IP Library Patent Application 12143598
Patent Application
App. No. 12/143,598

CHROMATICALLY CORRECTED OBJECTIVE AND PROJECTION EXPOSURE APPARATUS INCLUDING THE SAME

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Patent No.
US None
App. No.
12/143,598
Abstract

An objective having a plurality of optical elements arranged to image a pattern from an object field in an object surface of the objective to an image field in an image surface region of the objective at an image-side numerical aperture NA>0.8 with electromagnetic radiation from a wavelength band around a wavelength λ, includes a number N of dioptric optical elements, each dioptric optical element i made from a transparent material having a normalized optical dispersion Δn i =n i (λ 0 )− n i (λ 0 +1 pm) for a wavelength variation of 1 pm from a wavelength λ 0 . The objective satisfies the relation  ∑ i = 1 N  Δ   n i  ( s i - d i )  λ 0  NA 4 ≤ A for any ray of an axial ray bundle originating from a field point on an optical axis in the object field, where s i is a geometrical path length of a ray in an ith dioptric optical element having axial thickness d i and the sum extends on all dioptric optical elements of the objective. Where A=0.2 or below, spherochromatism is sufficiently corrected

Claims (123)

1 . An objective comprising:

a plurality of optical elements arranged to image a pattern from an object field in an object surface of the objective to an image field in an image surface region of the objective at an image-side numerical aperture NA>0.8 with electromagnetic radiation from a wavelength band around a wavelength λ, the optical elements including a number N of dioptric optical elements, each dioptric optical element i made from a transparent material having a normalized optical dispersion

Δn i =n i (λ 0 )− n i (λ 0 +1 pm)

for a wavelength variation of 1 pm from a wavelength λ 0 , wherein the objective satisfies the relation

i

=

1

N

Δ

n

i

(

s

i

-

d

i

)

λ

0

NA

4

A

for any ray of an axial ray bundle originating from a field point on an optical axis in the object field;

where s i is a geometrical path length of a ray in an ith dioptric optical element having axial thickness d i and the sum extends on all dioptric optical elements of the objective, and where

A=0.2.

2 . The objective according to claim 1 , where A=0.1.

3 . The objective according to claim 1 , wherein dioptric optical elements in an image-side end portion of the objective adjacent to the image surface have a substantially aplanatic construction.

4 . The objective according to claim 1 , wherein the optical elements form:

a first objective part configured to image the pattern from the object surface into a first intermediate image, and having a first pupil surface;

a second objective part configured to image the first intermediate image into a second intermediate image, and having a second pupil surface optically conjugate to the first pupil surface,

a third objective part configured to image the second intermediate image into the image surface, and having a third pupil surface optically conjugate to the first and second pupil surface.

5 . The objective according to claim 4 , wherein a maximum value of pupil distortion, PD MAX =Max(D P ) within the third objective part is less than 20%, where a normalized pupil distortion D P =V/NA 3 and V is the pupil distortion at a maximum value of image-side NA for which the objective is sufficiently corrected, where V at a given position is given by a difference between an actual ray height RH and a paraxial ray height PRH, normalized by the paraxial ray height PRH according to V=(RH−PRH)/PRH.

6 . The objective according to claim 5 , wherein PD MAX <15%.

7 . The objective according to claim 4 , wherein the second objective part includes a concave mirror having a reflective mirror surface positioned at or close to the second pupil surface, and a lens group with negative refracting power immediately in front of the concave mirror and coaxial with the concave mirror and passed twice by radiation.

8 . The objective according to claim 4 , wherein an aperture stop defining an effective image side numerical aperture NA of the objective is arranged at the first pupil surface or at the second pupil surface.

9 . The objective according to claim 1 , wherein the objective includes a concave mirror arranged at or optically close to a pupil surface of the objective and a negative group comprising at least one negative lens arranged in front of the concave mirror on a reflecting side thereof in a double pass region such that radiation passes at least twice in opposite directions through the negative group.

10 . The objective according to claim 1 , wherein the objective is configured as an immersion objective with image-side numerical aperture NA≧1 when used in conjunction with an immersion liquid in an image-side working space between an exit surface of the objective and the image surface during operation.

