Method of making building blocks from clay-containing compounds
View Patent ↗A method of making a building block from clay-containing compounds, which includes employing a major amount of such clay-containing material in combination with a calciferous additive and water to cure the shape the same under the influence of controlled pressure and temperature for a pre-determined time to create building block which is characterized by a mineralogical crystalline phase. The clay-containing compound includes a mixture of fine particulate material and coarser particulate material. The product produced by the method is also disclosed.
1. A method of making a shaped product comprising:
combining a major portion by weight of a clay-containing compound which essentially does not include free silica, said clay-containing compound comprising clay mineral selected from the group consisting of plagioclase, muscovite, kaolinite, biotite, hornblende, chlorite, montmorillonite, illite, vermiculite, serpentine, pyrophyllite, talc, phlogopite, glauconite, prehnite, stilpnomelane, apophyllite, anthophyllite, cummingtonite, tremolite- actinolite, pigeonite, diopside, hedenbergite, augite, acmite, jadeite, spodumene, wollastonite, pectolite, rhodonite, axinite, beryl, cordierite, lawsonite, pumpellyite, gehlenite, akermanite, hemimorphite, vesuvianite, zoisite, clinizoisite, epidote, allanite, olivine, willemite, zircon, thorite, titanite, andalusite, sillimanite, kyanite, staurolite, topaz, datolite, xhloritoid, and mixtures thereof, with a calciferous additive to form a first mixture in a dry form, wherein a first portion of said clay-containing compound has an average particle size that is coarser than a second portion of said clay-containing compound;
mixing the first mixture in the dry form;
combining water with said first mixture to create a second mixture in a moistened form, wherein said water is present in an amount from about 5 to 15 percent of said second mixture on a weight basis;
mixing the second mixture in the moistened form;
compacting said second mixture with pressure from about 34,474 to 68,948 kPa (5000 to 10,000 psi) to form a shaped product; and
hydrothermally treating said shaped product to facilitate the formation of an interlocking mineralogical matrix therein.
2. The method of claim 1 including employing as said calciferous additive lime selected from the group consisting of hydrated lime, quicklime and mixtures thereof.
3. The method of claim 2 including employing said calciferous additive in an amount of about 5 to 20 percent of the dry mixture on a weight basis.
4. The method of claim 2 including employing lime as said calciferous additive in an amount of about 10 to 15 percent of the dry mixture on a weight basis.
5. The method of claim 1 including effecting said hydrothermal treatment at a temperature of about 180 to 225 degrees Celsius for about 4 to 8 hours.
6. The method of claim 5 including effecting said hydrothermal treatment at a pressure of about 1067 to 2515 kPa (140 to 350 psi).
7. The method of claim 1 including effecting said compacting in a mold having a cavity of the desired shape for about 1 second to 3 minutes.
8. The method of claim 1 including employing said method to make a building block.
9. The method of claim 8 including creating said building block having a compressive strength of about 13,790 to 58,605 kPa (2,000 to 8,500psi).
10. The method of claim 9 including creating said building block having a compressive strength of about 24,132 to 58,605 kPa (3,500 to 8,500psi).
11. The method of claim 1 including adding a mineralogical coloring agent to produce a shaped product having a desired color.
12. The method of claim 11 including effecting said coloring agent addition prior to combining said water with said dry mixture.
13. The method of claim 1 wherein said clay-containing compound is selected from the group consisting of non-ferrous mine tailings, quarry fines and mixtures thereof.
14. The method of claim 13 wherein said non-ferrous mine tailings comprise copper.
15. The method of claim 1 wherein said first portion has an average particle size of greater than about 75 microns.
16. The method of claim 1 wherein said second portion has an average particle size of about 100 microns or less.
17. The method of claim 1 wherein said first portion and said second portion each comprise 50% by weight of the clay-containing compound.
18. The method of claim 1 wherein said clay-containing compound comprises 90 percent by weight of the dry mixture.