Use of O/W emulsions for chain lubrication

1. A method of lubricating a container conveyor comprising:

applying an oil in water emulsion composition to a portion of the conveyor or a portion of the container, the oil component of the emulsion composition comprising a compound of the following formula:

R 1 CO—OR 2

wherein R 1 CO is a saturated or unsaturated acyl residue with 12 to 18 carbon atoms, and R 2 is a linear or branched alkyl or alkenyl residue with 6 to 22 carbon atoms.

2. The method of claim 1 , wherein R 1 CO is an acyl residue of lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eleostearic acid, and mixtures thereof.

3. The method of claim 1 , wherein R 2 is a linear or branched alkyl or alkenyl residue with 12 to 18 carbon atoms.

4. The method of claim 1 , wherein R 2 is a linear or branched alkyl or alkenyl residue of hexanol, octanol, 2-ethylhexanol, decanol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, eleostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and mixtures thereof.

5. The method of claim 1 , wherein the oil component of the emulsion composition comprises cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, and mixtures thereof.

6. The method of claim 1 , wherein the emulsion composition further comprises a component selected from the group consisting of triglycerides, partial glycerides, fatty alcohol polyglycol ethers, and mixtures thereof.

7. The method of claim 6 , wherein the emulsion composition comprises:

(a) from about 1 to about 50 wt. % a compound of the formula:

R 1 CO—OR 2

wherein R 1 CO is a saturated or unsaturated acyl residue with 12 to 18 carbon atoms, and R 2 is a linear or branched alkyl or alkenyl residue with 6 to 22 carbon atoms;

(b) from about 0.04 to about 10 wt. % triglyceride;

(c) from about 0.04 to about 10 wt. % partial glyceride; and

(d) from about 0.04 to about 20 wt. % fatty alcohol polyglycol ether.

8. The method of claim 7 , wherein the emulsion composition further comprises water.

9. The method of claim 7 , wherein the emulsion composition further comprises additives.

10. The method of claim 1 , wherein the emulsion composition further comprises

(a) at least one alcohol selected from the group consisting of monohydroxy, dihydroxy, and trihydroxy compounds; and

(b) at least one additional component selected from the group consisting of:

(i) a nitrogen-containing, aliphatic organic compound having less than 10 carbon atoms in the molecule;

(ii) a carboxylic acid having from 1 to 10 carbon atoms in the molecule;

(iii) and mixtures thereof.

11. The method of claim 1 , wherein the emulsion composition further comprises an amine selected from the group consisting of primary amines, secondary amines, tertiary amines, salts thereof, and mixtures thereof.

12. The method of claim 1 , wherein the emulsion composition further comprises an antimicrobial.

13. The method of claim 12 , wherein the antimicrobial is selected from the group consisting of alcohols, aldehydes, antimicrobial acids, carboxylic esters, amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen acetals, oxygen formals, nitrogen acetals, nitrogen formals, benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propynylbutylcarbamate, iodine, iodophores, peroxides, peracids, and mixtures thereof.

14. A container conveyor lubricant composition comprising:

(a) a compound of the following formula:

R 1 CO—OR 2

wherein R 1 CO is a saturated or unsaturated acyl residue with 4 to 22 carbon atoms, and R 2 is a linear or branched alkyl or alkenyl residue with 6 to 22 carbon atoms;

(b) at least one alcohol component selected from the group consisting of a monohydroxy alcohol, a dihydroxy alcohol, and a trihydroxy alcohol; and

(c) at least one additional component selected from the group consisting of:

(i) a nitrogen-containing, aliphatic, organic compound with less than 10 carbon atoms in the molecule;

(ii) an organic carboxylic acid having 1 to 10 carbon atoms in the molecule;

(iii) and mixtures thereof.

15. The composition of claim 14 , wherein R 1 CO is an acyl residue of caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eleostearic acid, arachic acid, gadoleic acid, behenic acid, erucic acid and mixtures thereof.

16. The composition of claim 14 , wherein R 1 CO is an acyl residue of a fruit acid.

17. The composition of claim 16 , wherein the fruit acid is selected from the group consisting of malic acid, tartaric acid, citric acid and mixtures thereof.

18. The composition of claim 14 , wherein R 2 is a linear or branched alkyl or alkenyl residue of hexanol, octanol, 2-ethylhexanol, decanol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, eleostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and mixtures thereof.

19. The composition of claim 14 , wherein the compound of the formula R 1 CO—OR 2 comprises cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl erucate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl oleate and mixtures thereof.

20. The composition of claim 14 , further comprising at least one component selected from the group consisting of triglycerides, partial glycerides, and fatty alcohol polyglycol ethers.

21. The composition of claim 20 comprising:

(a) from about 1 to about 50 wt. % a compound of the formula:

R 1 CO—OR 2

wherein R 1 CO is a saturated or unsaturated acyl residue with 4 to 22 carbon atoms, and R 2 is a linear or branched alkyl or alkenyl residue with 6 to 22 carbon atoms;

(b) from about 0.04 to about 10 wt. % triglycerides;

(c) from about 0.04 to about 10 wt. % partial glycerides; and

(d) from about 0.04 to about 20 wt. % fatty alcohol polyglycol ethers.