IP Library Granted Patent US 9,269,906
Granted Patent B2
US 9,269,906 · App. 12/206,252 · Granted Feb 23, 2016

Light-emitting element, light-emitting device, and electronic device

Inventors: Tsunenori Suzuki (Kanagawa, JP); Satoko Shitagaki (Kanagawa, JP); Satoshi Seo (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L51/0059H01L51/006H01L51/0031H01L51/0072H01L51/001H01L51/007H01L51/0081H01L51/5052H01L2251/308
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Quick Facts
Patent No.
US 9,269,906
App. No.
12/206,252
Granted
Feb 23, 2016
Kind
B2
Abstract

It is an object to provide a light-emitting element having long lifetime. A light-emitting element is provided, in which a light-emitting layer, a first layer, and a second layer are provided between a first electrode and a second electrode; the first layer is provided between the light-emitting layer and the first electrode; the second layer is provided between the light-emitting layer and the second electrode; the first layer is a layer for controlling the hole transport; the second layer is a layer for controlling the electron transport; and light emission is obtained from the light-emitting layer by applying voltage to the first electrode and the second electrode such that the potential of the first electrode is higher than that of the second electrode.

Claims (97)

1. A light-emitting element comprising:

a first electrode;

a hole-transporting layer over the first electrode;

a light-emitting layer over the hole-transporting layer;

an electron-transporting layer over the light-emitting layer;

a second electrode over the electron-transporting layer;

a first layer between the first electrode and the hole-transporting layer; and

a second layer between the light-emitting layer and the electron-transporting layer,

wherein the first layer comprises a first organic compound having a hole-transporting property and a second organic compound having an electron-transporting property,

wherein the second layer comprises a third organic compound having an electron-transporting property and a fourth organic compound having a hole-transporting property,

wherein the light-emitting layer consists essentially of a host material and a light-emitting material,

wherein the light-emitting material is a first phosphorescent compound,

wherein the host material is different from the third organic compound,

wherein the fourth organic compound is a second phosphorescent compound different from the first phosphorescent compound, and

wherein the hole-transporting layer consists essentially of the first organic compound.

2. The light-emitting element according to claim 1 , wherein the second organic compound is any one of an oxadiazole derivative, a triazole derivative, and a phenanthroline derivative.

3. The light-emitting element according to claim 1 , wherein a concentration of the second organic compound in the first layer is greater than or equal to 1 wt % and less than or equal to 20 wt %.

4. The light-emitting element according to claim 1 , wherein a thickness of the first layer is greater than or equal to 1 nm and less than or equal to 20 nm.

5. The light-emitting element according to claim 1 , wherein a concentration of the fourth organic compound in the second layer is greater than or equal to 0.1 wt % and less than or equal to 5 wt %.

6. The light-emitting element according to claim 1 , wherein the second organic compound decreases a hole-transporting property of the first layer.

7. The light-emitting element according to claim 1 , wherein the third organic compound is a metal complex.

8. The light-emitting element according to claim 1 , wherein the second organic compound has a molecular structure having a heterocyclic.

9. The light-emitting element according to claim 1 , wherein the fourth organic compound decreases an electron-transporting property of the second layer.

10. The light-emitting element according to claim 1 , wherein the second organic compound is a substance to which a hole is not injected.

11. The light-emitting element according to claim 1 , wherein a thickness of the second layer is greater than or equal to 5 nm and less than or equal to 20 nm.

12. The light-emitting element according to claim 1 ,

wherein the first layer is in contact with the hole-transporting layer, and

wherein the second layer is in contact with the light-emitting layer and the electron-transporting layer.

13. A light-emitting device comprising the light-emitting element according to claim 1 and a control unit configured to control light emission of the light-emitting element.

14. An electronic device comprising a display portion, the display portion comprising the light-emitting element according to claim 1 and a control unit configured to control light emission of the light-emitting element.

15. A light-emitting element comprising:

a first electrode;

a hole injection layer over the first electrode;

a hole-transporting layer over the hole injection layer;

a light-emitting layer over the hole-transporting layer;

an electron-transporting layer over the light-emitting layer;

a second electrode over the electron-transporting layer;

a first layer between the hole injection layer and the hole-transporting layer; and

a second layer between the light-emitting layer and the electron-transporting layer,

wherein the first layer comprises a first organic compound having a hole-transporting property and a second organic compound having an electron-transporting property,

wherein the second layer comprises a third organic compound having an electron-transporting property and a fourth organic compound having a hole-transporting property,

wherein the light-emitting layer consists essentially of a host material and a light-emitting material,

wherein the light-emitting material is a first phosphorescent compound,

wherein the host material is different from the third organic compound,

wherein the fourth organic compound is a second phosphorescent compound,

wherein the hole-transporting layer consists essentially of the first organic compound, and

wherein a difference between a peak wavelength of an emission spectrum of the fourth organic compound and that of the light-emitting layer is within 30 nm.

16. The light-emitting element according to claim 15 , wherein the second organic compound is any one of an oxadiazole derivative, a triazole derivative, and a phenanthroline derivative.

