Peroxide-cured thermoplastic vulcanizates prepared with ultrahigh molecular weight plastics
A thermoplastic vulcanizate comprising a dynamically cured rubber, where the rubber is peroxide cured, and a thermoplastic phase, where at least 10% by weight of the thermoplastic phase includes an ultrahigh molecular weight plastic, where the ultrahigh molecular weight plastic is characterized by a M w that is greater than 0.8×10 6 g/mole.
1. A thermoplastic vulcanizate comprising:
a dynamically cured rubber, where the rubber is fully cured by a peroxide; and
a thermoplastic phase, where 100% by weight of the thermoplastic phase includes an ultrahigh molecular weight plastic, where the ultrahigh molecular weight plastic is a propylene-based polymer including greater than 90 mole percent propylene mer units and is characterized by a weight average molecular weight (M w ) that is from 3.0×10 6 to 3,968×10 6 g/mole, a molecular weight distribution (Mw/Mn) of from 2.5 to less than 5, stereo defects of less than 50 per 10,000 carbon atoms, and a meso pentad fraction of greater than 96 mole % mmmm pentads,
wherein the rubber is dynamically cured in the presence of the ultrahigh molecular weight plastic.
2. The thermoplastic vulcanizate of claim 1 , where the ultrahigh molecular weight plastic is characterized by a number average molecular weight (M n ) that is greater than 0.4×10 6 g/mole.
3. The thermoplastic vulcanizate of claim 1 , where the ultrahigh molecular weight plastic is characterized by a number average molecular weight (M n ) that is greater than 0.9×10 6 g/mole.
4. The thermoplastic vulcanizate of claim 1 , where the ultrahigh molecular weight plastic is characterized by an intrinsic viscosity that is greater than about 11 dl/g as determined according to ASTM D-1601-78.
5. The thermoplastic vulcanizate of claim 1 , where the ultrahigh molecular weight plastic is characterized by a heat of fusion (H f ) that is at least 86 J/g as determined by DSC, where the ultrahigh molecular weight plastic is characterized by a melting temperature (T m ) that is at least 160° C. as determined by DSC.
6. The thermoplastic vulcanizate of claim 1 , where the ultrahigh molecular weight plastic is characterized by an MFR at 230° C. and 2.16 kg load of less than 0.05 dg/min as determined according to ASTM D-1238-04.
7. The thermoplastic vulcanizate of claim 4 , where the ultrahigh molecular weight plastic is characterized by an MFR at 230° C. and 2.16 kg load of less than 0.03 dg/min as determined according to ASTM D-1238-04.
8. The thermoplastic vulcanizate of claim 5 , where the ultrahigh molecular weight plastic is characterized by an MFR at 230° C. and 2.16 kg load of less than 0.01 dg/min as determined according to ASTM D-1238-04.
9. The thermoplastic vulcanizate of claim 1 , where the dynamically cured rubber includes dynamically cured ethylene-propylene rubber and dynamically cured propylene-based rubbery copolymer.
10. A thermoplastic vulcanizate prepared by a process comprising:
dynamically vulcanizing a rubber with a peroxide curative in the presence of a thermoplastic resin included 100% of an ultrahigh molecular weight plastic, based on the weight of the thermoplastic resin, where the ultrahigh molecular weight plastic is a propylene-based polymer characterized by a weight average molecular weight (M w ) that is from 3.0×10 6 to 3,968×10 6 g/mole and a number average molecular weight(M n ) that is greater than 0.2×10 6 g/mole, a molecular weight distribution (Mw/Mn) of from 2.5 to less than 5, stereo defects of less than 50 per 10,000 carbon atoms, a meso pentad fraction of greater than 96 mole % mmmm pentads, and including greater than 90 mole percent propylene mer units, where said step of dynamically vulcanizing the rubber causes the thermoplastic resin to become a contiuous phase of the thermoplastic vulcanizate; and
to thereby produce the thermoplastic vulcanizate including (a) the dynamically cured rubber, where the rubber is fully cured by the peroxide, and (b) the thermoplastic phase, where 100% by weight of the thermoplastic phase includes the ultrahigh molecular weight plastic, where the ultrahigh molecular weight plastic is the propylene-based polymer including greater than 90 mole percent propylene mer units characterized by a M w that is from 3.0×10 6 to 3,968×10 6 g/mole an M n that is greater than 0.2×10 6 g/mole, and a molecular weight distribution (Mw/Mn) of from 2.5 to less than 5, stereo defects of less than 50 per 10,000 carbon atoms, and a meso pentad fraction of greater than 96 mole % mmmm pentads.