Device for removing nitrogen oxides from internal combustion engine waste gas and method for dosing an aggregate of internal combustion engine waste gas

1. A device for removing nitrogen oxides from exhaust of an internal combustion engine operated predominantly with excess air, comprising:

an exhaust line,

a metering point, which is assigned to the exhaust line, for metering a reducing agent containing additive into exhaust gas,

a nitrogen oxide reduction catalytic converter, which is arranged in the exhaust line downstream of the metering point, for reduction of nitrogen oxides contained in the exhaust gas with the reducing agent, having a first catalytic converter part and a second catalytic converter part arranged downstream of the first catalytic converter part, the nitrogen oxide reduction catalytic converter being designed to store the reducing agent,

a dosing unit for setting a metering quantity for the additive metered to the exhaust gas via the metering point, and

filling level determining means for determining a reducing agent filling level of reducing agent which is stored in at least one of the first catalytic converter part and the second catalytic converter part,

wherein the metering quantity of the additive is set as a function of the reducing agent filling level, determined by the filling level determining means, of the at least one of the first catalytic converter part and the second catalytic converter part, and

wherein the reducing agent filling level of a respective catalytic converter part is determined by summing and integration with respect to time of at least a conversion rate of reducing agent which is converted in the respective catalytic converter part, a desorption rate of reducing agent which is desorbed by the respective catalytic converter part, and a supply rate of reducing agent which is supplied to the respective catalytic converter part with the exhaust gas.

2. The device as claimed in claim 1 , wherein a characteristic diagram set is provided for the conversion rate and for the desorption rate, and wherein the characteristic diagram set is accessed by the filling level determining means during determination of the reducing agent filling level.

3. A device for removing nitrogen oxides from exhaust of an internal combustion engine operated predominantly with excess air, comprising:

an exhaust line,

a metering point, which is assigned to the exhaust line, for metering a reducing agent containing additive into exhaust gas,

a nitrogen oxide reduction catalytic converter, which is arranged in the exhaust line downstream of the metering point, for reduction of nitrogen oxides contained in the exhaust gas with the reducing agent, having a first catalytic converter part and a second catalytic converter part arranged downstream of the first catalytic converter part, the nitrogen oxide reduction catalytic converter being designed to store the reducing agent,

a dosing unit for setting a metering quantity for the additive metered to the exhaust gas via the metering point, and

filling level determining means for determining a reducing agent filling level of reducing agent which is stored in at least one of the first catalytic converter part and the second catalytic converter part,

wherein the metering quantity of the additive is set as a function of the reducing agent filling level, determined by the filling level determining means, of the at least one of the first catalytic converter part and the second catalytic converter part,

wherein, for the reducing agent filling level of the first catalytic converter part, a first range with a first lower threshold value and a first upper threshold value is predefined,

wherein, for the reducing agent filling level of the second catalytic converter part, a second range with a second lower threshold value and a second upper threshold value is predefined, and

wherein the dosing unit interacts with the filling level determining means in such a way as to permit an adjustment of the reducing agent filling level of at least one of the first catalytic converter part and the second catalytic converter part into the respective range.

4. The device as claimed in claim 3 , wherein, for the nitrogen oxide reduction catalytic converter, an aging factor is determined, and wherein at least one of the first and second ranges for the reducing agent filling level is predefinable as a function of the aging factor.

5. The device as claimed in claim 4 , wherein a first characteristic diagram set which is adapted for an unaged nitrogen oxide reduction catalytic converter and a second characteristic diagram set which is adapted for a definedly aged nitrogen oxide reduction catalytic converter are provided, wherein the first characteristic diagram set is assigned a first aging factor and the second characteristic diagram set is assigned a second aging factor, and wherein it is possible for the filling level determining means, during determination of the reducing agent filling level, to carry out an interpolation between the data of the first characteristic diagram set and the second characteristic diagram set as a function of the present aging factor.

6. A method for dosing a reducing agent containing additive into an exhaust line of an internal combustion engine, operated predominantly with an excess of air, having a metering point for metering the additive into exhaust gas, a nitrogen oxide reduction catalytic converter, which is arranged in the exhaust line downstream of the metering point, having a first catalytic converter part and a second catalytic converter part arranged downstream of the first catalytic converter part, and a dosing unit for regulating a metering quantity for the additive metered to the exhaust gas via the metering point, comprising:

determining a reducing agent filling level of at least one of the first catalytic converter part and the second catalytic converter part, and

selecting the reducing agent filling level of the first catalytic converter part or the reducing agent filling level of the second catalytic converter part as a regulating variable for regulation of metering of the additive as a function of the reducing agent filling level of at least one of the first catalytic converter part and the second catalytic converter part,

wherein the reducing agent filling level of a respective catalytic converter part is determined by summing and integration with respect to time of at least a conversion rate of reducing agent which is converted in the respective catalytic converter part, a desorption rate of reducing agent which is desorbed by the respective catalytic converter part, and a supply rate of reducing agent which is supplied to the respective catalytic converter part with the exhaust gas.

7. The method as claimed in claim 6 , wherein conversion of the reducing agent, which is stored in the respective catalytic converter part, with nitrogen oxide and oxygen contained in the exhaust gas is incorporated in the determination of the conversion rate.

8. The method as claimed in claim 7 , wherein a desorption rate of the first catalytic converter part is incorporated in the determination of the supply rate for the second catalytic converter part.

9. A method for dosing a reducing agent containing additive into an exhaust line of an internal combustion engine, operated predominantly with an excess of air, having a metering point for metering the additive into exhaust gas, a nitrogen oxide reduction catalytic converter, which is arranged in the exhaust line downstream of the metering point, having a first catalytic converter part and a second catalytic converter part arranged downstream of the first catalytic converter part, and a dosing unit for regulating a metering quantity for the additive metered to the exhaust gas via the metering point, comprising:

determining a reducing agent filling level of at least one of the first catalytic converter part and the second catalytic converter part, and

selecting the reducing agent filling level of the first catalytic converter part or the reducing agent filling level of the second catalytic converter part as a regulating variable for regulation of metering of the additive as a function of the reducing agent filling level of at least one of the first catalytic converter part and the second catalytic converter part,

wherein, for the reducing agent filling level of the first catalytic converter part, a first range with a first lower threshold value and a first upper threshold value is predefined,

wherein the reducing agent filling level of the first catalytic converter part is selected as a regulating variable for regulation of the metering of the additive if the reducing agent filling level of the first catalytic converter part lies below the first upper threshold value,

wherein, for the reducing agent filling level of the first catalytic converter part, an upper limit value which lies above the first upper threshold value is predefined, and

wherein the reducing agent filling level of the second catalytic converter part is selected as a regulating variable for the regulation of the metering of the additive if the reducing agent filling level of the first catalytic converter part lies between the first upper threshold value and the upper limit value.

10. The method as claimed in claim 9 , wherein at least one of the first range, the predefined upper limit value, and a second range for the reducing agent filling level of the second catalytic converter part is predefined as a function of an aging factor.