METHOD FOR FORMING CURED FILM
The invention provides a method for forming a cured film, comprising discharging an ink-jet ink, which comprises predetermined compounds, whose viscosity at 25° C. is approximately 150 to approximately 3,000 mPa·s, from an ink-jet head at a discharging temperature of approximately 80 to approximately 150° C., which has a low degree of spread of an ink-jet ink after landing, and which is able to form a highly-fine pattern.
1 . A method for forming a cured film comprising:
discharging an ink-jet ink,
wherein the ink-jet ink comprises at least one compound selected from the group consisting of compounds represented by general formula (1) and compounds represented by general formula (2), and
wherein the ink-jet ink has a viscosity at 25° C. of approximately 150 mPa·s to approximately 3,000 mPa·s,
from an ink-jet head at a discharging temperature of approximately 80° C. to approximately 150° C.,
wherein in the formula (1), R 1 is an organic group having 1 to 100 carbon atoms; R 2 and R 3 are each independently alkyl having 1 to 20 carbon atoms, phenyl, phenyl in which any hydrogen is replaced by alkyl having 1 to 5 carbon atoms, or phenyl in which any hydrogen is replaced by phenyl, wherein R 2 and R 3 may bind to each other to form a cyclic group(s); n is an integer from 1 to 10; and p and q are each independently 0 or 1, and
wherein in the formula (2), R 4 is hydrogen or methyl; R 5 is alkylene having 2 to 20 carbon atoms which may have a cyclic structure(s); and t is an integer from 1 to 30.
2 . The method for forming a cured film of claim 1 ,
wherein the ink-jet ink comprises at least one compound selected from compounds represented by the general formula (1) and at least one compound selected from compounds represented by the general formula (2).
3 . A method for forming a cured film comprising:
discharging an ink-jet ink,
wherein the ink-jet ink comprises at least one compound selected from the group consisting of compounds represented by general formula (3) and compounds represented by general formula (4), and
wherein the ink-jet ink has a viscosity at 25° C. of approximately 150 mPa·s to approximately 3,000 mPa·s,
from an ink-jet head at a discharging temperature of approximately 80° C. to approximately 150° C.,
wherein in the formula (3), R 1 is an organic group having 1 to 100 carbon atoms; and n is an integer from 1 to 10, and
wherein in the formula (4), R 4 is hydrogen or methyl; and R 5 is alkylene having 2 to 8 carbon atoms which may have a cyclic structure(s).
4 . The method for forming a cured film of claim 3 ,
wherein the ink-jet ink comprises at least one compound selected from compounds represented by the general formula (3) and at least one compound selected from compounds represented by the general formula (4).
5 . The method for forming a cured film of claim 1 , wherein the ink-jet ink further comprises a photopolymerization initiator.
6 . The method for forming a cured film of claim 5 , wherein the ink-jet ink comprises a solvent, wherein the solvent has a boiling point under ordinary pressure of approximately 300° C. or lower, and wherein the solvent is approximately 0 wt % to approximately 10 wt % based on total weight of the ink-jet ink.
7 . The method for forming a cured film of claim 5 , wherein the photopolymerization initiator is selected from the group consisting of bis(2,4,6-trimethylbenzoyl)phenylphosphineoxide and 2,4,6-trimethylbenzoyldiphenylphosphineoxide.
8 . (canceled)
9 . The method for forming a cured film of claim 1 , wherein R 1 is an organic group having 1 to 100 carbon atoms which has a radical polymerizable double bond.
10 . The method for forming a cured film of claim 1 , wherein R 5 is ethylene, propylene or butylene.
11 . The method for forming a cured film of claim 3 , wherein the compounds represented by the general formula (3) are selected from the group consisting of compounds represented by general formula (5), (6), (7) and (8),
wherein in the formula (5), a, b and c are each independently an integer from 0 to 10; 1 or 2 of three R 6 s are a group represented by the formula (5-1), and the remaining R 6 (s) is a group represented by the formula (5-2); and R 7 is hydrogen or methyl,
wherein in the formula (6), a, b and c are each independently an integer from 0 to 10; 1 or 2 of three R 6 s are a group represented by the formula (6-1), and the remaining R 6 (s) is a group represented by the formula (6-2); and R 7 is hydrogen or methyl,
wherein in the formula (7), a, b, c and d are each independently an integer from 0 to 10; 1 to 3 of four R 6 s are a group represented by the formula (7-1), and the remaining R 6 (s) is a group represented by the formula (7-2); and R 7 is hydrogen or methyl, and
wherein in the formula (8), a, b, c, d, e and f are each independently an integer from 0 to 10; 1 to 5 of six R 6 s are a group represented by the formula (8-1), and the remaining R 6 (s) is a group represented by the formula (8-2); and R 7 is hydrogen or methyl.
12 . The method for forming a cured film of claim 1 , wherein the viscosity of the ink-jet ink at 25° C. is approximately 150 to approximately 300 mPa·s.
13 . The method for forming a cured film of claim 1 , wherein the discharging temperature is approximately 90 to approximately 140° C.
14 . (canceled)
15 . A cured film formed using the method for forming a cured film of claim 1 .
16 . A patterned cured film formed using the method for forming a cured film of claim 1 .
17 . An electronic circuit substrate in which the cured film of 15 is formed on a substrate.
18 . An electronic component having the electronic circuit substrate of claim 17 .
19 . The method for forming a cured film of claim 3 , wherein the ink-jet ink further comprises a photopolymerization initiator.
20 . The method for forming a cured film of claim 19 , wherein the ink-jet ink comprises a solvent, wherein the solvent has a boiling point under ordinary pressure of approximately 300° C. or lower, and wherein the solvent is approximately 0 wt % to approximately 10 wt % based on total weight of the ink-jet ink.
21 . The method for forming a cured film of claim 3 , wherein R 1 is an organic group having 1 to 100 carbon atoms which has a radical polymerizable double bond.
22 . The method for forming a cured film of claim 3 , wherein R 5 is ethylene, propylene or butylene.
23 . The method for forming a cured film of claim 3 , wherein the viscosity of the ink-jet ink at 25° C. is approximately 150 to approximately 300 mPa·s.
24 . The method for forming a cured film of claim 3 , wherein the discharging temperature is approximately 90 to approximately 140° C.
25 . A cured film formed using the method for forming a cured film of claim 3 .
26 . A patterned cured film formed using the method for forming a cured film of claim 3 .
27 . An electronic circuit substrate in which the cured film according to claim 25 is formed on a substrate.
28 . An electronic component having the electronic circuit substrate according to claim 27 .
29 . The method for forming a cured film of claim 6 ,
wherein the ink-jet ink comprises ingredients where;
the total weight of the compounds is approximately 50 wt % to approximately 100 wt %, wherein the compounds are selected from the group consisting of compounds represented by the general formula (1) and represented by the general formula (2), and compounds represented by the general formula (3) and represented by the general formula (4);
the weight of the solvent is approximately 0 wt % to approximately 10 wt %;
the weight of the photopolymerization initiator is approximately 0 wt % to approximately 20 wt %; and
the total weight of a different radical polymerizable monomer and a compound selected from the group consisting of compounds having two or more oxiranes or oxetanes is approximately 0 wt % to approximately 50 wt %,
based on the whole weight of the ink-jet ink.