether, cyclohexanedimethanol divinyl ether, hydroxybutyl vinyl ether, dodecyl vinyl ether, propenyl ether propylene carbonate, methyl vinyl ether, ethyl vinyl ether, propyl vinyl ether, isobutyl vinyl ether, ethylene glycol monovinyl ether, diethylene glycol divinyl ether, butanediol divinyl ether, hexanediol divinyl ether, cyclohexanedimethanol monovinyl ether, cyclohexyl vinyl ether, 2-chloroethyl vinyl ether, 2-hydroxyethyl vinyl ether, diethylene glycol divinyl ether, 2,2-bis(4-vinyloxyethoxyphe-nyl)propane, 1,4-bis(2-vinyloxyethoxy)benzene ethyleneglycol monovinyl ether, ethyl vinyl ether, isobutyl vinyl ether, 1,6-hexanediol divinyl ether, aminopropyl vinyl ether, tert-amyl vinyl ether, butanediol divnyl ether, n-butyl vinyl ether, tert-butyl vinyl ether, cyclohexanedimethanol divinyl ether, cyclohexanedimethanol monovinyl ether, cyclohexyl vinyl ether, diethylaminoethyl vinyl ether, diethyleneglycol divinyl ether, diethyleneglycol monovinyl ether, dodeccyl vinyl ether, ethyleneglycol butyl vinyl ether, ethyleneglycol divinyl ether, ethylhexyl vinyl ether, hexanediol divinyl ether, 4-hydroxybutyl vinyl ether, isopropyl vinyl ether, octadecyl vinyl ether, polyethyleneglycol-520 methyl vinyl ether, polytetrahydrofurandivinyl ether, plurio-E200 divinyl ether, n-propyl vinyl ether, tetraethyleneglycol divinyl ether, triethyleneglycol divinyl ether, triethyleneglycol methyl vinyl ether, and trimethylolpropane trivinyl ether, hydroxylethyl vinyl ether, diethylene glycol divinyl ether, and combinations thereof.

3 . The low viscosity ink formulation of claim 1 wherein the mono-acrylate component is selected from the group consisting of monofunctional acrylate ester, monofunctional acrylate ester, acrylic ester, acrylic ester, acrylic monomer, 2-phenoxy ethyl acrylate, cyclic trimethyolpropane formal acrylate, isodecyl acrylate, lauryl acrylate, tridecyl acrylate, stearyl acrylate, 2(2-ethoxyethoxy) ethyl acrylate, isooctyl acrylate, tetrahydro furfuryl acrylate, methyl acrylate, ethyl acrylate, isopropyl acrylate, n-hexyl acrylate, allyl acrylate, 2-(2′-vinyloxy ethoxy)ethyl acrylate and combinations thereof.

4 . The low viscosity ink formulation of claim 1 wherein the vinyl ether component is selected from the group consisting of 3,6,9,12-tetraoxatetradeca-1,13-diene, 4-hydroxybutyl vinyl ether and combinations mixture thereof.

5 . The low viscosity ink formulation of claim 1 wherein the mono-acrylate component is selected the group consisting of 2-(2′-vinyloxy ethoxy)ethyl acrylate, 2(2-ethoxyethoxy)ethyl acrylate, tetrahydrofurfuryl acrylate and combinations thereof.

6 . The low viscosity ink formulation of claim 1 wherein the mono-acrylate component is isobornyl acrylate.

7 . The low viscosity ink formulation of claim 1 wherein, based upon the weight of the ink formulation, the vinyl ether component is present in an amount of about 1 to about 85 wt %, the mono-acrylate component is present in an amount about 1 to about 40 wt %, the photocation polymerization initiator is present in an amount of about 0.5 to about 15 wt % the free-radical photoinitiator in an amount of about of about 0.5 to about 20 wt %,

8 . The ink formulation of claim 1 having a viscosity between about 2 and about 10 cps at 25° C.

9 . The ink formulation of claim 1 having a viscosity between about 2 and about 7 cps at 25° C.

10 . The ink formulation of claim 1 wherein the formulation is an inkjet ink for drop-on-demand printheads.

11 . The ink formulation of claim 1 wherein the vinyl ether component is a blend of trietheyleneglycol divinylether and 4-hydroxybutylvinylether.

12 . The ink formulation of claim 1 wherein the photocation polymerization initiator is methyl benzoylformate combined with aryl sulfonium hexafluoro phosphate salt.

13 . The ink formulation of claim 1 wherein the photocation polymerization initiator is methyl benzoylformate combined with iodonium, (4-methylphenyl)[4-(2-methylpropyl)phenyl]-, hexafluorophosphate(1-).

14 . The ink formulation of claim 1 wherein the photocation polymerization initiator is methyl benzoylformate combined with mixed aryl sulfonium hexafluoro phosphate salt.

15 . The ink formulation of claim 1 wherein the free-radical photoinitiator is isopropylthioxanthone.

16 . A low viscosity ink formulation comprising a component containing both vinyl ether and acrylate functionality, a photocation polymerization initiator, and a free-radical photoinitiator, wherein the low viscosity ink formulation is free of epoxy functional monomer.