IP Library Granted Patent US 9,666,815
Granted Patent B2
US 9,666,815 · App. 12/334,370 · Granted May 30, 2017

Surface treatment of hydrophobic ferroelectric polymers for printing

Inventors: Tse Nga Ng (Palo Alto, CA); Ana Claudia Arias (Los Gatos, CA); Jurgen H. Daniel (San Francisco, CA)
Assignee: PALO ALTO RESEARCH CENTER INCORPORATED
H01L51/052H01L51/0005H01L51/0022H05K3/125H05K3/1208H01L27/1292H01L51/0036H01L51/0043H01L51/0545H05K3/381H05K2203/013H05K2203/087H05K2203/095H05K2203/1173
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Quick Facts
Patent No.
US 9,666,815
App. No.
12/334,370
Granted
May 30, 2017
Kind
B2
Abstract

An embodiment is a method and apparatus to treat surface of polymer for printing. Surface of a polymer having a surface energy modified for a time period to control a feature characteristic and/or provide a hysteresis behavior. A material is printed on the surface to form a circuit pattern having at least one of the controlled feature characteristic and the hysteresis behavior.

Claims (15)

1. An apparatus comprising:

a dielectric layer made of a polymer having a surface with modified surface energy, the modified surface energy controlling a feature characteristic and/or providing a hysteresis behavior, the dielectric layer including a surface and a portion below the surface, the surface of the dielectric layer being made of the surface with the modified surface energy of the polymer and the portion below the surface of the dielectric layer being made of the polymer, the surface of the dielectric layer being either (i) more hydrophobic or (ii) less hydrophobic than the portion below the surface of the dielectric layer; and

a circuit pattern printed on the surface, the circuit pattern having at least one of the controlled feature characteristic and the hysteresis behavior.

2. The apparatus of claim 1 wherein the feature characteristic includes at least one of a feature size, a feature uniformity, a contact angle, and a line width.

3. The apparatus of claim 1 wherein the polymer is a hydrophobic polymer or a ferroelectric material.

4. The apparatus of claim 3 wherein the ferroelectric material is a Poly (Vinylidene Fluoride) (PVDF) co-polymer.

5. The apparatus of claim 1 wherein the circuit pattern comprises:

a conductor or a semiconductor, including metal nanoparticles, or a polymeric ink pattern.

6. The apparatus of claim 1 wherein the circuit pattern comprises:

a circuit including at least one of an active element and a passive element.

7. The apparatus of claim 6 wherein the circuit comprises:

a non-volatile memory cell.

8. The apparatus of claim 1 wherein the circuit pattern comprises one of:

a conductive trace, a capacitor electrode, a via hole interconnect, and a contact.

9. The apparatus of claim 8 , wherein the conductive trace has a uniform width and low resistance.

Assignments (11)
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
CONFIRMATORY LICENSE Recorded Mar 18, 2016
From: PALO ALTO RESEARCH CENTER, INC.
To: US ARMY, SECRETARY OF THE ARMY
Reel/Frame 038174/0957 →
CONFIRMATORY LICENSE Recorded Apr 21, 2010
From: PALO ALTO RESEARCH CENTER, INCORPORATED
To: US ARMY, SECRETARY OF THE ARMY
Reel/Frame 024264/0022 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 12, 2008
From: NG, TSE NGA; ARIAS, ANA CLAUDIA; DANIEL, JURGEN H.
To: PALO ALTO RESEARCH CENTER INCORPORATED
Reel/Frame 021974/0108 →
Continuity (1)
Related Publication 20100148232A1 · Jun 17, 2010