System and method for extracting base metal values from oxide ores
A method for recovering base metal values from oxide ore is provided by the present disclosure. The ore includes a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper. The method includes the steps of: contacting the oxide ore with hydrogen chloride gas to obtain chlorides of the first and second metals and subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides. The method also includes the step of mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal and recovering the dissolved ions of the second metal from the aqueous solution.
1. A method for recovering base metal values from oxide ore including a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper, the method comprising the steps of:
contacting the oxide ore with hydrogen chloride to obtain chlorides of the first and second metals;
subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides;
mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal; and
recovering the dissolved ions of the second metal from the aqueous solution,
wherein the steps of contacting the oxide ore with hydrogen chloride, subjecting at least the first and second metals to pyrohydrolysis, mixing the oxides of the first metal and the chlorides of the second metal, and recovering the dissolved ions of the second metal from the aqueous solution are performed in a resin-free environment.
2. The method according to claim 1 , wherein the oxide ore is laterite ore.
3. The method according to claim 1 , further comprising the step of granulating the oxide ore to at least a first particle size.
4. The method according to claim 3 , wherein the first particle size is from about 0.5 mm to about 50 mm.
5. The method according to claim 1 , wherein the contacting step further comprises the step of:contacting the oxide ore with gaseous hydrogen chloride flux.
6. The method according to claim 1 , further comprising the step of:drying the oxide ore at a temperature from about 60° C. to about 150° C.
7. The method according to claim 1 , wherein the predetermined temperature is from about 25° C. to about 600° C.
8. The method according to claim 1 , wherein the pH of the aqueous solution is from about 1.0 to about 5.0.
9. The method according to claim 8 , wherein the aqueous solution is maintained at a temperature from about 15° C. to about 100° C.
10. The method according to claim 1 , wherein the mixing step is performed for a period from about 0.2 hours to about 10 hours.
11. The method according to claim 1 , further comprising the step of regenerating hydrochloric acid and reusing the regenerated hydrochloric acid in the contacting the oxide ore step.
12. A method for treating a laterite ore comprising a nickel oxide and at least one base metal oxide, the method comprising the steps of
contacting the laterite ore with gaseous hydrogen chloride to obtain a nickel chloride and at least one base metal chloride;
subjecting the nickel chloride and at least one base metal chloride to pyrohydrolysis to decompose the at least one base metal chloride into at least one base metal oxide;
mixing the nickel chloride and the at least one metal oxide in an aqueous solution to dissolve the nickel chloride; and
recovering the dissolved ions of the nickel chloride from the aqueous solution,
wherein the steps of contacting the oxide ore with hydrogen chloride, subjecting at least the first and second metals to pyrohydrolysis, mixing the oxides of the first metal and the chlorides of the second metal, and recovering the dissolved ions of the second metal from the aqueous solution are performed in a resin-free environment.
13. The method according to claim 12 , wherein the pH of the aqueous solution is from about 1.0 to about 5.0.
14. The method according to claim 13 , wherein the aqueous solution is maintained at a temperature from about 15° C. to about 100° C.
15. The method according to claim 12 , wherein the mixing step is performed for a period from about 0.2 hours to about 10 hours.
16. The method according to claim 12 , further comprising the step of regenerating hydrochloric acid and reusing the regenerated hydrochloric acid in the contacting the oxide ore step.
17. The method according to claim 1 , wherein subjecting at least the first and second metals to pyrohydrolysis is only performed after contacting the oxide ore with hydrogen chloride.
18. The method according to claim 12 , wherein subjecting the nickel chloride and the at least one base metal chloride to pyrohydrolysis is only performed after contacting the oxide ore with hydrogen chloride.