Process for the instantaneous control of precipitation of nickel and cobalt present in the leach liquor, by adjusting the pH of the solution
View Patent ↗The present invention concerns a process for the instantaneous control of the precipitation of nickel and cobalt present in a leach liquor by adjustment of the pH-value. Said leach liquor is obtained by pressurized acidic leaching of laterite ores and additionally contains aluminium, ferric and ferrous iron and chromium among others. The process comprises the following steps: precipitation of aluminium, ferric and ferrous iron, chromium etc. by increasing the pH-value by adding a suitable reagent such as lime and/or limestone, following precipitation of nickel and cobalt by further increasing the pH-value of the liquor, finally separating the precipitate from the low-content nickel and cobalt solution. The nickel and cobalt precipitate can be used for further refinement. In order to keep the process conditions constant, the steps of increasing the pH-value are controlled simultaneously.
1. A process for the instantaneous control of the precipitation of Ni and Co present in a leach liquor resulting from the pressure acid leaching of laterite ores using pH adjustments to the solution, comprising:
a. precipitating Al, ferric Fe, and Cr while minimizing the precipitation of Ni, Co, and Mn by making additions of lime and/or limestone to the solution while controlling the pH in the solution within a first pre-determined range;
b. precipitating ferrous Fe while minimizing the precipitation of Ni, Co, and Mn by making additions of lime and/or limestone to the solution while controlling the pH in the solution within a second pre-determined range;
c. separating the precipitated Al, ferric and ferrous Fe, and Cr from the solution; and
d. precipitating Ni and Co by making additions of magnesia to the solution while controlling the pH of the solution within a third predetermined range, wherein the procedure for precipitating Ni and Co from the solution comprises the steps of:
i. adding solid calcined magnesia to the solution while measuring the pH of the solution;
ii. adding the magnesia in a controlled manner such that the pH of the solution is maintained between 7.0 and 8.0;
iii. carrying out the precipitation over a period of time covering approximately three hours at a temperature of approximately 50° C.;
iv. separating the precipitated product from the solution using equipment designed for that purpose;
v. washing the precipitated material, thereby reducing or even eliminating the impregnated magnesium sulfate present therein; and
vi. treating the filtered and washed product at refineries designed for the recovery of the contained Ni and Co.
2. A process for the instantaneous control of the precipitation of Ni and Co present in a leach liquor resulting from the pressure acid leaching of laterite ores using pH adjustments to the solution according to claim 1 , in that the pH adjustments are carried out in one or more steps.