Thermoadhesive conjugate fiber and manufacturing method of the same
A major object of the invention is to provide a thermoadhesive conjugate fiber with low heat shrinkability and high adhesion having low orientation and high elongation and having extremely satisfactory card-passing properties. The object of the invention can be achieved by a thermoadhesive conjugate fiber made of a fiber forming resin component and a crystalline thermoplastic resin having a melting point of at least 20° C. lower than that of the fiber forming resin component and having a breaking elongation of from 60 to 600%, a dry heat shrinkage percentage at 120° C. of from −10.0 to 5.0%, and more preferably a percentage of crimp/number of crimps of 0.8 or more; and a manufacturing method of a thermoadhesive conjugate fiber, which includes drawing an undrawn yarn of a conjugate fiber taken up at a spinning rate of from 150 to 1,800 m/min in a low draw ratio of from 0.5 to 1.3 times at a temperature higher than both a glass transition temperature of a major crystalline thermoplastic resin of the thermo-adhesive resin component and a glass transition temperature of the fiber forming resin component and simultaneously subjecting to a fixed-length heat treatment and subsequently subjecting to a heat treatment under no tension at a temperature of at least 5° C. higher than the temperature of the fixed-length heat treatment.
1. A thermoadhesive conjugate fiber which is a conjugate fiber made of a fiber forming resin component and a thermoadhesive resin component, wherein the thermoadhesive resin component is made of a crystalline thermoplastic resin having a melting point of at least 20° C. lower than that of the fiber forming resin component and that the conjugate fiber has a breaking elongation of from 80 to 600% and a dry heat shrinkage percentage at 120° C. of from −10.0 to 5.0%.
2. The thermoadhesive conjugate fiber according to claim 1 , wherein a percentage of crimp/number of crimp is 0.8 or more.
3. The thermoadhesive conjugate fiber according to claim 1 , which is a concentric core/sheath type conjugate fiber or an eccentric core/sheath type conjugate fiber in which the fiber forming resin component is a core and the thermoadhesive resin component is a sheath.
4. The thermoadhesive conjugate fiber according to claim 3 , wherein a weight ratio of the resin component constituting the core to the resin component constituting the sheath is from 60/40 to 10/90 (weight ratio).
5. The thermoadhesive conjugate fiber according to claim 1 , wherein a melt flow rate (MFR) (measurement temperature: 230° C., load 21.18N polypropylene resin was measured, measurement temperature: 280° C., load 21.18N polyethylene terephthalate resin was measured, measurement temperature: 190° C., load 21.18N other resin was measured) of a major crystalline thermo-plastic resin constituting the thermo-adhesive resin component before the thermoadhesive conjugate fiber is made is from 1 to 15 g/10 mm.
6. The thermoadhesive conjugate fiber according to claim 1 , wherein a melt flow rate (MFR) (measurement temperature: 230° C., load 21.18N polypropylene resin was measured, measurement temperature: 280° C., load 21.18N polyethylene terephthalate resin was measured, measurement temperature: 190° C., load 21.18N other resin was measured) of a major crystalline thermo-plastic resin constituting the thermoadhesive resin component before the thermoadhesive conjugate fiber is made is at least 5 g/10 mm smaller than MFR of the fiber forming resin component.
7. The thermoadhesive conjugate fiber according to claim 1 , wherein the thermoadhesive resin component is constituted of a polymer blend made of two or more kinds of thermoplastic resins.
8. The thermoadhesive conjugate fiber according to claim 7 , wherein the thermoadhesive resin component is constituted of a polymer blend made of from 100 to 60% by weight of a crystalline thermoplastic resin A and from 0 to 40% by weight of a crystalline thermoplastic resin B; and that a melting point of the crystalline thermoplastic resin B is at least 20° C. lower than a melting point of the crystalline thermoplastic resin A.
9. The thermoadhesive conjugate fiber according to claim 7 , wherein the thermoadhesive resin component is constituted of a polymer blend made of from 99.8 to 90% by weight of a crystalline thermoplastic resin A and from 0.2 to 10% by weight of an amorphous thermoplastic resin; and that a glass transition temperature of the amorphous thermoplastic resin is at least 20° C. lower than a melting point of the crystalline thermoplastic resin A.
10. The thermoadhesive conjugate fiber according to claim 1 , wherein the fiber forming resin composition is polyethylene terephthalate.
