Continuous process for the production of nanostructures including nanotubes
The present invention provides methods for uniform growth of nanostructures such as nanotubes (e.g., carbon nanotubes) on the surface of a substrate, wherein the long axes of the nanostructures may be substantially aligned. The nanostructures may be further processed for use in various applications, such as composite materials. The present invention also provides systems and methods for growth of nanostructures, including batch processes and continuous processes. For example, in certain embodiments, a system for growing nanostructures is provided which includes a growth substrate, a region able to expose the surface of the growth substrate to a set of conditions selected to cause catalytic formation of nanostructures on the surface of the growth substrate, and a region able to expose the surface of the growth substrate to a set of conditions selected to remove nanostructures from the surface of the growth substrate.
1. A system for growing nanostructures, comprising:
a porous growth substrate with a first surface portion on a first side of the growth substrate suitable for growing nanostructures thereon, the growth substrate comprising a catalyst material;
a first region able to expose the first surface portion of the growth substrate to a first set of conditions selected to cause catalytic formation of nanostructures on the first surface portion of the growth substrate and configured such that a nanostructure precursor material is transported from a second side of the porous growth substrate to the first side of the porous growth substrate; and
a second region able to expose the first surface portion of the growth substrate to a second set of conditions, different from the first set of conditions, and selected to remove nanostructures from the first surface portion of the growth substrate while the first region exposes a second surface portion of the growth substrate to a set of conditions selected to cause catalytic formation of nanostructures on the second surface portion of the growth substrate.
2. A system as in claim 1 , wherein the growth substrate is a rotatable cylindrical substrate.
3. A system as in claim 2 , wherein the growth substrate is hollow.
4. A system as in claim 1 , further comprising a region able to expose the surface of the growth substrate to a set of conditions selected to replace the catalyst material with a different catalyst material.
5. A system as in claim 1 , wherein the nanostructures are nanotubes.
6. A system as in claim 5 , wherein the nanotubes are carbon nanotubes.
7. A system as in claim 1 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise removing the nanostructures without attaching the nanostructures to a receiving substrate.
8. A system as in claim 1 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise application of a mechanical tool, mechanical vibration, a chemical reagent, and/or heat to the nanostructures and/or the surface of the growth substrate.
9. A system as in claim 1 , wherein the growth substrate comprises alumina, silicon, carbon, a ceramic, and/or a metal.
10. A system as in claim 1 , wherein the region able to expose the surface of the growth substrate to a set of conditions selected to cause catalytic formation of nanostructures on the surface of the growth substrate is configured to flow a nanostructure precursor material through the porous growth substrate.
11. A system as in claim 10 , wherein the nanostructure precursor comprises a hydrocarbon.
12. A system as in claim 1 , wherein the catalyst material comprises a metal or metal oxide.
13. A system as in claim 12 , wherein the catalyst material comprises iron, cobalt, or nickel.
14. A system as in claim 1 , wherein the nanostructures are carbon nanostructures.
15. A system for growing nano structures, comprising:
a growth substrate with a surface suitable for growing nanostructures thereon;
a region able to expose the surface of the growth substrate to a set of conditions selected to cause catalytic formation of nanostructures on the surface of the growth substrate;
a region able to expose the surface of the growth substrate to a set of conditions selected to remove nanostructures from the surface of the growth substrate; and
a region able to expose the surface of the growth substrate to a set of conditions selected to reactivate a first catalyst material,
wherein the growth substrate is a rotatable, hollow, and cylindrical substrate and wherein the nanostructures are formed directly on the surface of the growth substrate.
16. A system as in claim 15 , wherein the growth substrate is porous.
17. A system as in claim 16 , wherein the region able to expose the surface to a set of conditions selected to cause catalytic formation of nanostructures on the surface of the growth substrate is configured to flow a nanostructure precursor material through the porous growth substrate.
18. A system as in claim 17 , wherein the nanostructure precursor comprises a hydrocarbon.
19. A system as in claim 15 , further comprising at least one support roller and/or at least one drive roller.
20. A system as in claim 15 , further comprising at least one set of electrical contacts associated with the growth substrate.
21. A system as in claim 15 , wherein the nanostructures are nanotubes.
22. A system as in claim 21 , wherein the nanotubes are carbon nanotubes.
23. A system as in claim 15 , wherein the nanostructures are nanowires.
24. A system as in claim 15 , wherein the nanostructures are nanofibers.
25. A system as in claim 15 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise removing the nanostructures without attaching the nanostructures to a receiving substrate.
26. A system as in claim 15 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise attaching the nanostructures to a receiving substrate.
27. A system as in claim 15 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise application of a mechanical tool, mechanical vibration, a chemical reagent, and/or heat to the nanostructures and/or the surface of the growth substrate.
28. A system as in claim 15 , wherein the growth substrate comprises alumina, silicon, carbon, a ceramic, and/or a metal.
29. A system as in claim 15 , wherein the first catalyst material comprises a metal or metal oxide.
30. A system as in claim 29 , wherein the first catalyst material comprises iron, cobalt, or nickel.
31. A system as in claim 15 , wherein the nanostructures are carbon nanostructures.
32. A system for growing nanostructures, comprising:
a growth substrate having a surface suitable for growing nanostructures thereon, wherein the surface is a topologically continuous surface;
a region able to expose a first portion of the surface of the growth substrate comprising a catalyst material to a set of conditions selected to cause catalytic formation of nanostructures on the surface of the growth substrate;
a region able to expose a second portion of the surface of the growth substrate to a set of conditions selected to remove nanostructures from the surface of the growth substrate without substantial removal of the catalyst material from the growth substrate; and
a region able to expose a third portion of the surface of the growth substrate to a set of conditions selected to reactivate the catalyst material on the surface of the growth substrate;
wherein, in operation, at least two regions are operated simultaneously.
33. A system as in claim 32 , wherein the growth substrate is a rotatable cylindrical substrate.
34. A system as in claim 33 , wherein the growth substrate is hollow.
35. A system as in claim 32 , wherein the growth substrate is porous.
36. A system as in claim 35 , wherein the region able to expose the surface of the growth substrate to a set of conditions selected to cause catalytic formation of nanostructures on the surface of the growth substrate is configured to flow a nanostructure precursor material through the porous growth substrate.
37. A system as in claim 36 , wherein the nanostructure precursor comprises a hydrocarbon.
38. A system as in claim 32 , further comprising at least one support roller and/or at least one drive roller.
39. A system as in claim 32 , further comprising at least one set of electrical contacts associated with the growth substrate.
40. A system as in claim 32 , wherein the nanostructures are nanotubes.
41. A system as in claim 40 , wherein the nanotubes are carbon nanotubes.
42. A system as in claim 32 , wherein the nanostructures are nanowires.
43. A system as in claim 32 , wherein the nanostructures are nanofibers.
44. A system as in claim 32 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise removing the nanostructures without attaching the nanostructures to a receiving substrate.
45. A system as in claim 32 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise attaching the nanostructures to a receiving substrate.
46. A system as in claim 32 , wherein the conditions selected to remove the nanostructures from the surface of the growth substrate comprise application of a mechanical tool, mechanical vibration, a chemical reagent, and/or heat to the nanostructures and/or the surface of the growth substrate.
47. A system as in claim 32 , wherein the growth substrate is a flexible belt arranged on at least one continuously rotating component.
48. A system as in claim 32 , wherein the catalyst material comprises a metal or metal oxide.
49. A system as in claim 48 , wherein the catalyst material comprises iron, cobalt, or nickel.
50. A system as in claim 32 , wherein the nanostructures are carbon nanostructures.