Process for contacting two phases whose contact is accompanied by heat evolution
A method for bringing into contact two phases which are not completely miscible with one another, and whose contact is accompanied by heat development owing to mass transfer and/or chemical reaction, in which a first phase is introduced into the lower region of a contactor and a second phase is introduced into the upper region of the contactor and passed in countercurrent flow to the first phase in the contactor, a treated first phase and an exhausted second phase being obtained, which comprises recirculating a part of the exhausted second phase to the contactor at least one point situated between the upper region and the lower region. In the preferred embodiment, the first phase is a fluid stream comprising acid gases such as CO 2 , H 2 S, SO 2 , CS 2 , HCN, COS or mercaptans, and the second phase is an absorption medium which comprises an aqueous solution of at least one organic and/or inorganic base.
1. A method for bringing into contact a first phase that is a fluid stream comprising acid gases, the acid gases comprising CO 2 , with a second phase that is an absorption medium which comprises an aqueous solution of at least one organic base,
wherein the first phase is introduced into the lower region of a contactor and the second phase is introduced into the upper region of the contactor and passed in countercurrent flow to the first phase in the contactor, a treated first phase at a top of the contactor, and a loaded absorption medium at a bottom of the contactor, being obtained, which comprises recirculating a first part of the loaded absorption medium obtained from the bottom of the contactor and directly introducing the recirculated first part to at least one point situated between the upper region and the lower region of the contactor, the first part of the loaded absorption medium being unregenerated, and regenerating the other part of the loaded absorption medium by expansion, heating, and/or stripping,
in which the height difference between the feed site of the first part of the loaded absorption medium and the introduction site of the first phase is 20 to 70% of the height difference between the feed site of the second phase and the introduction site of the first phase.
2. The method according to claim 1 , in which a ratio of the mass flow of the first part of the loaded absorption medium to the mass flow of the second phase is 0.1 to 3.0.
3. The method according to claim 1 , in which the height difference between the feed site of the first part of the loaded absorption medium and the introduction site of the first phase is 30 to 70% of the height difference between the feed site of the second phase and the introduction site of the first phase.
4. The method according to claim 1 , in which the mass flow of the treated first phase m(1′), the specific heat capacity of the treated first phase Cp(1′), the mass flow of the second phase m(2) and the specific heat capacity of the second phase Cp(2) satisfy the equation:
0.5· m (2)· Cp (2)≦ m (1′)· Cp (1′)≦2.0· m (2)· Cp (2).
5. The method according to claim 1 , in which the fluid stream to be treated has a carbon dioxide concentration of 0.5 to 5 mol %.
6. The method according to claim 1 , in which the absorption medium comprises an aqueous solution of monoethanolamine (MEA), methylaminopropylamine (MAPA), piperazine, diethanolamine (DEA), triethanolamine (TEA), diethylethanolamine (DEEA), diisopropylamine (DIPA), aminoethoxyethanol (AEE), dimethylaminopropanol (DIMAP) and methyldiethanolamine (MDEA), methyldiisopropanolamine (MDIPA), 2-amino-1-butanol (2-AB), 2-amino-2-methyl-1-propanol (AMP), potassium N,N-dimethylglycinate, potassium N-methylalaninate, potassium 2-aminoethanesulfonate, or mixtures thereof.
7. The method according to claim 6 , in which the absorption medium comprises an aqueous solution of methyldiethanolamine and piperazine.
8. The method according to claim 6 , in which the absorption medium comprises an aqueous solution of methyldiethanolamine and methylaminopropylamine.
9. The method according to claim 6 , in which the absorption medium comprises an aqueous solution of methyldiethanolamine and aminoethoxyethanol.
10. The method according to claim 6 , in which the absorption medium comprises an aqueous solution of methyldiethanolamine and 2-amino-1-butanol.
11. The method according to claim 6 , in which the absorption medium comprises an aqueous solution of potassium N,N-dimethylglycinate.
12. The method according to claim 6 , in which the absorption medium comprises an aqueous solution of potassium N-methylalaninate.
13. The method according to claim 2 , in which the height difference between the feed site of the first part of the loaded absorption medium and the introduction site of the first phase is 40 to 60% of the height difference between the feed site of the second phase and the introduction site of the first phase.
14. The method according to claim 2 , in which the first part of the loaded absorption medium is cooled prior to the introduction into the contactor.
15. The method according to claim 3 , in which the first part of the loaded absorption medium is cooled prior to the introduction into the contactor.
16. The method according to claim 2 , in which the mass flow of the treated first phase m(1′), the specific heat capacity of the treated first phase Cp(1′), the mass flow of the second phase m(2) and the specific heat capacity of the second phase Cp(2) satisfy the equation:
0.5· m (2)· Cp (2)≦ m (1′)· Cp (1′)≦2.0· m (2)· Cp (2).
17. The method according to claim 3 , in which the mass flow of the treated first phase m(1′), the specific heat capacity of the treated first phase Cp(1′), the mass flow of the second phase m(2) and the specific heat capacity of the second phase Cp(2) satisfy the equation:
0.5· m (2)· Cp (2)≦ m (1′)· Cp (1′)≦2.0· m (2)· Cp (2).
18. A method for bringing into contact a first phase that is a fluid stream comprising acid gases with a second phase that is an absorption medium which comprises an aqueous solution of at least one organic base, the method comprising:
introducing the first phase into a lower region of a contactor and introducing the second phase into an upper region of the contactor, wherein the first phase and the second phase are mixed and pass in countercurrent flow within the contactor, to provide a treated first phase and a loaded absorption medium;
recirculating a first portion of the loaded absorption medium directly to the contactor at a point between the upper region and the lower region of the contactor, the point being at a height difference between the feed site of the first portion of the loaded absorption medium and the introduction site of the first phase being 20 to 80% of the height difference between the feed site of the second phase and the introduction site of the first phase,
wherein the first portion of the loaded absorption medium is not regenerated, and a ratio of the mass flow of the first portion of the loaded absorption medium to the mass flow of the second phase is 0.1 to 3.0; and
regenerating a second portion of the loaded absorption medium by expansion, heating, and/or stripping.
19. The method according to claim 18 , wherein a mass flow of the treated first phase m(1′), the specific heat capacity of the treated first phase Cp(1′), the mass flow of the second phase m(2) and the specific heat capacity of the second phase Cp(2) satisfy the equation:
0.5· m (2)· Cp (2)≦ m (1′)· Cp (1′)≦2.0· m (2)· Cp (2).
20. The method according to claim 18 , wherein the first phase fluid stream includes carbon dioxide concentration of 0.5 to 5 mol %.
21. The method according to claim 18 , in which the absorption medium comprises an aqueous solution that includes methyldiethanolamine and at least one other amine selected from the group consisting of piperazine, methylaminopropylamine, aminoethoxyethanol and 2-amino-1-butanol.
22. The method according to claim 18 , in which the absorption medium comprises an aqueous solution including an amine salt selected from potassium N,N-dimethylglycinate or potassium N-methylalaninate.