The present invention pertains to an aqueous inkjet ink comprising pigment stabilized to dispersion with anionic dispersant, wherein cations present in the ink comprise a mixture, in a certain molar ratio, of lithium and one or more of sodium, potassium, rubidium and/or cesium. The inks exhibit greatly extended latency.
1. An ink-jet ink comprising an aqueous vehicle, a colorant, and a first and a second cationic species wherein:
i) said colorant comprises a pigment stabilized to a dispersion in said aqueous vehicle with an anionic polymeric dispersant;
ii) said first cationic species is Li + and has a molar concentration per unit weight of ink of M1;
iii) said second cationic species is any member or any combination of members selected from the group consisting of Na + , K + , Rb + and Cs + , and has a molar concentration per unit weight of ink of M2; and
iv) the molar ratio of the first cationic species to the total cation concentration (Mtot) satisfies equation 1 as follows:
0.20 <M 1 /Mtot< 0.45 (eq. 1)
wherein Mtot is the cumulative molar concentration of the first and second cationic species per unit weight of ink (Mtot=M1+M2).
2. The ink of claim 1 further comprising a first humectant consisting of 2-pyrrolidone and a second humectant selected from any member or combination of members of the group consisting of ethylene glycol, diethylene glycol and triethylene glycol.
3. The inkjet ink of claim 1 wherein the pH is greater than about 6.5.
4. The ink of claim 1 wherein the anionic dispersant is comprised of anionic moieties consisting essentially of carboxyl groups.
5. An ink according to any of claims 1 - 4 wherein the second cationic species is predominately K + .
6. The ink of claim 1 further comprising ammonium cations.
7. The ink of claim 1 characterized in that the decap time is equal to or longer than 40 seconds, wherein the decap time is defined as the amount of time an inkjet printhead, loaded with an ink, can be left uncapped and idle and still fire a drop of that ink without misdirection, loss of color or unacceptable decrease of velocity.
8. The ink of claim 2 comprising first humectant in a range of about 2 wt % to about 30 wt % and second humectant in the range of about 2 wt % to about 30 wt %, the percentages being based on the total weight of ink.
9. An inkjet ink according to any of the preceding claims wherein the colorant consists essentially of pigment stabilized to dispersion in the aqueous vehicle with an anionic dispersant.
10. The inkjet ink according to any of the preceding claims wherein the colorant is carbon black pigment.