IP Library Granted Patent US 8,361,251
Granted Patent B2
US 8,361,251 · App. 12/254,460 · Granted Jan 29, 2013

High ductility/strength magnesium alloys

Inventors: Aihua A. Luo (Troy, MI); Raja K Mishra (Shelby Township, MI); Anil K. Sachdev (Rochester Hills, MI)
Assignee: GM Global Technology Operations LLC
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Quick Facts
Patent No.
US 8,361,251
App. No.
12/254,460
Granted
Jan 29, 2013
Kind
B2
Abstract

A magnesium alloy comprising up to about six weight percent zinc and up to about one weight percent cerium may be hot worked to produce an intermediate or final alloy workpiece that exhibits enhanced ductility and strength at room temperature. The addition of zinc and a small amount of cerium may affect the magnesium alloy by increasing strength and ductility, and improving the work hardening behavior.

Claims (17)

1. A method of processing a magnesium-zinc-cerium alloy to improve its ductility and strength at room temperature, the method comprising:

providing a magnesium-zinc-cerium alloy billet consisting essentially of, by weight, zinc in an amount of about two percent, from about 0.2 to 0.5 percent cerium, and at the balance substantially magnesium, the billet being shaped with an predetermined straight-line axis for hot deformation; and

extruding the magnesium-zinc-cerium alloy billet along the predetermined axis at a temperature of at least 300° C. to form a workpiece, wherein the extrusion ratio is in the range of 10:1 to 60:1, the as-extruded workpiece having a typical yield strength value of about 135 Mpa and a typical elongation at fracture of about 27%; and, thereafter,

subjecting the extruded workpiece to a further deformation step at ambient temperature.

2. A method as set forth in claim 1 in which the magnesium-zinc-cerium alloy billet contains 2 percent cerium.

3. A method as set forth in claim 1 wherein extruding the

magnesium-zinc-cerium alloy billet comprises:

heating the magnesium-zinc-cerium alloy billet to a deformation temperature in the range of about 300° C. to about 500° C.;

extruding the billet through an extrusion die at a speed in the range of about 10 mm/second to 1000 mm/second of extrudate to form an extruded workpiece, wherein the extrusion ratio is in the range of 10:1 to 60:1, the as-extruded workpiece having a typical yield strength value of about 135 MPa and a typical elongation at fracture of about 27%; and thereafter

subjecting the extruded workpiece to a further deformation at ambient temperature.

4. A method as set forth in claim 3 wherein the magnesium-zinc-cerium alloy billet contains, by weight, about 0.2 percent cerium.

5. A method of processing a magnesium-zinc-cerium alloy to improve its ductility and strength at room temperature, the method comprising:

providing a magnesium-zinc-cerium alloy billet consisting essentially of, by weight, zinc in an amount of about two percent, about 0.2 percent cerium, and the balance substantially magnesium, the billet being shaped with an predetermined straight-line axis for hot deformation; and

extruding the magnesium-zinc-cerium alloy billet along the predetermined axis at a temperature of at least 300° C. to form an extruded workpiece comprising a hollow or channeled rod, the as-extruded workpiece having a typical yield strength value of about 135 MPa and a typical elongation at fracture of about 27%.

6. A method of processing a magnesium-zinc-cerium alloy as recited in claim 5 in which the extruded workpiece is subjected to a further deformation step at ambient temperature.

7. A method of processing a magnesium-zinc-cerium alloy as recited in claim 5 in which the hollow rod extruded workpiece is a tube.

8. A method as set forth in claim 7 further comprising subjecting the deformed magnesium-zinc-cerium alloy tube to a hydroforming step at ambient temperature.

Assignments (12)
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2014
From: WILMINGTON TRUST COMPANY
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 034384/0758 →
CHANGE OF NAME Recorded Feb 10, 2011
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 025781/0245 →
SECURITY AGREEMENT Recorded Nov 8, 2010
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: WILMINGTON TRUST COMPANY
Reel/Frame 025324/0515 →
RELEASE OF SECURITY INTEREST Recorded Nov 5, 2010
From: UAW RETIREE MEDICAL BENEFITS TRUST
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025315/0046 →
RELEASE OF SECURITY INTEREST Recorded Nov 4, 2010
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 025245/0909 →
SECURITY AGREEMENT Recorded Aug 28, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UAW RETIREE MEDICAL BENEFITS TRUST
Reel/Frame 023162/0237 →
SECURITY AGREEMENT Recorded Aug 27, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 023156/0313 →
RELEASE OF SECURITY INTEREST Recorded Aug 21, 2009
From: UNITED STATES DEPARTMENT OF THE TREASURY
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023126/0914 →
RELEASE OF SECURITY INTEREST Recorded Aug 21, 2009
From: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 023155/0769 →
SECURITY AGREEMENT Recorded Apr 16, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: CITICORP USA, INC. AS AGENT FOR BANK PRIORITY SECURED PARTIES; CITICORP USA, INC. AS AGENT FOR HEDGE PRIORITY SECURED PARTIES
Reel/Frame 022554/0538 →
SECURITY AGREEMENT Recorded Feb 4, 2009
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 022201/0448 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 20, 2008
From: LUO, AIHUA A.; MISHRA, RAJA K.; SACHDEV, ANIL K.
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 021708/0289 →
Continuity (2)
Continuation In Part 11935439 · Nov 6, 2007
Related Publication 20090116994A1 · May 7, 2009