Iron-gold barcode nanowire and manufacturing method thereof
Disclosed are an Fe—Au barcode type nanowire and a method of manufacturing the same. The nanowire has a magnetic-optical multifunction and is suitable for adjusting magnetic intensity thereof. The Fe—Au nanowire has a multilayered structure, in which an iron layer and a gold layer are alternately and repeatedly formed, and is formed in a single plating bath through a pulse electro-deposition.
1. A method of manufacturing a barcode nanowire having a superior biocompatibility, the method comprising the steps of:
preparing a nanotemplate having a pore and representing insulating property;
disposing the nanotemplate in an electrolytic solution including a first precursor for generating an iron ion and a second precursor for generating a gold ion; and
performing an electro-deposition to alternately and repeatedly form an iron layer and a gold layer in the pore,
wherein the electro-deposition step galvanostaticaly controls how iron ions and gold ions deposit into the pore, the electro-deposition step including a first step of forming the iron layer by applying a first current and a second step of forming the gold layer by applying a second current, the second has a current density lower than a current density of the first current, and the first and second steps are alternately and repeatedly performed until the nanowire has a required length,
wherein the density of the first current is in a range of from 10 mA/cm 2 to 50 mA/cm 2 , and the density of the second current is in a range of from 0.2 mA/cm 2 to 2 mA/cm 2 , and
wherein a molarity ratio of an iron to a gold ion is within a range of 4:1 to 40:1 in the electrolytic solution.
2. The method as claimed in claim 1 , further comprising the step of completely or partially oxidizing the iron layer of the nanowire to form an iron oxide layer by heating the nanowire in an oxygen atmosphere at a temperature and time combination selected to form a selected iron oxide.
3. The method as claimed in claim 1 , wherein the second precursor generates a gold (I) cation while dissociating in the electrolytic solution.
4. The method as claimed in claim 2 , wherein the second precursor generates a gold (I) cation while dissociating in the electrolytic solution.
5. The method as claimed in claim 1 , wherein the electrolytic solution includes iron (II) sulfate heptahydrate serving as the first precursor and potassium dicyanoaurate (I) serving as the second precursor.
6. The method as claimed in claim 2 , wherein the electrolytic solution includes iron (II) sulfate heptahydrate serving as the first precursor and potassium dicyanoaurate (I) serving as the second precursor.
7. The method as claimed in claim 2 , wherein the iron oxide layer includes at least any one selected from the group consisting of FeO, Fe 3 O 4 , γ-Fe 2 O 3 and α-Fe 2 O 3 .
8. The method as claimed in claim 1 , further comprising adding an inorganic acid buffer solution in an electrolytic solution in the electro-deposition step.
9. The method as claimed in claim 8 , wherein the inorganic buffer solution comprises H 3 BO 3 .
10. The method as claimed in claim 1 , further comprising constantly maintaining an acidity (pH) of an electrolytic solution in the electro-deposition step at a level of 3.4 ˜3.5, thereby maintaining a homeostasis of a current.
11. The method of claim 2 , wherein the heating time is selected to cause the iron-oxide layer to form a shell over a core of iron in the nanowire that is not oxidized.
12. The method of claim 2 , wherein the heating time is selected to cause the iron-oxide layer to completely oxidize the iron in the nanowire to create a Fe x O y —Au structure for the nanowire.