11 . The objective according to claim 1 , wherein the objective has an immersion lens group having a convex object-side entry surface bounding at a gas or vacuum and an image-side exit surface in contact with an immersion liquid in operation, wherein the immersion lens group is at least partly made of a high-index material with refractive index n≧1.6 at the wavelength λ.

12 . The objective according to claim 11 , wherein the immersion lens group is a monolithic plano-convex lens made of the high-index material.

13 . The objective according to claim 12 , wherein the high-index material is chosen from the group consisting of aluminum oxide (Al 2 O 3 ), beryllium oxide (BeO), magnesium aluminum oxide (MgAlO 4 , spinell), yttrium aluminium oxide (Y 3 Al 5 O 12 ), yttrium oxide (Y 2 O 3 ), lanthanum fluoride (LaF 3 ), lutetium aluminium garnet (LuAG), magnesium oxide (MgO), calcium oxide (CaO), lithium barium fluoride (LiBaF 3 ).

14 . The objective according to claim 1 , wherein NA/n I >0.8, where NA is the image-side numerical aperture and n I is the refractive index of the image space.

15 . The objective according to claim 1 , wherein the objective has an image-side numerical aperture NA≧1.35.

16 . The objective according to claim 1 , wherein a maximum angle of incidence on an optical surface of an imaging objective part imaging a last intermediate image onto the image surface fulfills the condition sin(i MAX )<E*NA/n I , wherein NA is the image-side numerical aperture, n I is the refractive index in an image space, and E=0.95.

17 . The objective according to claim 1 , wherein the objective is a projection objective for microlithography.

18 . An objective comprising:

a plurality of optical elements arranged to image a pattern from an object field in an object surface of the objective to an image field in an image surface region of the objective at an image-side numerical aperture NA>0.8 with electromagnetic radiation from a wavelength band around a wavelength λ,

the optical elements including optical elements forming a focussing lens group imaging a field surface closest to the image surface onto the image surface,

wherein a maximum value of pupil distortion, PD MAX =Max(D P ) within the focusing lens group is less than 20%, where a normalized pupil distortion D P =V/NA 3 and V is the pupil distortion at a maximum value of image-side NA for which the objective is sufficiently corrected, where V at a given position is given by a difference between an actual ray height RH and a paraxial ray height PRH, normalized by the paraxial ray height PRH according to V=(RH−PRH)/PRH.

19 . The objective according to claim 18 , wherein PD MAX <15%.

20 . The objective according to claim 18 , wherein the optical elements include a number N of dioptric optical elements, each dioptric optical element i made from a transparent material having a normalized optical dispersion

Δn i =n i (λ 0 )− n i (λ 0 +1 pm)

for a wavelength variation of 1 pm from a wavelength λ 0 , wherein the objective satisfies the relation

i

=

1

N

Δ

n

i

(

s

i

-

d

i

)

λ

0

NA

4

A

for any ray of an axial ray bundle originating from a field point on an optical axis in the object field;

where s i is a geometrical path length of a ray in an ith dioptric optical element having axial thickness d i and the sum extends on all dioptric optical elements of the objective, and where

A=0.2.

21 . The objective according to claim 20 , wherein A=0.1.

22 . The objective according to claim 18 , wherein dioptric optical elements in an image-side end portion of the objective adjacent to the image surface have a substantially aplanatic construction.

23 . The objective according to claim 18 , wherein the optical elements form:

a first objective part configured to image the pattern from the object surface into a first intermediate image, and having a first pupil surface;

a second objective part configured to image the first intermediate image into a second intermediate image, and having a second pupil surface optically conjugate to the first pupil surface,

a third objective part configured to image the second intermediate image into the image surface, and having a third pupil surface optically conjugate to the first and second pupil surface.

24 . The objective according to claim 23 , wherein the second objective part includes a concave mirror having a reflective mirror surface positioned at or close to the second pupil surface, and a lens group with negative refracting power immediately in front of the concave mirror and coaxial with the concave mirror and passed twice by radiation.

25 . The objective according to claim 23 , wherein an aperture stop defining an effective image side numerical aperture NA of the objective is arranged at the first pupil surface or at the second pupil surface.

