Nitrated extreme pressure additives and blends
This invention relates to products useful in friction-reducing extreme-pressure lubricating applications such as internal combustion engines, gear oils and applications which involve rubbing metallic moving parts. The invention includes additive blends and a process of using synergistic combinations of nitro compounds with non-chlorine containing additives such as sulfur-containing moieties and phosphorus-containing moieties.
1. A process for reducing friction in an oil-lubricated application using a blend of at least one nitrated moiety with at least one other moiety containing sulfur, phosphorus or combinations thereof comprising the steps of:
adding to an hydrocarbon oil of lubricating viscosity from about 2% to 75% by weight of an additive comprising:
at least one nitrated soybean oil, formed by reacting with a nitrating agent selected from the group consisting of nitric acid and nitrogen dioxide, and
adding at least one non-chlorine containing moiety to said additive, a combination of said non-chlorine containing moiety and said nitrated soybean oil, improving a performance of said additive in at least one physical characteristic when compared to using said additive without said combination,
said at least one non-chlorine containing moiety selected from the group consisting of a sulfur-containing moiety, a phosphorus-containing moiety and a moiety containing both sulfur and phosphorus, and further wherein
said sulfur-containing moiety comprises at least one of an alkyl sulfamate, an alkyl sulfonate and a polysulfide and wherein
said phosphorus-containing moiety comprises at least one of a phosphate ester and an phosphite and wherein
said moiety containing both sulfur and phosphorus comprises at least one of a thiophosphate, a zinc thiophosphate and a zinc dithiophosphate.
2. A process for reducing friction in an oil-lubricated application using a blend of at least one nitrated moiety with at least one other moiety containing sulfur, phosphorus or combinations thereof comprising the steps of:
adding to an hydrocarbon oil of lubricating viscosity from about 2% to 75% by weight of an additive comprising:
at least one nitrated reaction product of an ester blend of a polyol and an unsaturated fatty acid, formed by reacting with a nitrating agent selected from the group consisting of nitric acid and nitrogen dioxide, and
adding at least one non-chlorine containing moiety to said additive, a combination of said non-chlorine containing moiety and said at least one nitrated reaction product of an ester blend of a polyol and an unsaturated fatty acid, improving a performance of said additive in at least one physical characteristic when compared to using said additive without said combination,
said at least one non-chlorine containing moiety selected from the group consisting of a sulfur-containing moiety, a phosphorus-containing moiety and a moiety containing both sulfur and phosphorus, and further wherein
said sulfur-containing moiety comprises at least one of an alkyl sulfamate, an alkyl sulfonate and a polysulfide and wherein
said phosphorus-containing moiety comprises at least one of a phosphate ester and a phosphite and wherein
said moiety containing both sulfur and phosphorus comprises at least one of a thiophosphate, a zinc thiophosphate and a zinc dithiophosphate.
3. A process for reducing friction in an oil-lubricated application using a blend of at least one nitrated moiety with at least one other moiety containing sulfur, phosphorus or combinations thereof comprising the steps of:
adding to an hydrocarbon oil of lubricating viscosity from about 2% to 75% by weight of an additive comprising:
at least one nitrated unsaturated fatty acid formed by reacting with a nitrating agent selected from the group consisting of nitric acid and nitrogen dioxide, and
adding at least one non-chlorine containing moiety to said additive, a combination of said non-chlorine containing moiety and said nitrated unsaturated fatty acid, improving a performance of said additive in at least one physical characteristic when compared to using said additive without said combination,
said at least one non-chlorine containing moiety selected from the group consisting of a sulfur-containing moiety, a phosphorus-containing moiety and a moiety containing both sulfur and phosphorus, and further wherein
said sulfur-containing moiety comprises at least one of an alkyl sulfamate, an alkyl sulfonate and a polysulfide and wherein
said phosphorus-containing moiety comprises at least one of a phosphate ester and a phosphite and wherein
said moiety containing both sulfur and phosphorus comprises at least one of a thiophosphate, a zinc thiophosphate and a zinc dithiophosphate.