IP Library Granted Patent US 7,750,386
Granted Patent B2
US 7,750,386 · App. 12/269,507 · Granted Jul 6, 2010

Memory cells including nanoporous layers containing conductive material

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Quick Facts
Patent No.
US 7,750,386
App. No.
12/269,507
Granted
Jul 6, 2010
Kind
B2
Abstract

A memory cell that includes a first contact having a first surface and an opposing second surface; a second contact having a first surface and an opposing second surface; a memory material layer having a first surface and an opposing second surface; and a nanoporous layer having a first surface and an opposing second surface, the nanoporous layer including at least one nanopore and dielectric material, the at least one nanopore being substantially filled with a conductive metal, wherein a surface of the nanoporous layer is in contact with a surface of the first contact or the second contact and the second surface of the nanoporous layer is in contact with a surface of the memory material layer.

Claims (42)

1. A memory cell comprising:

a first contact having a first surface and an opposing second surface;

a second contact having a first surface and an opposing second surface;

a memory material layer having a first surface and an opposing second surface; and

a nanoporous layer having a first surface and an opposing second surface, the nanoporous layer comprising at least one nanopore and dielectric material, the at least one nanopore being substantially filled with a conductive metal,

wherein the first surface of the nanoporous layer is in contact with a surface of the first contact or the second contact and the opposing second surface of the nanoporous layer is in contact with a surface of the memory material layer.

2. The memory cell according to claim 1 , wherein the memory material layer comprises a resistive random access memory (RRAM) material, a phase change memory (PCM) material, a programmable metallization cell (PMC) material or a spin torque transfer random access memory (STRAM) material.

3. The memory cell according to claim 1 , wherein the nanoporous layer comprises crosslinked polymer.

4. The memory cell according to claim 3 , wherein the nanoporous layer comprises crosslinked polystyrene.

5. The memory cell according to claim 1 , wherein the nanoporous layer comprises alumina (Al 2 O 3 ), zirconia (ZrO 2 ) or titania (TiO 2 ).

6. The memory cell according to claim 1 , wherein the nanoporous layer comprises a plurality of nanopores.

7. The memory cell according to claim 6 , wherein the plurality of nanopores are distributed in a hexagonally arranged pattern.

8. The memory cell according to claim 6 , wherein the dielectric material is continuous in the nanoporous layer and the plurality of nanopores are randomly dispersed throughout the dielectric material.

9. The memory cell according to claim 1 , wherein the at least one nanopore has a diameter from about 2 nm to about 200 nm.

10. The memory cell according to claim 1 , wherein the conductive metal substantially filling the at least one nanopore is chosen from the group consisting of: silver (Ag), copper (Cu), nickel (Ni) gold (Au), platinum (Pt) and palladium (Pd).

11. The memory cell according to claim 1 , wherein the nanoporous layer has a thickness from about 5 nm to about 50 nm.

12. A memory array comprising:

a plurality of memory cells, each memory cell comprising:

a first contact having a first surface and an opposing second surface;

a second contact having a first surface and an opposing second surface;

a memory material layer having a first surface and an opposing second surface; and

a nanoporous layer having a first surface and an opposing second surface, the nanoporous layer comprising at least one nanopore and dielectric material, the at least one nanopore being substantially filled with a conductive metal,

wherein the first surface of the nanoporous layer is in contact with a surface of the first contact or the second contact and the second opposing surface of the nanoporous layer is in contact with a surface of the memory material layer;

a plurality of transistors coupled to the plurality of memory cells;

at least one word line; and

at least one bit line,

wherein the word line is generally orthogonal to the bit line and each of the plurality of memory cells are operatively coupled to a word line and a bit line.

13. The memory array according to claim 12 , wherein the memory material layer comprises a resistive random access memory (RRAM) material, a phase change memory (PCM) material, a programmable metallization cell (PMC) material or a spin torque transfer random access memory (STRAM) material.

