Bacterial poly(hydroxy alkanoate) polymer and natural fiber composites
View Patent ↗A biocomposite is produced from natural fiber fabrics embedded in a matrix of biosynthetic polyhydroxy-alkanoate (PHA) polymers. The PHA is synthesized using aerobic microbial biosynthesis using mixed bacterial cultures and a feedstock containing anaerobic degradation products such as methane and volatile fatty acids derived from microbial biodegradation of organic waste materials, which may include waste biocomposites. Monomers may be added to the synthesized PHA polymer to control mechanical properties of the resulting biocomposite. The natural fibers and/or PHA may be pretreated using various techniques to improve the bond between the fibers and the PHA resin matrix and water absorption resistance of the fibers. The composite may be a laminate of treated and untreated fabric layers, or differently treated layers, to achieve good in-service performance as well as rapid and/or optimal biogas production when taken out of service and put in an anaerobic environment to degrade.
1. A method for producing a biocomposite material, the method comprising:
performing anaerobic microbial biodegradation of waste materials to produce anaerobic degradation products;
wherein the waste materials comprise waste biocomposite materials;
wherein the anaerobic degradation products comprise methane and carbon dioxide;
performing aerobic microbial biosynthesis of PHA polymers from a feedstock using mixed bacterial cultures, wherein the feedstock comprises the methane produced by the anaerobic microbial biodegradation;
extracting the biosynthesized PHA polymers to obtain PHA granules; and
fabricating the biocomposite material from the PHA granules and natural fibers;
wherein fabricating the biocomposite material comprises producing a PHA polymer resin from the PHA granules, and embedding multiple layers of a natural fiber fabric in the PHA polymer resin to form a laminate biocomposite material.
2. The method of claim 1 wherein the anaerobic degradation products comprise volatile fatty acids, and wherein the feedstock comprises the volatile fatty acids.
3. The method of claim 2 wherein the volatile fatty acids comprise acetic and propionic acids.
4. The method of claim 1 wherein the natural fibers are a woven fabric.
5. The method of claim 1 wherein the natural fibers are a mat.
6. The method of claim 1 wherein forming the biocomposite material comprises a hand/wet lay-up process.
7. The method of claim 1 wherein forming the biocomposite material comprises embedding the natural fibers in a matrix produced from the PHA granules.
8. The method of claim 1 wherein fabricating the biocomposite material comprises forming a matrix from monomers and PHA derived from the PHA granules.
9. The method of claim 8 wherein the monomers comprise monomer units selected from the group consisting of hydroxyhexanoate (HH), hydroxybuterate (HB), and hydroxyvalerate (HV).