System and method for controlling an anode side recirculation pump in a fuel cell system
View Patent ↗A system and method for controlling the speed of a recirculation pump in an anode recirculation loop of a fuel cell system based on a predetermined ratio of fresh hydrogen to recirculated anode gas. The system uses a model to determine the volume flow of the recirculated gas through a fuel cell stack to determine the recirculation rate based on a measured temperature of the recirculated gas, a measured pressure drop across a recirculation pump, a pressure drop across the anode inlet and outlet of the stack, a percentage of hydrogen in the recirculated gas, and the density of the recirculated gas.
1. A method for determining the speed of a recirculation pump in an anode recirculation loop of a fuel cell stack based on a predetermined ratio of fresh hydrogen to recirculated hydrogen, said method comprising:
measuring the pressure drop across the recirculation pump;
measuring the temperature of the anode recirculation gas flowing through the recirculation loop;
feeding fresh hydrogen into the recirculation loop;
calculating the pressure drop across the anode side of the stack;
calculating the volume flow of the recirculation gas through the anode side of the stack as a function of the calculated pressure drop across the anode side of the stack, the percentage of hydrogen in the recirculation gas, the measured temperature of the anode recirculation gas flowing through the recirculation loop and the measured pressure drop across the recirculation pump; and
using the calculated volume flow and the amount of fresh hydrogen being fed into the recirculation loop to determine the speed of the pump to achieve the predetermined ratio.
2. The method according to claim 1 wherein calculating the pressure drop across the anode side of the stack includes using the measured pressure.
3. The method according to claim 2 wherein calculating the pressure drop across the anode side of the stack includes determining and using the pressure drop across a water separator in the recirculation loop that removes water from the recirculation gas.
4. The method according to claim 3 wherein calculating the pressure drop across the anode side of the stack includes determining and using the pressure drop across piping in the recirculation loop.
5. The method according to claim 4 wherein calculating the pressure drop across the anode side of the stack includes using the equation:
Δ p anode =(1 −c piping )·(Δ p pump −Δp separator )
where Δp anode is the pressure drop across the anode side of the stack, c piping is the pressure drop across the piping in the recirculation loop, Δp pump is the measured pressure drop across the pump and Δp separator is the pressure drop across the water separator.
6. The method according to claim 1 further comprising calculating the density of the recirculation gas flowing through the recirculation loop using the calculated volume flow, the measured pressure drop and the speed of the pump.
7. The method according to claim 6 wherein the density of the recirculation gas is calculated by the equation:
ρ
=
p
·
∑
n
i
·
M
W
i
nRT
=
p
·
∑
n
i
n
·
M
W
i
RT
where n is the speed of the pump, ρ is the density, p is the measured pressure, T is the measured temperature and MW is the molecular weight of the gas.
8. The method according to claim 6 further comprising calculating the percentage of hydrogen in the recirculation gas as a function of the density of the recirculation gas flowing through the recirculation pump, the measured temperature and the measured pressure.
9. The method according to claim 8 wherein an accurate value for the volume flow of the recirculation gas through the anode side of the stack and the percentage of hydrogen in the recirculation gas is provided after a few cycles of calculating the percentage of hydrogen in the recirculation gas, calculating the volume flow of the recirculation gas of the anode side of the stack and calculating the density of the recirculation gas.
10. A fuel cell system comprising:
a fuel cell stack;
a recirculation loop for recirculating anode exhaust gas from the stack to an anode inlet;
a source of fresh hydrogen;
a mixing junction for mixing the fresh hydrogen with the recirculated gas;
a recirculation pump for pumping the recirculation gas through the recirculation loop;
a temperature sensor for measuring the temperature of the recirculation gas in the recirculation loop;
a pressure sensor for measuring the pressure drop across the recirculation pump; and
a controller programmed to control the speed of the pump to control the ratio of fresh hydrogen to recirculated hydrogen, said controller calculating the pressure drop across the anode side of the stack, calculating the volume flow of the recirculated gas through the anode side of the stack as a function of the calculated pressure drop across the anode side of the stack, the percentage of hydrogen in the recirculation gas, the measured temperature of the anode recirculation gas flowing through the recirculation loop and the measured pressure drop across the recirculation pump, and using the calculated volume flow to determine the speed of the pump to achieve a predetermined ratio of fresh hydrogen to recirculated hydrogen.
11. The system according to claim 10 wherein the controller calculates the pressure drop across the anode side of the stack using the measured pressure.
12. The system according to claim 11 further comprising a water separator for removing water from the recirculated gas, said controller calculating the pressure drop across the anode side of the stack by determining and using the pressure drop across the water separator.
13. The system according to claim 12 wherein the controller calculates the pressure drop across the anode side of the stack by determining and using the pressure drop across piping in the recirculation loop.
14. The system according to claim 13 wherein the controller calculates the pressure drop across the anode side of the stack by using the equation:
Δ p anode =(1 −c piping )·(Δ p pump −Δp separator )
where Δp anode is the pressure drop across the anode side of the stack, c piping is the pressure drop across the piping in the recirculation loop, Δp pump is the measured pressure drop across the pump and Δp separator is the pressure drop across the water separator.
15. The system according to claim 10 wherein the controller calculates the density of the recirculation gas flowing through the recirculation pump using the calculated volume flow, the measured pressure drop and the speed of the pump.
16. The system according to claim 15 wherein the controller calculates the density of the recirculation gas by the equation:
ρ
=
p
·
∑
n
i
·
M
W
i
nRT
=
p
·
∑
n
i
n
·
M
W
i
RT
where n is the speed of the pump, ρ is the density, p is the measured pressure, T is the measured temperature and MW is the molecular weight of the gas.
17. The system according to claim 15 wherein the controller calculates the percentage of hydrogen in the recirculation gas as a function of the density of the recirculation gas flowing through the recirculation pump, the measured temperature and the measured pressure.
18. The system according to claim 17 wherein the controller calculates an accurate value for the volume flow of the recirculation gas through the anode side of the stack and the percentage of hydrogen in the recirculation gas after a few cycles of calculating the percentage of hydrogen in the recirculation gas, calculating the volume flow of the recirculation gas of the anode side of the stack and calculating the density of the recirculation gas.
19. A fuel cell system comprising:
a fuel cell stack;
a recirculation loop for recirculating anode exhaust gas from the stack to an anode inlet;
a source of fresh hydrogen;
a mixing junction for mixing the fresh hydrogen with the recirculated gas;
a recirculation pump for pumping the recirculation gas through the recirculation loop;
a temperature sensor for measuring the temperature of the recirculation gas in the recirculation loop;
a pressure sensor for measuring the pressure drop across the recirculation pump; and
a controller programmed to control the speed of the pump to control the ratio of fresh hydrogen to recirculated hydrogen, said controller using a model to determine the speed of the pump based on the measured temperature of the anode recirculation gas in the recirculation loop, the measured pressure drop across the recirculation pump, the concentration of hydrogen in the recirculated gas, the volume flow of the recirculated gas through the stack, the pressure drop across the anode inlet and outlet of the stack and the density of the recirculated gas.
20. The system according to claim 19 further comprising a water separator for removing water from the recirculated gas, said controller calculating the pressure drop across the anode side of the stack using the pressure drop across the water separator, a pressure drop across piping in the recirculation loop and the measured pressure.