14. The memory array according to claim 12 wherein the nanoporous layer comprises crosslinked polymer.

15. The memory array according to claim 12 , wherein the nanoporous layer comprises a plurality of nanopores, where each of the plurality of nanopores has a diameter from about 2 nm to about 200 nm.

16. The memory array according to claim 12 , wherein the conductive metal substantially filling the at least one nanopore is chosen from the group consisting of: silver (Ag), copper (Cu), nickel (Ni) gold (Au), platinum (Pt) and palladium (Pd).

17. A method of forming a memory cell comprising the steps of:

forming a first contact layer by depositing a first conductive material on a substrate;

depositing a nanoporous layer on the first contact layer;

creating a plurality of nanopores in the nanoporous layer;

filling the nanopores with a second conductive material;

forming a memory material layer adjacent the nanoporous layer;

forming a second contact layer by depositing a third conductive material on the memory material layer, wherein after the step of creating a plurality of nanopores, the nanoporous layer also comprises a dielectric material.

18. The method of claim 17 , wherein the step of filling the nanopores comprises electrodeposition using the first contact layer as an electrode in the electrodeposition.

19. The method of claim 17 , wherein the step of depositing the nanoporous layer comprises depositing a fourth conductive material and the step of creating the plurality of nanopores comprises anodizing the fourth conductive material to convert it to the dielectric material that contains the nanopores and removing any non-anodized material from the plurality of nanopores.

20. The method of claim 19 , wherein the step of depositing the fourth conductive material further comprises patterning the fourth conductive material with a plurality of defects.

21. The method of claim 17 , wherein the step of depositing the nanoporous layer comprises depositing a diblock copolymer and the step of creating the plurality of nanopores comprises annealing the diblock copolymer under an applied electric field to create cylindrical microdomains, exposing the diblock copolymer to ultra-violet light to degrade a selected number of the cylindrical microdomains, and removing degraded material from the nanopores.

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded Jul 23, 2025
From: THE BANK OF NOVA SCOTIA
To: SEAGATE TECHNOLOGY PUBLIC LIMITED COMPANY; SEAGATE TECHNOLOGY; SEAGATE TECHNOLOGY HDD HOLDINGS; I365 INC.; SEAGATE TECHNOLOGY LLC; SEAGATE TECHNOLOGY INTERNATIONAL; SEAGATE HDD CAYMAN; SEAGATE TECHNOLOGY (US) HOLDINGS, INC.
Reel/Frame 072193/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Jul 19, 2013
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT AND SECOND PRIORITY REPRESENTATIVE
To: SEAGATE TECHNOLOGY LLC; EVAULT INC. (F/K/A I365 INC.); SEAGATE TECHNOLOGY INTERNATIONAL; SEAGATE TECHNOLOGY US HOLDINGS, INC.
Reel/Frame 030833/0001 →
SECURITY AGREEMENT Recorded Mar 24, 2011
From: SEAGATE TECHNOLOGY LLC
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026010/0350 →
RELEASE Recorded Jan 19, 2011
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: SEAGATE TECHNOLOGY HDD HOLDINGS; MAXTOR CORPORATION; SEAGATE TECHNOLOGY LLC; SEAGATE TECHNOLOGY INTERNATIONAL
Reel/Frame 025662/0001 →
SECURITY AGREEMENT Recorded May 15, 2009
From: MAXTOR CORPORATION; SEAGATE TECHNOLOGY LLC; SEAGATE TECHNOLOGY INTERNATIONAL
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT AND FIRST PRIORITY REPRESENTATIVE; WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT AND SECOND PRIORITY REPRESENTATIVE
Reel/Frame 022757/0017 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2008
From: TIAN, WEI; VENKATASAMY, VEKATRAM; SUN, MING; TANG, MICHAEL XUEFEI; JIN, INSIK
To: SEAGATE TECHNOLOGY LLC
Reel/Frame 021842/0514 →