11. The thermoadhesive conjugate fiber according to claim 1 , wherein a major crystalline thermoplastic resin of the thermoadhesive resin component is a polyolefin resin.
12. The thermoadhesive conjugate fiber according to claim 1 , wherein a major crystalline thermoplastic resin of the thermoadhesive resin component is a crystalline copolyester.
13. A manufacturing method of the thermoadhesive conjugate fiber according to claim 1 , which includes drawing an undrawn yarn of a conjugate fiber taken up at a spinning rate of from 150 to 1,800 m/min in a low draw ratio of from 0.5 to 1.3 times at a temperature higher than both a glass transition temperature of a major crystalline thermoplastic resin of the thermoadhesive resin component and a glass transition temperature of the fiber forming resin component and simultaneously subjecting to a fixed-length heat treatment and subsequently subjecting to a heat treatment under no tension at a temperature of at least 5° C. higher than the temperature of the fixed-length heat treatment.
14. A manufacturing method of the thermoadhesive conjugate fiber according to claim 6 , which includes drawing an undrawn yarn of a conjugate fiber in which a melt flow rate of a major crystalline thermoplastic resin constituting the thermo-adhesive resin component is at least 5 g/10 mm smaller than a melt flow rate of the fiber forming resin component and which has been taken up at a spinning rate of from 150 to 1,800 m/min in a low draw ratio of from 0.5 to 1.3 times at a temperature higher than both a glass transition temperature of the major crystalline thermoplastic resin of the thermoadhesive resin component and a glass transition temperature of the fiber forming resin component and simultaneously subjecting to a fixed-length heat treatment and subsequently subjecting to a heat treatment under no tension at a temperature of at least 5° C. higher than the temperature of the fixed-length heat treatment.
15. A manufacturing method of the thermoadhesive conjugate fiber according to claim 8 , which includes drawing an undrawn yarn of a conjugate fiber in which the thermoadhesive resin component is constituted of a polymer blend made of from 100 to 60% by weight of a crystalline thermoplastic resin A and from 0 to 40% by weight of a crystalline thermoplastic resin B and a melting point of the crystalline thermoplastic resin B is at least 20° C. lower than a melting point of the crystalline thermoplastic resin A and which has been taken up at a spinning rate of from 150 to 1,800 m/min in a low draw ratio of from 0.5 to 1.3 times at a temperature higher than both a glass transition temperature of the major crystalline thermoplastic resin A of the thermoadhesive resin component and a glass transition temperature of the fiber forming resin component and simultaneously subjecting to a fixed-length heat treatment and subsequently subjecting to a heat treatment under no tension at a temperature of at least 5° C. higher than the temperature of the fixed-length heat treatment.
16. A manufacturing method of the thermoadhesive conjugate fiber according to claim 9 , which includes drawing an undrawn yarn of a conjugate fiber in which the thermoadhesive resin component is constituted of a polymer blend made of from 99.8 to 90% by weight of a crystalline thermoplastic resin A and from 0.2 to 10% by weight of an amorphous thermoplastic resin and a glass transition temperature of the amorphous thermoplastic resin is at least 20° C. lower than a melting point of the crystalline thermoplastic resin A and which has been taken up at a spinning rate of from 150 to 1,800 m/min in a low draw ratio of from 0.5 to 1.3 times at a temperature higher than both a glass transition temperature of the major crystalline thermoplastic resin A of the thermoadhesive resin component and a glass transition temperature of the fiber forming resin component and simultaneously subjecting to a fixed-length heat treatment and subsequently subjecting to a heat treatment under no tension at a temperature of at least 5° C. higher than the temperature of the fixed-length heat treatment.
17. The manufacturing method of the thermoadhesive conjugate fiber according to claim 13 , wherein the fixed-length heat treatment is carried out in warm water; and that the heat treatment under no tension is carried out in hot air.
18. The manufacturing method of the thermoadhesive conjugate fiber according to claim 14 , wherein the fixed-length heat treatment is carried out in warm water; and that the heat treatment under no tension is carried out in hot air.
19. The manufacturing method of the thermoadhesive conjugate fiber according to claim 15 , wherein the fixed-length heat treatment is carried out in warm water; and that the heat treatment under no tension is carried out in hot air.
20. The manufacturing method of the thermoadhesive conjugate fiber according to claim 16 , wherein the fixed-length heat treatment is carried out in warm water; and that the heat treatment under no tension is carried out in hot air.