Surface conditioner and surface conditioning method
The invention provides a surface conditioner which can prevent an aluminum alloy from stray current corrosion in chemical conversion treatment and reduce the difference between contact and noncontact areas in conversion coating build-up on an aluminum alloy and which enables the formation of excellent chemical conversion coatings on various metal materials and a surface conditioner which can prevent metal from rusting after surface conditioning and is excellent in dispersion stability in a treating bath. A surface conditioner to be applied prior to the phosphating of metal which contains (A) zinc phosphate particles having D 50 of 3 μm or below, (B) a water-soluble organic polymer, and (C) a layer clay mineral and has a pH of 3 to 12, characterized by further containing as the function imparting agent (D) a di- or tri-valent metal nitrite, zinc oxide and/or sodium hydroxide, or a nonionic or anionic surfactant.
1. A surface conditioner having a pH of 3 to 12 that is used prior to phosphate conversion coating of a metal, the surface conditioner comprising:
(A) zinc phosphate particles for which D 50 is not more than 3 μm,
(B) a water-soluble organic polymer,
(C) a laminar clay mineral, and
(D) a function-imparting agent, wherein the function-imparting agent is selected from the group consisting of (a) a zeta potential modifier, (b) a nonionic surfactant having an HLB value of 6 or greater, and (c) a divalent or trivalent metal nitrite compound, in which a quantity of the metal nitrite compound, calculated as an equivalent quantity of NO 2 , is within a range from 10 to 500 ppm.
2. The surface conditioner according to claim 1 , wherein the water-soluble organic polymer (B) is at least one polymer selected from the group consisting of:
(1) carboxylic acid group-containing copolymers obtainable by copolymerizing a monomer mixture comprising less than 50% by mass of at least one carboxylic acid group-containing monomer selected from the group consisting of (meth)acrylic acid, maleic acid, maleic anhydride, itaconic acid and itaconic anhydride, and greater than 50% by mass of another monomer that is capable of copolymerization with the carboxylic acid group-containing monomer,
(2) phosphate esters represented by either a formula (I) shown below:
(wherein, R 1 represents an alkyl group or alkylphenol group of 8 to 30 carbon atoms, 1 represents either 0 or 1, m is from 1 to 20, and n represents 1, 2 or 3),
or a formula (II) shown below:
(wherein, h represents an integer from 2 to 24, and i represents either 1 or 2),
(3) polyester resins,
(4) phosphonic acid group-containing resins, and
(5) polyamine-based resins,
and the function-imparting agent (D) is a divalent or trivalent metal nitrite compound, in which a quantity of the metal nitrite compound, calculated as an equivalent quantity of NO 2 , is within a range from 10 to 500 ppm.
3. A surface conditioner according to claim 1 , wherein
the water-soluble organic polymer (B) is a carboxylic acid group-containing copolymer obtainable by copolymerizing a monomer mixture comprising less than 50% by mass of at least one carboxylic acid group-containing monomer selected from the group consisting of (meth)acrylic acid, maleic acid, maleic anhydride, itaconic acid and itaconic anhydride, and greater than 50% by mass of another monomer that is capable of copolymerization with the carboxylic acid group-containing monomer,
wherein the zeta potential modifier is zinc oxide and/or sodium hydroxide,
a zeta potential is not more than −50 mV, and
a pH is within a range from 8 to 11.
4. The surface conditioner according to claim 2 , wherein
the monomer that is capable of copolymerization with the carboxylic acid group-containing monomer comprises a sulfonic acid monomer and/or styrene.
5. The surface conditioner according to claim 2 , wherein
the carboxylic acid group-containing copolymer is obtainable by copolymerizing a monomer mixture comprising less than 50% by mass of (meth)acrylic acid, and more than 50% by mass of a combined mass of 2-(meth)acrylamido-2-methylpropanesulfonic acid and/or allylsulfonic acid.
6. The surface conditioner according to claim 1 , wherein the laminar clay mineral is a natural hectorite and/or a synthetic hectorite.
7. The surface conditioner according to claim 1 , wherein the laminar clay mineral is a material obtained by surface treating bentonite with an alkyltrialkoxysilane represented by a formula (III) shown below:
(wherein, R 2 represents a saturated alkyl group of 1 to 22 carbon atoms, and R 3 groups may be identical or different, and each represent a methyl group, ethyl group, propyl group or butyl group).
8. The surface conditioner according to claim 2 , wherein a weight average molecular weight of the phosphonic acid group-containing resin is within a range from 3,000 to 20,000.
9. A surface conditioning method, comprising bringing the surface conditioner according to claim 1 into contact with a metal surface.
10. A surface conditioning method, comprising a step of bringing the surface conditioner according to claim 1 into contact with a metal surface, wherein the step comprises adsorbing zinc phosphate equivalent to at least 3 mg/m 2 of Zn.