Thermally stable subsea control hydraulic fluid compositions
View Patent ↗An aqueous hydraulic fluid composition comprising of one or more lubricants such as a monovalent metal salt, ammonium, or alkanolamine salt of a dicarboxylic acid, such as a C21 dicarboxylic acid is described in which the aqueous hydraulic fluid composition demonstrates increased thermal stability when exposed to elevated temperatures for a prolonged period of time while being able to tolerate the presence of 10% v/v synthetic seawater. The aqueous hydraulic fluid composition contains less than about 20% by weight (preferably none or substantially none) of an oil selected from the group consisting of mineral oils, synthetic hydrocarbon oils, and mixtures thereof.
1. An aqueous hydraulic fluid composition comprising:
a lubricant comprising at least one monovalent metal, ammonium, or alkanolamine salt of a dicarboxylic acid;
an additional lubricant comprising a metal or alkanolamine salt of a mono, di, tri or polymeric alkoxylate;
wherein the hydraulic fluid composition is at least substantially free of an oil selected from the group consisting of mineral oils, synthetic hydrocarbon oils, and mixtures thereof.
2. The aqueous hydraulic fluid composition according to claim 1 , wherein the composition comprises water in an amount between about 10% and about 65% by weight based on the total weight of the hydraulic fluid composition.
3. The aqueous hydraulic fluid composition according to claim 1 , wherein the dicarboxylic acid comprises a C21 dicarboxylic acid converted to a salt with a monovalent metal, ammonia, or alkanolamine.
4. The aqueous hydraulic fluid composition according to claim 3 , wherein the salt of the dicarboxylic acid is a dipotassium salt of the C21 dicarboxylic acid or an alkanolamine salt of the C21 dicarboxylic acid.
5. The aqueous hydraulic fluid composition according to claim 1 , further comprising a second lubricant, said second lubricant selected from the group consisting of alkyl/aryl phosphate esters, alkyl/aryl phosphite esters, phospholipids, carboxylic acids, salts of carboxylic acids, and combinations of the foregoing.
6. The aqueous hydraulic fluid composition according to claim 5 , wherein the phospholipid comprises a phosphatide selected from the group consisting of phosphatidylcholine, phosphatidylinositol, phosphatidylserien, phosphatidylethanolamine and combinations of one or more of the foregoing.
7. The aqueous hydraulic fluid composition according to claim 1 , wherein the composition further comprises a biocide.
8. The aqueous hydraulic fluid composition according to claim 7 , wherein the biocide is selected from the group consisting of a boron containing salt, such as borax decahydrate, a sulfur-containing biocide or a nitrogen-containing biocide. Nitrogen-containing biocides include gluteraldehyde, triazines, oxazolidines, and guanidines as well as compounds selected from fatty acid quaternary ammonium salts, such as didecyl dimethyl quaternary ammonium chloride salt.
9. The aqueous hydraulic fluid composition according to claim 1 , wherein the composition further comprises of one or more corrosion inhibitors.
10. The aqueous hydraulic fluid composition according to claim 9 , wherein the corrosion inhibitor is selected from the group consisting of alkyl/aryl phosphate esters, alkyl/aryl phosphite esters, phospholipids, carboxylic acids, salts of carboxylic acids, and combinations of the foregoing.
11. The aqueous hydraulic fluid composition according to claim 5 , wherein the composition further comprises an anti-freeze additive.
12. The aqueous hydraulic fluid composition according to claim 11 , wherein the anti-freeze additive is selected from the group consisting of monoethylene glycol, glycerol, propylene glycol, 2-butene-1,4-diol, polyethylene glycols and polypropylene glycols.
13. The aqueous hydraulic fluid composition according to claim 11 , wherein the anti-freeze additive is monoethylene glycol.
14. The aqueous hydraulic fluid composition according to claim 1 , wherein the dicarboxylic acid comprises 2-cyclohexene-1-octanoic-5-carboxy-4-hexyl.