Rubber composition and pneumatic tire using same
View Patent ↗A tire sidewall may be formed from a composition including a rubber component and a non-ionic surfactant.
1. A tire sidewall formed from a composition comprising:
a rubber component including from about 25 to 65 weight percent natural rubber; and
a non-ionic surfactant represented by the formula
where R 1 is a monovalent organic group having a carbon number of from 11 to 14, where each R 2 is independently hydrogen or a group that may be represented by the formula C(O)R 1 , and where m, n, and p are independently an integer from 1 to about 10.
2. The sidewall composition of claim 1 , where the non-ionic surfactant includes polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitol tetraoleate, or mixtures thereof.
3. The sidewall composition of claim 1 , where R 1 is an alkyl or alkenyl group.
4. The sidewall composition of claim 1 , wherein the phenolic resin includes a synthetic resin obtained by reacting a phenolic compound with an aldehyde, where the phenolic compound includes an unsubstituted phenol, resorcin, an alkylphenol substituted in the p-position by a (C4 to C12) alkyl group, a phenolic resin modified by a natural resin, or a mixture thereof, and where the aldehyde includes formaldehyde, butyraldehyde, benzaldehyde, salicylaldehyde, acrolein, crotonealdehyde, acetaldehyde, or a mixture thereof.
5. The sidewall of claim 1 , where the composition further comprises a mild extraction solvator or a heavy naphthenic oil that contains less than about 3 percent by weight polycyclic aromatic content and has a glass transition temperature of from −40° C. to −80° C.
6. The sidewall of claim 1 , where the non-ionic surfactant is in the liquid state at standard temperature and pressure.
7. The sidewall of claim 6 , where the sidewall has a blacker appearance than those prepared using non-liquid, non-ionic surfactants.
8. The sidewall of claim 1 , where the composition includes less than about 6 pbw phr antiozonant.
9. The sidewall of claim 1 , where the composition includes less than about 5 pbw phr antiozonant.
10. The sidewall of claim 1 , where the composition includes less than about 4 pbw phr antiozonant.
11. The sidewall of claim 1 , where the amount of antiozonant in the composition is reduced in comparison to conventional sidewall compositions.
12. A tire sidewall comprising:
a vulcanized rubber component including 25 to 65 weight percent natural rubber;
a non-ionic surfactant represented by the formula
where R 1 is a monovalent organic group having a carbon number of from 11 to 14 or 15 to 24, with the proviso that where R 1 has a carbon number of 15 to 24, the sidewall further comprises a phenolic resin, where each R 2 is independently hydrogen or a group that may be represented by the formula C(O)R 1 , and where m, n, and p are independently an integer from 1 to about 10; and
between about 1 and about 6 pbw phr of an antiozonant.
13. The sidewall of claim 12 , where the non-ionic surfactant includes polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitol tetraoleate, or mixtures thereof.
14. The sidewall composition of claim 12 , where R 1 is an alkyl or alkenyl group.
15. The sidewall of claim 12 , where R 1 has a carbon number of from 11 to 14.
16. The sidewall of claim 12 , wherein the phenolic resin includes a synthetic resin obtained by reacting a phenolic compound with an aldehyde, where the phenolic compound includes an unsubstituted phenol, resorcin, an alkylphenol substituted in the p-position by a (C4 to C12) alkyl group, a phenolic resin modified by a natural resin, or a mixture thereof, and where the aldehyde includes formaldehyde, butyraldehyde, benzaldehyde, salicylaldehyde, acrolein, crotonealdehyde, acetaldehyde, or a mixture thereof.
17. The sidewall of claim 12 , where the sidewall further comprises a mild extraction solvator or a heavy naphthenic oil that contains less than about 3 percent by weight polycyclic aromatic content and has a glass transition temperature of from −40° C. to −80° C.
18. The sidewall of claim 12 , where the non-ionic surfactant is in the liquid state at standard temperature and pressure.
19. The sidewall of claim 18 , where the sidewall has a blacker appearance than those prepared using non-liquid, non-ionic surfactants.
20. A method for preparing a tire, the method comprising the steps of:
mixing ingredients including at least one rubber component, a filler, optionally a non-ionic surfactant, and optionally a phenolic resin, to form a first mixture, where the rubber component includes 25 to 65 weight percent natural rubber;
cooling the first mixture;
further mixing the first mixture, optionally with additional ingredients including a non-ionic surfactant and optionally a phenolic resin, to form an intermediate mixture, with the proviso that at least one of the ingredients mixed to form the first mixture or the additional ingredients added to form the intermediate composition includes a non-ionic surfactant represented by the formula
where R 1 is an alkyl group or an alkenyl group having a carbon number of from 11 to 14, where each R 2 is independently hydrogen or a group that may be represented by the formula C(O)R 1 , and where m, n, and p are independently an integer from 1 to about 10;
adding ingredients including a curative to the intermediate mixture to form a vulcanizable mixture;
mixing the vulcanizable mixture;
forming the vulcanizable mixture into a tire sidewall component;
building a tire by including the tire component; and
curing the tire.
21. The method of claim 20 , where the non-ionic surfactant includes polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitol tetraoleate, or mixtures thereof.
22. The sidewall composition of claim 20 , where R 1 is an alkyl or alkenyl group.
23. The method of claim 20 , wherein the phenolic resin includes a synthetic resin obtained by reacting a phenolic compound with an aldehyde, where the phenolic compound includes an unsubstituted phenol, resorcin, an alkylphenol substituted in the p-position by a (C4 to C12) alkyl group, a phenolic resin modified by a natural resin, or a mixture thereof, and where the aldehyde includes formaldehyde, butyraldehyde, benzaldehyde, salicylaldehyde, acrolein, crotonealdehyde, acetaldehyde, or a mixture thereof.
24. The method of claim 20 , where one of the ingredients mixed to form the first mixture or the additional ingredients added to form the intermediate composition is a mild extraction solvator or a heavy naphthenic oil that contains less than about 3 percent by weight polycyclic aromatic content and has a glass transition temperature of from −40° C. to −80° C.
25. The method of claim 20 , where the non-ionic surfactant is in the liquid state at standard temperature and pressure.
26. The method of claim 25 , where the sidewall component has a blacker appearance than those prepared using non-liquid, non-ionic surfactants.