White light emitting device
View Patent ↗A white light emitting device including: a blue light emitting diode (LED); a green silicate phosphor formed on the blue LED; and a red sulfide phosphor with a surface coated with a silicone oxide layer, the red sulfide phosphor formed on the blue LED.
1. A white light emitting device comprising:
a blue light emitting diode (LED);
a green silicate phosphor formed on the blue LED; and
a red sulfide phosphor with a surface coated with a silicon oxide layer, the red sulfide phosphor formed on the blue LED,
wherein the green silicate phosphor comprises Eu-doped Mg 2 SiO 4 :Eu, Re, the Re that is one or more rare-earth elements selected from a group consisting of Ce, Pr, Sm, Gd, Tb, Dy, Ho, and Er, and
wherein the red sulfide phosphor comprises (Ca, Sr) (S, Se):Eu, Re′, the Re′ that is one or more rare-earth elements selected from a group consisting of Pr, Gd, Tb, Dy, Ho, and Er.
2. The white light emitting device of claim 1 , wherein the green silicate phosphor has a peak wavelength of 520 to 550 nm and the red sulfide phosphor has a peak wavelength of 630 to 660 nm, and
the green silicate phosphor has a full width at half maximum (FWHM) of 30 to 90 nm and the red sulfide phosphor has an FWHM of 40 to 100 nm.
3. The white light emitting device of claim 1 , wherein the red sulfide phosphor with a coated surface comprises:
red sulfide phosphor particles;
a silicon oxide layer formed on the red sulfide phosphor particles; and
a buffer layer bonded between the red sulfide phosphor particles and the silicon oxide layer and containing sulfur and a hydrocarbon radical.
4. The white light emitting device of claim 3 , wherein the hydrocarbon radical is an alkyl group.
5. The white light emitting device of claim 1 , further comprising a resin encapsulation portion encapsulating the blue LED,
wherein the green silicate phosphor and the red sulfide phosphor with a coated surface are dispersed in the resin encapsulation portion.
6. The white light emitting device of claim 1 , further comprising a package body having a reflective cup,
wherein the blue LED is mounted on the reflective cup of the package body.
7. The white light emitting device of claim 1 , wherein the green silicate phosphor and the red sulfide phosphor with a coated surface are provided in the form of one of a single phosphor layer and a multilayer phosphor layer on the blue LED.
8. The white light emitting device of claim 1 , further comprising a resin encapsulation portion having a lens convex upwardly and encapsulating the blue LED.