Method for obtaining high-tenacity aramid yarn
The invention relates to a method for obtaining high-tenacity aramid yarn, wherein the yarn is made of a copolymer obtained from a mixture of monomers comprising DAPBI, an aromatic para-diamine, and an aromatic para-diacid, wherein the yarn is heated in at least two process steps, characterized in that in a first step the yarn is heated at a temperature of 200 to 360° C. at a tension of at least 0.2 cN/dtex, followed by a second step wherein the yarn is heated at a temperature of 370 to 500° C. at a tension of less than 1 cN/dtex. The invention further pertains to a multifilament aramid yarn spun from a sulfuric acid spin dope and having a tenacity of at least 2500 mN/tex.
1. A method for obtaining high-tenacity aramid yarn, wherein the yarn has a tenacity of at least 2750 mN/tex and is made of a copolymer obtained from a mixture of monomers comprising at least 12.5 mole% DAPBI, an aromatic para-diamine, and an aromatic para-diacid, and the yarn is heated in at least two process steps, the process steps comprising:
a first step where the yarn is heated at a temperature of 200to 360° C. at a tension of at least 0.2cN/dtex, followed by a second step where the yarn is heated at a temperature of 370to 500° C. at a tension of less than 1 cN/dtex, wherein the tension in the first process step is higher than in the second process step.
2. The method according to claim 1 , wherein the yarn after the first process step is directly led to a heating device for performing the second process step without winding and unwinding the yarn between the two process steps.
3. The method according to claim 1 , wherein the yarn is as-spun yarn.
4. The method according to claim 1 , wherein the yarn is spun from a sulfuric acid spin dope.
5. The method according to claim 1 , wherein the first process step is performed at 240to 330 ° C. at a tension of at least 1 cN/dtex.
6. The method according to claim 1 , wherein the second process step is performed at 400to 470 ° C. at a tension less than 0.5 cN/dtex.
7. The method according to claim 1 , wherein the heating residence times of the two process steps are at least 10 seconds.
8. The method according to claim 7 , wherein the copolymer is obtained from a mixture of monomers further comprising TDC and/or CI-TDC, and PPD and/or Cl-PPD.
9. The method according to claim 1 , wherein the first process step is performed at a tension of at least 3 cN/dtex.
10. The method according to claim 1 , wherein the second process step is performed at a tension of less than 0.2 cN/dtex.