Ion mobility spectrometer with substance collector

1. An ion mobility spectrometer, comprising:

a substance collector;

a measuring tube coupled to the substance collector, the measuring tube having a reaction chamber and a drift chamber;

a membrane inlet coupled to at least one of the substance collector and the measuring tube, the membrane inlet having an inner chamber; and

a filter coupled to a pump in a closed internal gas circuit, the closed internal gas circuit defined by the substance collector, the measuring tube and the membrane inlet.

2. The ion mobility spectrometer of claim 1 , wherein the substance collector is configured in a circulating gas flow path between the inner chamber and the reaction chamber.

3. The ion mobility spectrometer of claim 1 , wherein

the substance collector is coupled to the measuring tube through the reaction chamber; and

the internal gas circuit is further defined by a plurality of control elements, the control elements having a first switching state and a second switching state, the first switching state coupling the reaction chamber and the substance collector through an analyte substance containing gas flow path, the second switching state coupling the filter, the substance collector and the reaction chamber through a cleaned circulating gas flow path.

4. The ion mobility spectrometer of claim 3 , wherein each control element comprises at least one of a valve and a controllable flow resistance.

5. The ion mobility spectrometer of claim 3 , wherein the control elements are not coupled between the substance collector and the reaction chamber.

6. Ion mobility spectrometer of claim 3 , wherein

the control elements are not coupled in a circulating gas flow path between the inner chamber and the substance collector; and

the control elements are not coupled in a second circulating gas flow path between the inner chamber and the reaction chamber.

7. The ion mobility spectrometer of claim 1 , wherein

the reaction chamber further comprises a first gas connection and a second gas connection;

the drift chamber further comprises a third gas connection;

the inner chamber is coupled to the first gas connection and a first end connection of a first 3/2-way valve;

the second gas connection is coupled to a second end connection of the first 3/2-way valve through a branching point;

the substance collector is configured between the second gas connection and the branching point; and

the pump further comprises a pressure side and a suction side, the pressure side of the pump is coupled to, through at least one of a direct path and a path through the filter, the third gas connection, the inner chamber and a center connection of a second 3/2-way valve, the suction side of the pump is coupled to a center connection of the first 3/2-way valve and a second end of the second 3/2-way valve.

8. The ion mobility spectrometer of claim 1 , wherein

the memory inlet further comprising a second inner chamber, the inner chamber and the second inner chamber are configured in parallel;

the measuring tube further comprises first, second and third gas connections;

the pump further comprises a pressure side and a suction side, the pressure side is coupled to, through at least one of a direct path and a path through the filter, the first gas connection, the inner chambers and, through a side branch, a first end connection of a 3/2-way valve, the suction side is coupled to a center connection of the 3/2-way valve;

the inner chamber is coupled through a first branching point to the second gas connection and the first end connection of the 3/2-way valve;

the second inner chamber is coupled through a second branching point to the third gas connection and a second end connection of the 3/2-way valve; and

the substance collector is configured between the first branching point and a connection of a side branch of the first end connection of the 3/2-way valve.

9. The ion mobility spectrometer of claim 1 , wherein the substance collector is thermally joined to a heating element.

10. The ion mobility spectrometer of claim 1 , wherein the substance collector is thermally joined to a cooling element.

11. The ion mobility spectrometer of claim 1 , wherein the substance collector further comprises at least one surface having capture molecules, the capture molecules operable to have an affinity greater for a first analyte substance than for at least one of other analyte substances and groups of analyte substances.

12. The ion mobility spectrometer of claim 1 , wherein the substance collector comprises a capillary tube having Tenax granules.

13. The ion mobility spectrometer of claim 1 , further comprising a gas chromatographic separating column coupled between the substance collector and the measuring tube in the closed internal gas circuit.

14. The ion mobility spectrometer of claim 13 , wherein the gas chromatographic separating column further comprises a heating element.

15. A method, comprising:

providing an ion mobility spectrometer comprising a measuring tube, a substance collector and a membrane inlet, the measuring tube, the substance collector and the membrane inlet defining a closed internal gas circuit;

separating the closed internal gas circuit from an external sample gas flow through the membrane inlet;

transferring circulating gas containing an analyte substance from the membrane inlet to the substance collector, the analyte substance accumulated in the substance collector;

releasing the accumulated analyte substances; and

transferring the released analyte substances to the measuring tube.

16. The method of claim 15 , further comprising at least one of

cooling the substance collector during collection; and

heating the substance collector during collection.

17. The method of claim 15 , further comprising at least one of

heating the substance collector periodically in accordance with a time function for a thermal desorption analysis; and

heating the substance collector continuously in accordance with the time function for the thermal desorption analysis.

18. The method of claim 15 , wherein the circulating gas containing the analyte substance from the membrane inlet to the substance collector is transferred through the measuring tube.

19. The method of claim 18 , wherein the direction of gas flow through the substance collector is reversed between the transferring of the circulating gas and the transferring of the released analyte substances.