Easy-open end
An easy-open end which is excellent from the standpoint of sanitation and environmental friendliness yet satisfying both the close adhesion and the scratch resistance despite of using a bisphenol A-free primer. The easy-open end has a polyester film applied, via a primer, onto the inner surface of the end of an aluminum base sheet forming a surface-treating layer that contains a zirconium compound and/or a titanium compound and an organic compound, wherein the primer contains a polyester resin that contains not less than 30% by weight of a carboxyl group-introduced polyester resin, and a phenol resin at a weight ratio of 50:50 to 85:15.
1. An easy-open end having a score and a rivet, and having a polyester film applied, via a primer, onto an inner surface of an end of an aluminum base sheet on which a surface-treating layer has been formed, said surface-treating layer containing a zirconium compound and/or a titanium compound and an organic compound,
wherein said primer is composed of a polyester resin and a phenol resin in the range from a weight ratio of polyester resin:phenol resin of 50:50 to 85:15, said polyester resin containing not less than 30% by weight of a carboxyl group-introduced polyester resin based on the weight of the polyester resin, said carboxyl group-introduced polyester resin is obtained by a ring-opening addition reaction of a compound having a carboxylic anhydride group with a polyester resin, the compound having a carboxylic anhydride group comprises carboxylic polyanhydride, and said carboxyl group-introduced polyester resin has not less than two carboxylic anhydride groups on a molecule thereof.
2. The easy-open end according to claim 1 , wherein said carboxyl group-introduced polyester resin has an acid value of 150 to 800 meq/kg.
3. The easy-open end according to claim 1 , wherein said phenol resin is an m-cresol resole phenol resin.
4. The easy-open end according to claim 1 , wherein said surface-treating layer is an organic/inorganic composite surface-treating layer containing the zirconium compound in an amount of 2 to 20 mg/m 2 calculated as zirconium atoms, a phosphorus compound in an amount of 1 to 10 mg/m 2 calculated as phosphorus atoms, and the organic compound in an amount of 5 to 60 mg/m 2 calculated as carbon atoms, said organic compound is an organic polymer having a structural unit represented by the following formula (1),
wherein φ is a benzene ring, and X is a hydrogen atom
or a group Z represented by the following formula (2),
wherein R 1 and R 2 are hydrogen atoms, alkyl groups having 1 to 10 carbon atoms or hydroxyalkyl groups having 1 to 10 carbon atoms,
the introduction ratio of the groups Z being 0.3 to 1.0 groups per a benzene ring,
and when Xs are all hydrogen atoms, said organic polymer has an average molecular weight of 1,000 to 100,000.
5. The easy-open end according to claim 1 , wherein said surface-treating layer is an organic/inorganic composite surface-treating layer containing the zirconium compound and/or the titanium compound in an amount of 4 to 30 mg/m 2 calculated as zirconium atoms and/or titanium atoms, an organic phosphonic acid compound in an amount of 0.2 to 9 mg/m 2 calculated as phosphorus atoms, and a tannin in an amount of 2 to 90 mg/m 2 calculated as carbon atoms.