CONDUCTING PLATES FOR FUEL CELL ELEMENTS
The present invention relates to the use of the A286 alloy grade for the manufacture of a sheet, optionally surfaced, making it possible to obtain a conducting plate of mono polar or bipolar type for a fuel cell element. The invention also relates to this optional surface treatment process, which comprises a cold-rolling step followed by a continuous annealing step in an oxidizing atmosphere and by an acid pickling step.
1 - 17 . (canceled)
18 . A method for manufacturing a monopolar or bipolar conducting plate for a fuel cell element, comprising the step of providing at least one alloy having, in percentages by weight:
24.0 to 27.0% nickel;
13.5 to 16.0% chromium;
1.90 to 2.35% titanium;
1.0 to 1.5% molybdenum;
0.10 to 0.50% vanadium;
at most 0.08% carbon;
at most 2.0% manganese;
at most 1.0% silicon;
at most 0.35% aluminium;
at most 0.03% sulphur; and
at most 0.01% boron,
the balance consisting of iron and impurities.
19 . The method of claim 18 , wherein the alloy contains:
24.0 to 25.5% nickel;
14.0 to 16.0% chromium;
2.00 to 2.30% titanium;
1.2 to 1.5% molybdenum;
0.10 to 0.50% vanadium;
at most 0.06% carbon;
at most 2.0% manganese;
at most 0.3% silicon;
at most 0.25% aluminium;
at most 0.01% sulphur; and
at most 0.01% boron, the balance consisting of iron and impurities.
20 . A sheet comprising at least one alloy as defined in claim 18 , wherein said sheet has, at least on one of its faces, an arithmetic mean roughness Sa of 0.12 μm or higher, a maximum height amplitude St of less than 4 μm and, preferably, a developed surface area Sdr of greater than 0.2%.
21 . A process for surfacing a sheet based on an alloy as defined in claim 18 , comprising the following steps in succession:
(a) a semi-finished product chosen from a thin slab or a hot-rolled sheet is cold rolled;
(b) the sheet obtained in step (a) is continuously annealed, at a temperature between 900 and 1200° C. for a time ranging from 10 seconds to 30 minutes, in an oxidizing atmosphere; and
(c) the annealed sheet obtained from step (b) is pickled by bringing it into contact with at least one mineral acid at a temperature of between 40 and 100° C.
22 . The process of claim 21 , which further includes an electrolytic pickling step.
23 . The process of claim 21 , which further includes a step of rinsing, preferably with water, and then of drying the pickled sheet.
24 . A sheet obtainable by the process according to claim 21 .
25 . A process for manufacturing a conducting plate for a fuel cell element, comprising providing the sheet of claim 24 .
26 . A process for manufacturing a conducting plate for a fuel cell element, which comprises the surfacing of a sheet containing at least one alloy, having, in percentages by weight,
24. 0 to 27.0% nickel,
13.5 to 16.0% chromium,
1.90 to 2.35% titanium,
1.0 to 1.5% molybdenum,
0.10 to 0.50% vanadium,
at most 0.08% carbon,
at most 2.0% manganese,
at most 1.0% silicon,
at most 0.35% aluminium,
at most 0.03% sulphur,and
at most 0.01% boron,
the balance consisting of iron and impurities, according to the process defined in claim 21 , wherein the manufacturing process further includes at least the following steps:
said sheet having a thickness of 0.05 to 0.5 mm, in particular 0.1 to 0.2 mm, undergoes a first deformation by means of a first tool in order to obtain a corrugated blank; and
said corrugated blank undergoes a second, tangential deformation by means of a second tool.
27 . The process of claim 26 , wherein the succession of first and second deformations gives the sheet an elongation of at least 25% to 35% relative to the initial length of the sheet.
28 . The process of claim 26 , wherein said sheet has, at least on one of its faces, an arithmetic mean roughness Sa of 0.12 μm or higher, a maximum height amplitude St of less than 4 μm and, preferably, a developed surface area Sdr of greater than 0.2%.
29 . A conducting plate for a fuel cell element, which can be obtained by the process according to claim 26 .
30 . A fuel cell element comprising at least one monopolar or bipolar conducting plate comprising at least one alloy as defined in claim 18 .
31 . A fuel cell element comprising at least one monopolar or bipolar conducting plate comprising a sheet according to claim 20 .
32 . A fuel cell element comprising at least one monopolar or bipolar conducting plate according to claim 29 .
33 . A fuel cell, in particular of the PEMFC (photon exchange membrane fuel cell) type, containing the cell element according to claim 30 .
34 . A method for supplying electricity to a vehicle, such as a motor vehicle, or a telecommunication means, such as a relay antenna or a mobile telephone, comprising providing a fuel cell according to claim 33 .