Use of polyolefin waxes in hot melt road marking compositions
The invention relates to hot melt compositions comprising polyolefin waxes prepared using metallocene catalysts, have a dropping point or ring & ball softening point of between 80 and 165° C., have a melt viscosity, measured at a temperature of 170° C., of between 20 and 40 000 mPa·s, and have a glass transition temperature of not more than −10° C. and also to their use as hot melt adhesives and as binders for producing roadmarkings.
1. A hot melt road marking composition comprising
a. 20 to 90% by weight of one or more polyolefin waxes prepared using metallocene catalysts, have a dropping point or ring & ball softening point of between 80 and 165° C., have a melt viscosity, measured at a temperature of 170° C., of between 20 and 40 000 mPa·s, and have a glass transition temperature of not more than −10° C.,
b. a component selected from the group consisting of a polyolefin polymer, a polar polymer, an apolar polymer, a plasticizer, an antioxidant, a stabilizer, and mixtures thereof,
c. a further component selected from the group consisting of a filler, a pigment, a light reflecting adjuvant and mixtures thereof,
wherein the one or more polyolefin waxes prepared using metallocene catalysts are not polar modified.
2. The hot melt road marking composition as claimed in claim 1 , wherein the one or more polyolefin waxes have a dropping point or ring & ball softening point of between 90 and 160° C., a melt viscosity, measured at a temperature of 170° C., of between 50 and 30 000 mPa·s, and a glass transition temperature of not more than −20° C.
3. The hot melt road marking composition as claimed in claim 1 , wherein the one or more polyolefin waxes have a number-average molar mass M n of between 500 and 20 000 g/mol, and a weight-average molar mass M w of between 1000 and 40 000 g/mol.
4. The hot melt road marking composition as claimed in claim 1 , wherein the one or more polyolefin waxes are propylene homopolymer waxes.
5. The hot melt road marking composition as claimed in claim 1 , wherein the one or more polyolefin waxes are copolymer waxes of propylene and one or more further monomers selected from the group consisting of ethylene and branched or unbranched 1-alkenes having 4 to 20 carbon atoms and the amount of structural units originating from propylene in the copolymer waxes is from 70 to 99.9% by weight.
6. The hot melt road marking composition as claimed in claim 1 , wherein the one or more polyolefin waxes are copolymer waxes of ethylene and at least one branched or unbranched 1-alkene having 3 to 20 carbon atoms and the amount of structural units originating from the one or more 1-alkenes in the copolymer waxes is from 0.1% to 30% by weight.
7. The hot melt road marking composition as claimed in claim 1 , wherein the one or more polyolefin waxes are present in the hot melt road marking composition in fractions of between 50% and 99% by weight.
8. The hot melt road marking composition as claimed in claim 1 , wherein the one or more polyolefin waxes are present in the hot melt road marking composition in fractions of between 60% and 90% by weight.
9. The hot melt road marking composition as claimed in claim 5 , wherein the copolymer waxes of propylene and one or more further monomers selected from the group consisting of ethylene and branched or unbranched 1-alkenes having 4 to 20 carbon atoms waxes have undergone polar modification.
10. The hot melt road marking composition as claimed in claim 6 , wherein the copolymer waxes of ethylene and at least one branched or unbranched 1-alkene having 3 to 20 carbon atoms have undergone polar modification.