Method of producing a strip of nanocrystalline material and device for producing a wound core from said strip
The invention relates to a method of producing a strip of nanocrystalline material which is obtained from a wound ribbon that is cast in an amorphous state, having atomic composition [Fe 1−a−b Co a Ni b ] 100−x−y−z−α−β−γ Cu x Si y B z Nb α M′ β M″ γ , M′ being at least one of elements V, Cr, Al and Zn, and M″ being at least one of elements C, Ge, P, Ga, Sb, In and Be, with: a ≦0.07 and b ≦0.1, 0.5 ≦x ≦1.5 and 2 ≦α≦5, 10≦y≦16.9 and 5≦z≦8, β≦2 and γ≦2. According to the invention, the amorphous ribbon is subjected to crystallization annealing, in which the ribbon undergoes annealing in the unwound state, passing through at least two S-shaped blocks under voltage along an essentially longitudinal axial direction of the ribbon, such that the ribbon is maintained at an annealing temperature of between 530° C. and 700° C. for between 5 and 120 seconds and under axial tensile stress of between 2 and 1000 MPa. The tensile stress applied to the amorphous ribbon, the displacement speed of the ribbon during annealing and the annealing time and temperature are all selected such that the cross-section profile of the strip is not in the form of a Ω and the maximum deflection of the cross-section of the strip is less than 3% of the width of the strip and preferably less than 1% of the width. The invention also relates to the strip and the core thus obtained and to the device used to implement said method.
1. A process for the manufacture of a strip made of nanocrystalline material which is obtained from a ribbon cast in an amorphous state, said strip having the atomic composition:
[Fe 1−a−b Co a Ni b ] 100−x−y−z−α−β−γ Cu x Si y B z Nb α M′ β M″ γ
wherein M′ is at least one of the elements V, Cr, Al and Zn, and M″ is at least one of the elements C, Ge, P, Ga, Sb, In and Be, with:
a≦0.07 and b≦0.1
0.5≦x≦1.5 and 2≦α≦5
10≦y≦16.9 and 5≦z≦8
β≦2 and γ≦2
by subjecting the amorphous ribbon to a crystallization annealing in which the ribbon is subjected to the annealing in the unwound state, in forward progression through at least two S-type units and under tension in a substantially longitudinal axial direction of the ribbon, so that the ribbon is maintained at an annealing temperature of between 530° C. and 700° C., for a period of time of between 5 and 120 seconds, under an axial tensile stress of between 2 and 1000 MPa, the tensile stress to which said amorphous ribbon is subjected, its rate of forward progression during said annealing, the annealing time and the annealing temperature being chosen so that the cross section profile of the strip is not Ω-shaped and exhibits a maximum deflection of the transverse cross section of the strip of less than 3% of the width of the strip.
2. The process as claimed in claim 1 , in which the rate of forward progression of the strip is greater than or equal to 10 cm per second and per meter of furnace working zone.
3. The process as claimed in claim 1 , in which the axial tensile stress is greater than 500 Mpa and up to 1000 Mpa.
4. The process as claimed in claim 1 , in which the level of breakage of the amorphous ribbon in forward progression is less than 10 breakages per kilometer of ribbon.
5. The process as claimed in claim 1 , in which, in addition, y is greater than or equal to 12 and less than or equal to 16.9.
6. The process as claimed in claim 1 , in which:
a≦0.04 and b≦0.07
0.5≦x≦1.5 and 2≦α≦5
13≦y≦16.6 and 5.8≦z≦8
β≦2 and γ≦2.
7. The process as claimed in claim 6 , in which:
a≦0.02 and b≦0.05
0.5≦x≦1.5 and 2.5≦α≦4
β≦1 and 5.8≦z≦7.5.
8. The process as claimed in claim 1 , in which:
a+b≦ 0.1.
9. The process as claimed in claim 1 in which:
a=0.
10. The process as claimed in claim 1 , in which:
b=0.
11. The process as claimed in claim 1 , wherein the maximum deflection of the transverse cross section of the strip is less than 1% of the width of the strip.
12. The process as claimed in claim 1 , wherein the strip has a planar cross section.