17. The light-emitting element according to claim 15 , wherein a concentration of the second organic compound in the first layer is greater than or equal to 1 wt % and less than or equal to 20 wt %.

18. The light-emitting element according to claim 15 , wherein a thickness of the first layer is greater than or equal to 1 nm and less than or equal to 20 nm.

19. The light-emitting element according to claim 15 , wherein a concentration of the fourth organic compound in the second layer is greater than or equal to 0.1 wt % and less than or equal to 5 wt %.

20. The light-emitting element according to claim 15 , wherein the second organic compound decreases a hole-transporting property of the first layer.

21. The light-emitting element according to claim 15 , wherein the third organic compound is a metal complex.

22. The light-emitting element according to claim 15 , wherein the second organic compound has a molecular structure having a heterocyclic.

23. The light-emitting element according to claim 15 , wherein the fourth organic compound decreases an electron-transporting property of the second layer.

24. The light-emitting element according to claim 15 , wherein the hole injection layer comprises the first organic compound.

25. The light-emitting element according to claim 15 , wherein the second organic compound is a substance to which a hole is not injected.

26. The light-emitting element according to claim 15 , wherein a thickness of the second layer is greater than or equal to 5 nm and less than or equal to 20 nm.

27. The light-emitting element according to claim 15 ,

wherein the first layer is in contact with the hole injection layer and the hole-transporting layer, and

wherein the second layer is in contact with the light-emitting layer and the electron-transporting layer.

28. A light-emitting device comprising the light-emitting element according to claim 15 and a control unit configured to control light emission of the light-emitting element.

29. An electronic device comprising a display portion, the display portion comprising the light-emitting element according to claim 15 and a control unit configured to control light emission of the light-emitting element.

30. A light-emitting element comprising:

a first electrode;

a hole injection layer over the first electrode;

a hole-transporting layer over the hole injection layer;

a light-emitting layer over the hole-transporting layer;

an electron-transporting layer over the light-emitting layer;

a second electrode over the electron-transporting layer;

a first layer between the hole injection layer and the hole-transporting layer; and

a second layer between the light-emitting layer and the electron-transporting layer,

wherein the first layer comprises a first organic compound having a hole-transporting property and a second organic compound having an electron-transporting property,

wherein the second layer comprises a third organic compound having an electron-transporting property and a fourth organic compound having a hole-transporting property,

wherein the hole injection layer comprises a fifth organic compound and a metal oxide;

wherein the light-emitting layer consists essentially of a host material and a light-emitting material,

wherein the light-emitting material is a first phosphorescent compound,

wherein the host material is different from the third organic compound,

wherein the fourth organic compound is a second phosphorescent compound,

wherein the electron-transporting layer contains neither the third organic compound nor the fourth organic compound, and

wherein the hole-transporting layer consists essentially of the first organic compound.

31. The light-emitting element according to claim 30 , wherein the second organic compound is any one of an oxadiazole derivative, a triazole derivative, and a phenanthroline derivative.

32. The light-emitting element according to claim 30 , wherein a concentration of the second organic compound in the first layer is greater than or equal to 1 wt % and less than or equal to 20 wt %.

33. The light-emitting element according to claim 30 , wherein a thickness of the first layer is greater than or equal to 1 nm and less than or equal to 20 nm.

34. The light-emitting element according to claim 30 , wherein a concentration of the fourth organic compound in the second layer is greater than or equal to 0.1 wt% and less than or equal to 5 wt %.

35. The light-emitting element according to claim 30 , wherein the second organic compound decreases a hole-transporting property of the first layer.

36. The light-emitting element according to claim 30 , wherein the third organic compound is a metal complex.

37. The light-emitting element according to claim 30 , wherein the second organic compound has a molecular structure having a heterocyclic.

38. The light-emitting element according to claim 30 , wherein the fourth organic compound decreases an electron-transporting property of the second layer.

39. The light-emitting element according to claim 30 , wherein the fifth organic compound contained in the hole injection layer is the first organic compound.

40. The light-emitting element according to claim 30 , wherein the second organic compound is a substance to which a hole is not injected.

41. The light-emitting element according to claim 30 , wherein a thickness of the second layer is greater than or equal to 5 nm and less than or equal to 20 nm.

42. The light-emitting element according to claim 30 ,

wherein the first layer is in contact with the hole injection layer and the hole-transporting layer, and

wherein the second layer is in contact with the light-emitting layer and the electron-transporting layer.

43. A light-emitting device comprising the light-emitting element according to claim 30 and a control unit configured to control light emission of the light-emitting element.

44. An electronic device comprising a display portion, the display portion comprising the light-emitting element according to claim 30 and a control unit configured to control light emission of the light-emitting element.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2008
From: SUZUKI, TSUNENORI; SHITAGAKI, SATOKO; SEO, SATOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 021496/0028 →
Priority Claims (1)
JP 2007-237910 · Sep 13, 2007 · national
Continuity (1)
Related Publication 20090072725A1 · Mar 19, 2009