Method for purifying cyclic ketones
The present invention relates to a process for purifying a composition (I) comprising at least one cyclic ketone having from 7 to 16 carbon atoms, which comprises thermal treatment of the composition (I) with a catalyst comprising at least one transition metal and further purification by means of a process selected from the group consisting of distillation, extraction and crystallization. Furthermore, the present invention relates to a process for preparing cyclododecanone, which comprises such a purification, and the use of at least one catalyst comprising at least one transition metal for purifying a composition (I) comprising at least one cyclic ketone having from 7 to 16 carbon atoms by thermal treatment of the composition (I) with a catalyst comprising at least one transition metal.
1. A process for preparing cyclododecanone which comprises at least the steps
(a) preparing of a composition (I′) comprising at least cyclododecanone, comprising at least the steps
(a-1) trimerization of a butadiene to form a cyclododecatriene,
(a-2) oxidating the cyclododecatriene to form a cyclododecadienone,
(a-3) hydrogenating the cyclododecadienone to form the cyclododecanone,
(b) purifying the composition (I′), which comprises at least the steps
(i) thermal treating of the composition (I′) with at least one catalyst comprising at least one transition metal,
(ii) further purifying by means of a process selected from the group consisting of distillation, extraction and crystallization.
2. The process according to claim 1 , wherein the treating in step (i) is carried out at a temperature of from 60 to 350° C.
3. The process according to claim 1 , wherein the treating in step (i) is carried out for a time of from 0.1 to 50 hours.
4. The process according to claim 2 , wherein the treatment in step (i) is carried out for a time of from 0.1 to 50 hours.
5. The process according to claim 1 , wherein the catalyst is present in homogeneously dissolved form or heterogeneous form.
6. The process according to claim 4 , wherein the catalyst is present in homogeneously dissolved form or heterogeneous form.
7. The process according to claim 1 , wherein the composition (I′) further comprises at least one further oxygen-comprising organic compound in addition to the at least one cyclic ketone.
8. The process according to claim 6 , wherein the composition (I′) further comprises at least one further oxygen-comprising organic compound in addition to the at least one cyclic ketone.
9. A process for preparing cyclododecanone which comprises at least the steps
(a) preparing of a composition (I′) comprising at least cyclododecanone, comprising at least the steps
(a-1) trimerization of a butadiene to form a cyclododecatriene,
(a-2) oxidating the cyclododecatriene to form a cyclododecadienone,
(a-3) hydrogenating the cyclododecadienone to form the cyclododecanone,
(b) purifying the composition (I′), which comprises at least the steps
(i) thermal treating of the composition (I′) with at least one catalyst comprising at least one transition metal,
(ii) further purifying by means of a process selected from the group consisting of distillation, extraction and crystallization
wherein the treating in step (i) is carried out at a temperature of from 60 to 350° C. and for a time of from 0.1 to 50 hours.
10. A process for preparing cyclododecanone which comprises at least the steps
(a) preparation of a composition (I′) comprising at least cyclododecanone, comprising at least the steps
(a-1) trimerization of a butadiene to form a cyclododecatriene,
(a-2) oxidating the cyclododecatriene to form a cyclododecadienone,
(a-3) hydrogenating the cyclododecadienone to form the cyclododecanone,
(b) purifying the composition (I′), which comprises at least the steps
(i) thermal treating the composition (I′) with at least one catalyst comprising at least one transition metal,
(ii) further purifying by means of a process selected from the group consisting of distillation, extraction and crystallization,
wherein the treating in step (i) is carried out at a temperature of from 60 to 350° C. and for a time of from 0.1 to 50 hours, and
wherein the composition (I′) comprises at least one further oxygen-comprising organic compound in addition to the at least one cyclic ketone.
11. The process as claimed in claim 1 , wherein the process in step (b)(ii) is crystallization or extraction.
12. The process as claimed in claim 1 , wherein the process in step (b)(ii) is crystallization.
13. The process as claimed in claim 1 , wherein the process in step (b)(ii) is extraction.
14. The process as claimed in claim 1 , wherein the process in step (b)(ii) is distillation.
15. The process as claimed in claim 10 , wherein the process in step (b)(ii) is crystallization or extraction.
16. The process as claimed in claim 10 , wherein the process in step (b)(ii) is crystallization.
17. The process as claimed in claim 10 , wherein the process in step (b)(ii) is extraction.
18. The process as claimed in claim 10 , wherein the process in step (b)(ii) is distillation.