Heat-sensitive recording material
A heat-sensitive recording material is proposed, which comprises a substrate and a heat-sensitive recording layer that contains color formers and color acceptors, where the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N′-3-(p-toluenesulfonyloxyphenyl)urea with the following formula (1): and a urea-urethane compound with the following formula (2): where the ratio of the two color acceptors, i.e., the ratio of N-(p-toluenesulfonyl)-N′-3-(p-toluenesulfonyloxyphenyl)urea according to formula (1) to the urea-urethane compound according to formula (2), is in the range of 10:1 to 1:1, based on wt. % in the heat-sensitive recording layer.
1. A heat-sensitive recording material with comprising a substrate and a heat-sensitive recording layer that contains one or more color formers and two color acceptors, characterized by the fact that wherein
the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, and
the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N′-3-(p-toluenesulfonyloxyphenyl)urea with having the following formula (1):
and a urea-urethane compound with having the following formula (2):
wherein the ratio of the two color acceptors, i.e., the ratio of N-(p-toluenesulfonyl)-N′-3-(p-toluenesulfonyloxyphenyl)urea according to formula (1) to the urea-urethane compound according to formula (2), is in the range of 10:1 to 1:1, based on wt. % in the heat-sensitive recording layer.
2. A heat-sensitive recording material in accordance with claim 1 , characterized by the fact that wherein the dynamic print density of a thermal test copy produced with a thermal printing head at a resolution of 300 dpi and an energy per unit surface area of 9 mJ/mm 2 is in the range of 0.91 to 1.03 ODU.
3. A heat-sensitive recording material in accordance with either of claim 1 and claim 2 , characterized by the fact that wherein the percent resistance of a thermal test copy produced with a thermal printing head at a resolution of 300 dpi is
in the range of 91.5% to 96.5% with respect to a 25% ethanol solution,
in the range of 95.5% to 99.5% with respect to water, and
in the range of 90.5% to 95.5% with respect to plasticizers (TESA®-Grafik-Film 57331).
4. A heat-sensitive recording material in accordance with any of claims 1 to 3 , characterized by the fact that wherein the recording layer has a whiteness in the range of 79-85% with the use of light without a UV component, measured according to ISO 2469/ISO 2470 with the use of D65 light at a viewing angle of 8°.
5. A heat-sensitive recording material in accordance with claim 1 , characterized by the fact that wherein the recording layer has a whiteness in the range of 87-93% with the use of light with a UV component, measured according to ISO 2469/ISO 2470 with the use of D65 light at a viewing angle of 8°.
6. A heat-sensitive recording material in accordance with any of claims 1 to 5 , characterized by the fact that wherein a pigmented intermediate layer is formed between the substrate and the heat-sensitive recording layer.
7. The heat-sensitive recording material of claim 1 , wherein the ratio of urea compound according to formula (1) to the urea-urethane compound according to formula (2) is in the range of from 5:1 to 2.5:1.
8. A ticket comprising a substrate and a heat-sensitive recording layer that contains one or more color formers and two color acceptors as a ticket or passenger ticket,
wherein,
the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, and
the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N′-3-(p-toluenesulfonyloxyphenyl)urea with having the following formula (1):
and a urea-urethane compound with having the following formula (2):
wherein the ratio of the two color acceptors, i.e., the ratio of N-(p-toluenesulfonyl)-N′-3-(p-toluenesulfonyloxyphenyl)urea according to formula (1) to the urea-urethane compound according to formula (2), is in the range of 10:1 to 1:1, based on wt. % in the heat-sensitive recording layer.
9. The ticket of claim 8 , wherein the ratio of urea compound according to formula (1) to the urea-urethane compound according to formula (2) is in the range of from 5:1 to 2.5:1.