Retardation control element, liquid crystal display device with the retardation control element, method of producing the retardation control element
The invention provides a retardation control element capable of inhibiting a retardation defect that becomes a cause of light leakage and color shift of a liquid crystal display device from occurring, a method of producing the same, and a liquid crystal display device including such a retardation control element. A method of producing a retardation control element includes: a first step of filtering liquid crystal ink containing crosslinkable liquid crystal molecules with a filter material having a maximum pore diameter in the range of 0.1 to 5 μm; a second step of coating the filtered liquid crystal ink in a thin film on a revolving light-transmitting base material by means of a spin coating method; a third step of, after drying the base material under reduced pressure as needs arise, heating the coated liquid crystal ink to a liquid crystal phase temperature to align the crosslinkable liquid crystal molecules; and a fourth step of photo-polymerizing the aligned crosslinkable liquid crystal molecules each other to form a birefringence functional layer, wherein the second step is carried out with the base material covered with a tight cover.
1. A retardation control element, comprising:
a light-transmitting base material; and
a birefringence functional layer obtained by mutually crosslinking and polymerizing crosslinkable liquid crystal compounds coated directly or indirectly on the base material,
wherein a maximum outer diameter of foreign matters present on a surface or inside of the birefringence functional layer is 7 μm or less, the number per unit area of the foreign matters having an outer diameter in the range of 0.2 to 2 μm is 15 pieces /mm 2 or less, the number per unit area of the foreign matters having an outer diameter in the range of 2 to 5 μm is 10 pieces/mm 2 or less, and the number per unit area of the foreign matters having an outer diameter in the range of 5 to 7 μm is 5 pieces/mm 2 or less.
2. A retardation control element, comprising:
a light-transmitting base material; and
a birefringence functional layer obtained by mutually crosslinking and polymerizing crosslinkable liquid crystal compounds coated directly or indirectly on the base material,
wherein a maximum outer diameter of foreign matters present on a surface or inside of the birefringence functional layer is 5 μm or less, the number per unit area of the foreign matters having an outer diameter in the range of 0.2 to 2 μm is 15 pieces/mm 2 or less and the number per unit area of the foreign matters having an outer diameter in the range of 2 to 5 μm is 5 pieces/mm 2 or less.
3. The retardation control element according to claim 1 , wherein a thickness of the birefringence functional layer is in the range of 1 to 3 μm.
4. The retardation control element according to claim 2 , wherein a thickness of the birefringence functional layer is in the range of 1 to 3 μm.
5. The retardation control element according to claim 1 , wherein columns having height in the range of 2.5 to 5 μm from the surface of the birefringence functional layer are erected in a dispersed manner directly or indirectly on the surface of the base material.
6. The retardation control element according to claim 2 , wherein columns having height in the range of 2.5 to 5 μm from the surface of the birefringence functional layer are erected in a dispersed manner directly or indirectly on the surface of the base material.
7. The retardation control element according to claim 1 , wherein a coloring layer coated with a coloring material is formed between the base material and the birefringence functional layer or directly or indirectly on the birefringence functional layer.
8. The retardation control element according to claim 2 , wherein a coloring layer coated with a coloring material is formed between the base material and the birefringence functional layer or directly or indirectly on the birefringence functional layer.
9. The retardation control element according to claim 1 , wherein a coloring layer coated with a coloring material is formed between the base material and the birefringence functional layer, and a horizontal alignment film for horizontally aligning liquid crystal molecules is formed on the birefringence functional layer.
10. The retardation control element according to claim 2 , wherein a coloring layer coated with a coloring material is formed between the base material and the birefringence functional layer, and a horizontal alignment film for horizontally aligning liquid crystal molecules is formed on the birefringence functional layer.
11. A liquid crystal display device, comprising:
the retardation control element of claim 9 ;
another light-transmitting base material including a liquid crystal driving electrode and a horizontal alignment film and arranged facing the retardation control element; and
a driving liquid crystal layer arranged between the horizontal alignment film of the retardation control element and the horizontal alignment film of the another light-transmitting base material.
12. A liquid crystal display device, comprising:
the retardation control element of claim 10 ;
another light-transmitting base material including a liquid crystal driving electrode and a horizontal alignment film and arranged facing the retardation control element; and
a driving liquid crystal layer arranged between the horizontal alignment film of the retardation control element and the horizontal alignment film of the another light-transmitting base material.
13. A method of producing a retardation control element, comprising:
a first step of filtering liquid crystal ink containing crosslinkable liquid crystal molecules with a filter material having a maximum pore diameter in the range of 0.1 to 5 μm;
a second step of coating the filtered liquid crystal ink in a thin film on a light-transmitting base material;
a third step of, after drying the base material under reduced pressure as needs arise, heating the coated liquid crystal ink to a liquid crystal phase temperature to align the crosslinkable liquid crystal molecules; and
a fourth step of photo-polymerizing the aligned crosslinkable liquid crystal molecules each other to form a birefringence functional layer.
14. A method of producing a retardation control element, comprising:
coating liquid crystal ink containing crosslinkable liquid crystal molecules in a thin film on a revolving light-transmitting base material by means of a spin coating method;
after drying the base material under reduced pressure as needs arise, heating the coated liquid crystal ink to a liquid crystal phase temperature to align the crosslinkable liquid crystal molecules; and
photo-polymerizing the aligned crosslinkable liquid crystal molecules each other to form a birefringence functional layer,
wherein the coating the liquid crystal ink in a thin film is carried out with the base material covered with a tight cover.
15. A method of producing a retardation control element, comprising:
a first step of filtering liquid crystal ink containing crosslinkable liquid crystal molecules with a filter material having a maximum pore diameter in the range of 0.1 to 5 μm;
a second step of coating the filtered liquid crystal ink in a thin film on a revolving light-transmitting base material by means of a spin coating method;
a third step of, after drying the base material under reduced pressure as needs arise, heating the coated liquid crystal ink to a liquid crystal phase temperature to align the crosslinkable liquid crystal molecules; and
a fourth step of photo-polymerizing the aligned crosslinkable liquid crystal molecules each other to form a birefringence functional layer,
wherein the second step is carried out with the base material covered with a tight cover.