Cosmetics containing a multi-functional composite powder
This invention provides cosmetics containing a multi-functional composite powder having the properties of (a) an excellent adhesiveness, (b) an excellent extendability, (c) an appropriate glossy effect, (d) a homogeneous cosmetic film, (e) an appropriate covering capability, (f) a cosmetic film not causing a white masking, (g) a high compatibility between a color appearance of cosmetics and a color tone of the cosmetic film, (h) an excellent soft-focusing capability, (i) an excellent ultraviolet protective effect, and the like. The multi-functional composite powder is constituted by a scale-like base material, a group of particles comprising at least fine particles of titanium dioxide deposited on a surface of the scale-like base material, and a thin film of a composite oxide containing titanium and iron coated thereon.
1. A cosmetic composition containing a multi-functional composite powder wherein the multifunctional composite powder is constituted by:
(i) a scale-like base material,
(ii) a group of particles disposed on and covering only a part of a surface of the scale-like base material, the group of particles comprising at least particles of titanium dioxide having an average particle diameter of from 0.1 to 0.4 μm, and
(iii) a thin film of a composite oxide of titanium and iron on and coating a part of the surface of the scale-like base material, wherein
the thin film of the composite oxide of titanium and iron coats the part of the surface of the scale-like base material that is not covered by the group of particles,
the thin film has a thickness smaller than the average diameter of the particles of the group of particles, and
the particles of the group of particles are not completely covered by the thin film so that visible light incident on the particles is scattered.
2. The cosmetic composition according to claim 1 , wherein the group of particles further includes particles of ferric oxide in an amount from 0.01 to 10.0% by weight of the group of particles, the particles of ferric oxide having an average particle diameter of from 0.1 to 1.0 μm.
3. The cosmetic composition according to claim 1 , wherein the particles of titanium dioxide have a white color and are a color pigment.
4. The cosmetic composition according to claim 2 , wherein the particles of ferric oxide have a red-brown color and are a color pigment.
5. The cosmetic composition according to claim 1 , wherein the particles of titanium dioxide have been subjected to a surface treatment with oxides, hydroxides, and/or hydrous oxides of one or more metal elements selected from the group consisting of silicon, aluminum, zinc, and iron.
6. The cosmetic composition according to claim 1 , wherein the particles of titanium dioxide disposed on part of the surface of the scale-like base material are present in an amount from 5 to 30% by weight of the multi-functional composite powder.
7. The cosmetic composition according to claim 1 , wherein the thin film of the composite oxide is present in an amount from 10 to 30% by weight of the multi-functional composite powder.
8. The cosmetic composition according to claim 1 , wherein the composite oxide of titanium and iron contains titanium and iron in a weight ratio (Fe 2 O 3 /TiO 2 ) in a range from 0.01 to 0.3, when the titanium is represented as TiO 2 and the iron is represented as Fe 2 O 3 .
9. The cosmetic composition according to claim 1 , wherein the multi-functional composite powder is present in an amount from 5 to 60% by weight of the cosmetic composition.
10. The cosmetic composition according to claim 1 , wherein the cosmetic composition does not contain particles of titanium dioxide as a pigment other than in the multi-functional composite powder.
11. The cosmetic composition according to claim 1 , wherein the cosmetic composition is a make-up cosmetic composition.
12. The cosmetic composition according to claim 2 , wherein the particles of ferric oxide have been subjected to a surface treatment with oxides, hydroxides, and/or hydrous oxides of one or more metal elements selected from the group consisting of silicon, aluminum, zinc, and iron.
13. The cosmetic composition according to claim 1 , wherein the composite oxide of titanium and iron coating the part of the surface of the scale-like base member not covered by the particles has the formula