Incorporation of nitrogen into high k dielectric film
View Patent ↗A high k dielectric film and methods for forming the same are disclosed. The high k material includes two peaks of impurity concentration, particularly nitrogen, such as at a lower interface and upper interface, making the layer particularly suitable for transistor gate dielectric applications. The methods of formation include low temperature processes, particularly CVD using a remote plasma generator and atomic layer deposition using selective incorporation of nitrogen in the cyclic process. Advantageously, nitrogen levels are tailored during the deposition process and temperatures are low enough to avoid interdiffusion and allow maintenance of the desired impurity profile.
1. A gate dielectric layer in an integrated circuit comprising a graded concentration of aluminum, the dielectric comprising a lower interface having a first aluminum concentration, a bulk portion having a second aluminum concentration lower than the first aluminum concentration and an upper interface having a third aluminum concentration higher than the second aluminum concentration.
2. The dielectric layer of claim 1 , which comprises zirconium oxide with a graded concentration of aluminum.
3. The dielectric layer of claim 1 , which comprises hafnium oxide with a graded concentration of aluminum.
4. The dielectric layer of claim 1 , which is less than 7 nm thick.
5. The dielectric layer of claim 1 , wherein the bulk portion comprises substantially pure zirconium oxide.