Differential scanning calorimeter
View Patent ↗There is provided a differential scanning calorimeter for exactly measuring a calorie variation of the measured sample on the basis of the temperature difference between sample container and the reference container without the influence of the heat irregularity incoming from the surroundings and the noise components. The differential scanning calorimeter includes a heating furnace of an approximately H-shaped section having an approximately drum-shaped wall part and an approximately plate-shaped heat inflow part, a heater disposed outside the wall part so as to heat the heating furnace, a approximately bar-shaped heat-resistance member that is arranged along the center axis L of the wall part, that protrudes from both sides of the heat inflow part by an approximately equal length, that is made of a material heat conductivity lower than that of the material of the heating furnace, a sample container disposed at one end of the heat-resistance member, a reference container disposed at the other end of the heat-resistance member, and a differential heat flow detector measuring a difference between the temperature of the sample container and the temperature of the reference container as a measured value.
1. A differential scanning calorimeter comprising:
a heating furnace of an approximately H-shaped cross section having an approximately drum-shaped wall part to cover the surroundings and an approximately plate-shaped heat inflow part to be formed at the inner circumference of the wall part,
wherein the heating furnace is disposed with a center axis approximately vertical;
a heater disposed at the outer circumference of the wall part and to heat the heating furnace;
an approximately bar-shaped heat-resistance member that is vertically arranged along the center axis of the heating furnace, that protrudes by an approximately equal length from both sides of the heat inflow part, that is secured at the heat inflow part, and that is made of a material with heat conductivity lower than that of the material of the heating furnace;
a sample container disposed at one end of the heat-resistance member so as to contain a measured sample;
a reference container disposed at an opposite end of the heat-resistance member; and a differential heat flow detector detecting a difference between the temperature of the sample container and the temperature of the reference container as a measured value.
2. A differential scanning calorimeter comprising,
a heating furnace of an approximately H-shaped cross section having an approximately drum-shaped wall part to cover the surroundings and an approximately plate-shaped heat inflow part to be formed at the inner circumference of the wall part;
a heater disposed at the outer circumference of the wall part of the heating furnace and to heat the heating furnace,
wherein the heating furnace is disposed with a center axis approximately vertical;
a first heat-resistance member and a second heat-resistance member as a pair of bar-shaped members that are vertically arranged along the center axis of the heating furnace, that protrude by an approximately equal length from the both sides of the heat inflow part, that are secured at the heat inflow part, and that are made of a material with heat conductivity lower than that of the material of the heating furnace;
a sample container disposed at one end of the first heat-resistance member so as to contain a measured sample;
a first reference container disposed at an opposite end of the first heat-resistance member;
a second reference container disposed at one end of the second heat-resistance member protruding in the same direction as one end of the first heat-resistance member;
a third reference container disposed at an opposite end of the second heat-resistance member; and
a differential heat flow detector detecting a difference between a value obtained by subtracting the temperature of the first reference container from the temperature of the sample container and a value obtained by subtracting the temperature of the third reference container from the temperature of the second reference container as a measured value.