Silicon-based decorative coatings

1 . A method of coating an outer surface of object with a decorative coating, comprising the steps of

a) placing an object having an outer surface to be coated with a decorative coating in a treatment environment (e.g., treatment chamber) for treatment;

b) dehydrating the outer surface of the object;

c) evacuating the treatment environment;

d) introducing a silicon hydride gas into the treatment environment to contact the outer surface of the object;

e) heating and pressurizing the silicon hydride gas in the treatment environment;

f) depositing a layer of silicon on the outer surface of the object;

g) controlling the duration of the silicon depositing step to prevent the formation of silicon dust;

h) purging the treatment environment with an inert gas to remove the silicon hydride gas;

i) repeating steps c-h until a desired decorative coating is obtained on the outer surface of the object desired to be provided with the decorative coating;

j) evacuating the treatment environment; and,

k) cooling the object having the decorative coating formed thereon to room temperature.

2 . A method of coating an outer surface of an object with a decorative coating, comprising the steps of

a) placing an object having an outer surface to be coated with a decorative coating in a treatment environment (e.g., treatment chamber) for treatment;

b) dehydrating the outer surface of the object;

c) evacuating the treatment environment;

d) introducing a silicon hydride gas into the treatment environment to contact the outer surface of the object;

e) heating and pressurizing the silicon hydride gas prior to, during or after the introduction of silicon hydride gas in the treatment environment;

f) depositing a layer of silicon on the outer surface of the object;

g) controlling the duration of the silicon depositing step, the pressure of the silicon hydride gas, and the presence of contaminants on the outer surface of the object to prevent the formation of silicon dust;

h) cooling the object to a lower temperature and maintaining the object at a lower temperature for a period of time,

i) purging the treatment environment with an inert gas to remove the silicon hydride gas;

j) repeating steps c-j until a desired decorative coating is obtained on the outer surface of the object desired to be provided with the decorative coating;

k) evacuating the treatment environment; and,

l) cooling the object having the decorative coating formed thereon to room temperature.

3 . A method of coating the outer surface of an object with a decorative coating, comprising the steps of

a) placing an object having an outer surface to be coated with a decorative coating in a treatment environment (e.g., treatment chamber) for treatment;

b) depositing a coating of hydrogenated amorphous silicon on the outer surface of the object; and

c) functionalizing the coated object by exposing the coated object to a binding reagent having at least one unsaturated hydrocarbon group at an effective pressure and elevated temperature for an effective length of time.

4 . The method of claim 3 , further including

initially cleaning the object by heating it to a temperature between to about 100 degrees C. and about 600 C. for a time period ranging from few minutes to about 15 hours before exposing the object to hydrogenated amorphous silicon, quenching residual silicon radicals in the hydrogenated amorphous silicon coating either before or after functionalizing the coated object, and/or exposing the object to oxygen prior to or contemporaneously with the hydrosilylation step.

5 . An object having an outer surface treated in accordance with the method of claim 1 .

6 . An object having an outer surface treated in accordance with the method of claim 2 .

7 . An object having an outer surface treated in accordance with the method of claim 3 .

8 . An object having an outer surface treated in accordance with the method of claim 4 .