Bipolar separator plate for use in a fuel cell assembly and for preventing poisoning of reforming catalyst
An anode support for supporting an anode electrode in a fuel cell assembly in which the anode support has a first support member formed of a porous non-wettable material and a second support member abutting and joined with the second member and having a plurality of through openings. Also disclosed is a bipolar separator having an electrolyte barrier over predetermined limited portions of its outer surface so as to prevent or retard electrolyte creeping.
1. A bipolar separator for use with a fuel cell comprising:
a plate member having opposing first and second surfaces compatible with fuel gas and oxidant gas, respectively, said plate member having first and second opposing ends and third and fourth opposing ends;
first, second, third and fourth pocket members, said first and second pocket members being situated adjacent said first and second opposing ends of said plate member and extending outward of said first surface and then facing each other and said third and fourth pocket members being situated adjacent said third and fourth opposing ends of said plate member and extending outward of said second surface and then facing each other, said third and fourth pocket members each having an inner surface facing the plate member and an outer surface opposing said inner surface and facing away from said plate member;
said bipolar separator having first and second outer surface parts formed by outer surfaces of said third and fourth pocket members, respectively;
and an electrolyte barrier comprising a non-wettable material situated on a limited portion of an outer surface of said third pocket member and a limited portion of an outer surface of said fourth pocket member, wherein the limited portion of said outer surface is smaller than the entire outer surface, said limited portion of said outer surface of said third pocket member includes a surface portion at the end of said outer surface of said third pocket member closest to said plate member and said limited portion of said outer surface of said fourth pocket member includes a surface portion at the end of said outer surface of said fourth pocket member closest to said plate member.
2. A bipolar separator in accordance with claim 1 , wherein said electrolyte barrier comprises one of a weld bead, a foil welded to and a coating applied to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member.
3. A bipolar separator in accordance with claim 2 , wherein said electrolyte barrier comprises at least one of Ni, Cu, Ni alloy and Cu alloy.
4. A bipolar separator in accordance with claim 3 , wherein said electrolyte barrier further comprises a filler.
5. A bipolar separator in accordance with claim 4 , wherein said filler comprises a welding filler rod.
6. A bipolar separator in accordance with claim 2 , wherein said electrolyte barrier has a thickness of 10 to 100 μm and a width of at least 0.254 cm.
7. A bipolar separator in accordance with claim 1 , wherein:
said electrolyte barrier comprises one of a weld bead and a foil welded to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member; and
said electrolyte barrier further comprises a non-wettable coating: applied to said limited portion of the outer surface of said third pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said third pocket; and applied to said limited portion of the outer surface of said fourth pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said fourth pocket member.
8. A bipolar separator in accordance with claim 1 , wherein:
said third pocket member includes a back extension aligned with an end extension at said third end of said plate member, edge surfaces of said back extension of said third pocket member and said end extension at said third end of said plate member forming a wet-seal edge, and
said fourth pocket member includes a back extension aligned with an end extension at said fourth end of said plate member, edge surfaces of said back extension of said fourth pocket member and said end extension at said fourth end of said plate member forming a wet-seal edge; and
wherein the edge surface of the back extension of said third pocket member forms a part of the limited portion of the outer surface of the third pocket member and the edge surface of the back extension of the fourth pocket member forms a part of the limited portion of the outer surface of the fourth pocket member.
9. A bipolar separator in accordance with claim 8 , wherein:
said electrolyte barrier comprises one of a weld bead, a foil welded to and a coating applied to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member.
10. A bipolar separator in accordance with claim 8 :
said electrolyte barrier comprises one of a weld bead and a foil welded to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member; and
said electrolyte further comprises a non-wettable coating: applied to said limited portion of the outer surface of said third pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said third pocket; and applied to said limited portion of the outer surface of said fourth pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said fourth pocket member.
11. A bipolar separator in accordance with claim 8 , wherein;
said plate member is formed separately from said pocket members,
said first pocket member includes a back extension aligned with an end extension at said first end of said plate member;
and said second pocket member includes a back extension aligned with an end extension at said second end of said plate member; and
said back extensions of said first, second, third and fourth pocket member are welded to the end extensions at the first, second, third and fourth ends of said plate member.