26 . The objective according to claim 18 , wherein the objective includes a concave mirror arranged at or optically close to a pupil surface of the objective and a negative group comprising at least one negative lens arranged in front of the concave mirror on a reflecting side thereof in a double pass region such that radiation passes at least twice in opposite directions through the negative group.

27 . The objective according to claim 18 , wherein the objective is configured as an immersion objective with image-side numerical aperture NA≧1 when used in conjunction with an immersion liquid in an image-side working space between an exit surface of the objective and the image surface during operation.

28 . The objective according to claim 18 , wherein the objective has an immersion lens group having a convex object-side entry surface bounding at a gas or vacuum and an image-side exit surface in contact with an immersion liquid in operation, wherein the immersion lens group is at least partly made of a high-index material with refractive index n≧1.6 at the wavelength λ.

29 . The objective according to claim 28 , wherein the immersion lens group is a monolithic plano-convex lens made of the high-index material.

30 . The objective according to claim 29 , wherein the high-index material is chosen from the group consisting of aluminum oxide (Al 2 O 3 ), beryllium oxide (BeO), magnesium aluminum oxide (MgAlO 4 , spinell), yttrium aluminium oxide (Y 3 Al 5 O 12 ), yttrium oxide (Y 2 O 3 ), lanthanum fluoride (LaF 3 ), lutetium aluminium garnet (LuAG), magnesium oxide (MgO), calcium oxide (CaO), lithium barium fluoride (LiBaF 3 ).

31 . The objective according to claim 18 , wherein NA/n I >0.8, where NA is the image-side numerical aperture and n I is the refractive index of the image space.

32 . The objective according to claim 18 , wherein the objective has an image-side numerical aperture NA≧1.35.

33 . The objective according to claim 18 , wherein a maximum angle of incidence on an optical surface of the focussing lens group fulfills the condition sin(i MAX )<E*NA/n I , wherein NA is the image-side numerical aperture, n I is the refractive index in an image space, and E=0.95.

34 . The objective according to claim 18 , wherein the objective is a projection objective for microlithography.

35 . A projection exposure apparatus configured to expose a radiation-sensitive substrate arranged in a region of an image surface of a projection objective with at least one image of a pattern of a mask that is arranged in a region of an object surface of the projection objective, comprising:

a radiation source emitting ultraviolet radiation from a wavelength band around a wavelength λ;

an illumination system receiving the radiation from the radiation source and shaping illumination radiation directed onto the pattern of the mask; and

a projection objective according to claim 1 .

36 . The projection exposure apparatus according to claim 35 , wherein λ<260 nm and wherein the Full Width at Half Maximum FWHM of the radiation source is greater than 0.5 pm.

37 . The projection exposure apparatus according to claim 36 , wherein the radiation source is a laser emitting at about λ=193 nm.

38 . The projection exposure apparatus according to claim 37 , wherein FWHM≧1 pm.

39 . A projection exposure apparatus configured to expose a radiation-sensitive substrate arranged in a region of an image surface of a projection objective with at least one image of a pattern of a mask that is arranged in a region of an object surface of the projection objective, comprising: a radiation source emitting ultraviolet radiation from a wavelength band around a wavelength λ;

an illumination system receiving the radiation from the radiation source and shaping illumination radiation directed onto the pattern of the mask; and

a projection objective according to claim 18 .

40 . The projection exposure apparatus according to claim 39 , wherein λ<260 nm and wherein the Full Width at Half Maximum FWHM of the radiation source is greater than 0.5 pm.

41 . The projection exposure apparatus according to claim 40 , wherein the radiation source is a laser emitting at about λ=193 nm.

42 . The projection exposure apparatus according to claim 41 , wherein FWHM≧1 pm.

Assignments (2)
A MODIFYING CONVERSION Recorded Jan 18, 2011
From: CARL ZEISS SMT AG
To: CARL ZEISS SMT GMBH
Reel/Frame 025763/0367 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 3, 2008
From: EPPLE, ALEXANDER; FELDMANN, HEIKO
To: CARL ZEISS SMT AG
Reel/Frame 021632/0325 →