Epoxy composite material containing polyaniline/carbon black and preparation method thereof
View Patent ↗An epoxy composite material containing polyaniline/carbon black and preparation method thereof are disclosed. The epoxy composite material containing polyaniline/carbon black includes a plurality of polyaniline/carbon black composite with core-shell structure distributed in epoxy resin while polyaniline covers on surface of nanoscale carbon black to form the polyaniline/carbon black composite with core-shell structure. The polyaniline/carbon black composite with core-shell structure contains 10˜30 wt. % of nanoscale carbon black. A method for preparing an epoxy composite material containing polyaniline/carbon black includes steps of: adding a plurality of polyaniline/carbon black composites with core-shell structure into epoxy resin; and dispersing the plurality of polyaniline/carbon black composites with core-shell structure in the epoxy resin to produce the epoxy composite material containing polyaniline/carbon black being applied to conductive coating or microwave absorbing elements.
1. A method for preparing an epoxy composite material containing polyaniline/carbon black composites comprising the steps of:
adding aniline into nanoscale carbon black solution and then adding ammonium persulfate and acid into the mixture to produce the polyaniline/carbon black composites with a core-shell structure;
adding a plurality of polyaniline/carbon black composites with core-shell structure into an epoxy resin; and
distributing the plurality of polyaniline/carbon black composites with core-shell structure in the epoxy resin to produce the epoxy composite material containing polyaniline/carbon black composites, said polyaniline/carbon black composites with core-shell structure containing 20-30 wt. % of nanoscale carbon black and the weight ratio of said polyaniline/carbon black composites with core-shell structure to the epoxy resin is 3:7.
2. The method as claimed in claim 1 , wherein the step of dispersing the plurality of polyaniline/carbon black composites with core-shell structure in the epoxy resin to produce the epoxy composite material containing polyaniline/carbon black further comprising a step of using a DC (direct current)-stirrer to disperse the plurality of polyaniline/carbon black composites with core-shell structure in the epoxy resin.
3. The method as claimed in claim 1 , wherein in the step of dispersing the plurality of polyaniline/carbon black composites with core-shell structure in the epoxy resin to produce the epoxy composite material containing polyaniline/carbon black, the plurality of polyaniline/carbon black composites with core-shell structure are distributed evenly in the epoxy resin.
4. The method as claimed in claim 1 , wherein the step of dispersing the plurality of polyaniline/carbon black composites with core-shell structure in the epoxy resin to produce the epoxy composite material containing polyaniline/carbon black further comprising a step of hot pressing.
5. The method as claimed in claim 1 , wherein the nanoscale carbon black solution is produced by adding nanoscale carbon black into a dispersing agent and ethanol solution, then further adding acid into the mixture solution and processing the mixture by ultrasound vibration.
6. The method as claimed in claim 1 , wherein the step of adding aniline into nanoscale carbon black solution and then adding ammonium persulfate and acid into the mixture to produce the polyaniline/carbon black composites with core-shell structure further comprising a step of vacuum filtration and acid rinsing.
7. The method as claimed in claim 6 , wherein after the step of vacuum filtration and acid rinsing, a step of being heated for drying and grinded is further included.