Methods and apparatus for catalytic hydrothermal gasification of biomass
Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.
1. A catalytic hydrothermal process characterized by:
heating under pressure a wet biomass feedstock to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, and for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, the temperature and pressure less than the critical temperature and pressure of water;
separating the precipitates out of the wet feedstock, removing sulfur contaminants from the wet biomass feedstock, at a temperature and pressure less than the critical temperature and pressure of water; and
exposing the wet biomass feedstock to a heterogeneous metal catalyst and gasifying at least a portion of the organic constituents after said separating, said exposing occurs at temperatures and pressures below the critical point of water;
wherein the process is operated in continuous mode and wherein water in the feedstock is in a liquid phase during said heating, separating, and exposing steps.
2. The process of claim 1 , wherein the heating comprises heating the wet biomass feedstock to at least 300° C.
3. The process of claim 1 , wherein the separating the precipitates comprises an operation selected from the group consisting of gravity separation, hydrocyclonic separation, filtration, or combinations thereof.
4. The process of claim 1 , wherein the heterogeneous metal catalyst comprises Ru, Ni, or Ni with added Na.
5. The process of claim 1 , wherein the heterogeneous catalyst comprises Ru on a carbon support.
6. The process of claim 1 , wherein the removing sulfur contaminants comprises capturing sulfur contaminants in an adsorbent bed by reaction with a metal or a metal oxide.
7. The process of claim 1 , wherein the wet feedstock is selected from the group consisting of high-moisture biomass slurries, biosludge from wastewater treatment systems, sewage sludge from municipal treatment systems, wet byproducts from biorefinery operations, wet byproducts/residues from food processing, animal waste and waste from centralized animal raising facilities, organic chemical manufacturing wastewater streams, industrial wastewater contaminated with organics, and combinations thereof.
8. The process of claim 1 , wherein the exposing occurs at 340-360° C. and 18-21 MPa.
9. The process of claim 1 , wherein said gasifying of the organic constituents yields a hydrogen-containing feedstock for catalytic reformation.
10. A catalytic hydrothermal process characterized by:
heating under pressure a wet biomass feedstock to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, and for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants;
separating the precipitates out of the wet feedstock, removing sulfur contaminants from the wet biomass feedstock; and
exposing the wet biomass feedstock to a heterogeneous metal catalyst and gasifying at least a portion of the organic constituents after said separating, said exposing occurs at temperatures and pressures below the critical point of water;
wherein the process is operated in continuous mode and wherein water in the feedstock is in a liquid phase at a temperature less than or equal to 360° C. during said heating, separating, and exposing steps.