Multijunction solar cell with two step diffusion region in substrate
View Patent ↗A solar cell having a first subcell including a germanium (Ge) substrate having a diffusion region doped with n-type dopants including phosphorus and arsenic, wherein the upper portion of such diffusion region has a higher concentration of phosphorus (P) atoms than arsenic (As) atoms, and a second subcell including a layer of either gallium arsenide (GaAs) or indium gallium arsenide (InGaAs) disposed over the substrate.
1. A solar cell comprising:
a first subcell including a bulk germanium (Ge) substrate composed entirely of doped or undoped germanium, the bulk Ge substrate having a diffusion region doped with n-type dopants including phosphorus and arsenic, wherein an upper portion of such diffusion region has a higher concentration of phosphorus (P) atoms than arsenic (As) atoms, wherein the diffusion region further includes a lower portion, and As atoms have a higher concentration compared to P atoms in the lower portion,
a second subcell including a layer of either gallium arsenide (GaAs) or indium gallium arsenide (InGaAs) disposed over the bulk Ge substrate,
a nucleation layer in direct physical contact with the bulk Ge substrate, wherein the nucleation layer controls the diffusion of As atoms into the substrate, the nucleation layer being devoid of arsenic.
2. A solar cell as recited in claim 1 wherein the nucleation layer has a lattice parameter substantially equal to the lattice parameter of the germanium substrate.
3. A solar cell as recited in claim 1 wherein the nucleation layer is a compound of InGaP.
4. A solar cell as recited in claim 1 wherein the nucleation layer has a thickness equal to 350 angstroms or less.
5. A solar cell defined in claim 1 wherein a junction in the germanium substrate is located between 0.3 μm and 0.7 μm from the top surface of the germanium substrate.
6. A solar cell as defined in claim 1 wherein diffused phosphorus and arsenic in the germanium substrate have a diffusion profile arranged to provide current and voltage characteristics that optimize the power output of the solar cell.
7. A solar cell as defined in claim 1 further comprising a third subcell disposed over the second subcell.
8. A solar cell as defined in claim 1 wherein the diffusion region comprises a two-step diffusion profile.
9. A solar cell as recited in claim 1 wherein the germanium substrate is p-type.
10. A solar cell as recited in claim 9 wherein the diffusion region corresponds to an n-type portion of a shallow n-p junction in the germanium substrate.
11. A solar cell as recited in claim 7 wherein the third subcell is composed of InGaP.
12. A solar cell as recited in claim 1 further comprising a buffer layer disposed over said nucleation layer.
13. A solar cell as recited in claim 12 wherein the buffer layer is composed of GaAs.
14. A solar cell as recited in claim 11 wherein the thickness of the third subcell is configured so that the short circuit current of the third subcell is equal to the short circuit current of the second subcell.
15. A solar cell as recited in claim 1 wherein the depth of diffusion of the As dopant in the two-step diffusion region is greater than a depth of diffusion of the P dopant in the two-step diffusion region.