12. A fuel cell assembly comprising:
a fuel cell including an anode, a cathode and an electrolyte matrix disposed between said anode and said cathode;
an anode current collector abutting said anode and forming a plurality of passages for passing fuel gas and storing a reforming catalyst therein; and
a bipolar separator abutting said anode current collector for separating said fuel cell assembly from an adjacent fuel cell assembly, said bipolar separator comprising a plate member having opposing first and second surfaces, said first surface being compatible with fuel gas and abutting said anode current collector and said second surface being compatible with oxidant gas and abutting said adjacent fuel cell assembly, said plate member having first and second opposing ends and third and fourth opposing ends;
first, second, third and fourth pocket members, said first and second pocket members being situated adjacent said first and second opposing ends of said plate member and extending outward of said first surface and then facing each other, and said third and fourth pocket members being situated adjacent said third and fourth opposing ends of said plate member and extending outward of said second surface and then facing each other, said third and fourth pocket members each having an inner surface facing the plate member and an outer surface opposing said inner surface and facing away from said plate member;
said bipolar separator having first and second outer surface parts formed by outer surfaces of said third and fourth pocket members, respectively;
and an electrolyte barrier comprising a non-wettable material situated on a limited portion of an outer surface of said third pocket member and a limited portion of an outer surface of said fourth pocket member, wherein the limited portion of the outer surface is smaller than the entire outer surface, said limited portion of said outer surface of said third pocket member includes a surface portion at the end of said outer surface of said third pocket member closest to said plate member and said limited portion of said outer surface of said fourth pocket member includes a surface portion at the end of said outer surface of said fourth pocket member closest to said plate member.
13. A fuel cell assembly in accordance with claim 12 , wherein said electrolyte barrier comprises a non-wettable material comprising at least one of Ni, Cu, Ni alloy and Cu alloy.
14. A fuel cell assembly in accordance with claim 12 , wherein said electrolyte barrier comprises one of a weld bead, a foil welded to and a coating applied to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member.
15. A fuel cell assembly in accordance with claim 14 , wherein said electrolyte barrier further comprises a filler.
16. A fuel cell assembly in accordance with claim 15 , wherein said filler comprises a welding filler rod.
17. A fuel cell assembly in accordance with claim 14 , wherein said electrolyte barrier has a thickness of 10 to 100 μM and a width of at least 0.254 cm.
18. A fuel cell assembly in accordance with claim 12 , wherein:
said electrolyte barrier comprises one of a weld bead and a foil welded to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member; and
said electrolyte barrier further comprises a non-wettable coating: applied to said limited portion of the outer surface of said third pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said third pocket; and applied to said limited portion of the outer surface of said fourth pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said fourth pocket member.
19. A fuel cell assembly in accordance with claim 12 , wherein:
said third pocket member includes a back extension aligned with an end extension at said third end of said plate member, edge surfaces of said back extension of said third pocket member and said end extension at said third end of said plate member forming a wet-seal edge, and
said fourth pocket member includes a back extension aligned with an end extension at said fourth end of said plate member, edge surfaces of said back extension of said fourth pocket member and said end extension at said fourth end of said plate member forming a wet-seal edge; and
wherein the edge surface of the back extension of said third pocket member forms a part of the limited portion of the outer surface of the third pocket member and the edge surface of the back extension of the fourth pocket member forms a part of the limited portion of the outer surface of the fourth pocket member.
20. A fuel cell assembly in accordance with claim 19 , wherein:
said electrolyte barrier comprises one of a weld bead, a foil welded to and a coating applied to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member.
21. A fuel cell assembly in accordance with claim 19 :
said electrolyte barrier comprises one of a weld bead and a foil welded to said limited portion of the outer surface of said third pocket member and to said limited portion of the outer surface of said fourth pocket member; and
said electrolyte further comprises a non-wettable coating: applied to said limited portion of the outer surface of said third pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said third pocket; and applied to said limited portion of the outer surface of said fourth pocket member and extending from said one of said weld bead and said foil welded to said limited portion of said outer surface of said fourth pocket member.
22. A fuel cell assembly in accordance with claim 19 , wherein;
said plate member is formed separately from said pocket members,
said first pocket member includes a back extension aligned with an end extension at said first end of said plate member;
and said second pocket member includes a back extension aligned with an end extension at said second end of said plate member; and
said back extensions of said first, second, third and fourth pocket member are welded to the end extensions at the first, second, third and fourth ends of said plate member.