CONVERSION OF METHANE INTO C3˜C13 HYDROCARBONS
A process for converting methane into C 3 ˜C 13 hydrocarbons is provided including the steps of reacting methane with oxygen and HBr/H 2 O over a first catalyst in a first reactor to methane bromides and converting the methane bromides into C 3 ˜C 13 hydrocarbons and HBr over a second catalyst in a second reactor. The process may further include recovering HBr produced in the second reactor and recylcing it into the first reactor.
1 . A process for converting methane into higher hydrocarbons comprising the steps of:
(a) contacting methane with a source of oxygen and hydrogen bromide to form one or more methane bromide compounds, in the presence of a first catalyst within a first reactor;
(b) converting the methane bromides into C 3 ˜C 13 hydrocarbons and hydrogen bromide in the presence of a second catalyst within a second reactor.
2 . The process of claim 1 , further comprises the step of (c) recovering the hydrogen bromide produced in step (b) and recycling the recovered hydrogen bromide into step (a).
3 . The process according to claim 1 , wherein the first catalyst comprises at least one of metal, metal halides and metal oxides supported on silicon dioxide, wherein said metal is selected from the group consisting of Ru, Rh, Pd, Ir, Pt, Mg, Ca, Ba, Y, La, Sm, Bi, Fe, Co, Ni, Cu, V and Mo.
4 . The process according to claim 3 , wherein the first catalyst comprises at least one of metal and metal chlorides supported on silicon dioxide, wherein said metal is selected from the group consisting of Ru, Rh, Pd, Ir and Pt.
5 . The process according to claim 3 , wherein the first catalyst comprises at least one metal oxide supported on silicon dioxide, wherein said metal is selected from the group consisting of Mg, Ca, Ba, Y, La, Sm, Bi, Fe, Co, Ni, Cu, V and Mo.
6 . The process according to claim 3 , wherein the first catalyst is prepared from a first catalyst precursor, wherein said first catalyst precursor comprises silicon dioxide, at least one halide of one or more metals selected from the group of Ru, Rh, Pd, Ir and Pt, and/or at least one of nitrates, sulphates, halides, carbonates, oxalates or acetates of one or more metals selected from the group consisting of Mg, Ca, Ba, Y, La, Sm, Bi, Fe, Co, Ni, Cu, V and Mo.
7 . The process according to claim 6 , wherein the first catalyst precursor comprises silicon dioxide, RuCl 3 , and at least one nitrate of one or more metals selected from the group consisting of Mg, Ca, Ba, Y, La, Sm, Bi, Fe, Co, Ni, Cu, V and Mo.
8 . The process according to claim 1 , wherein step (a) is carried out at a temperature between about 400° C. and about 800° C.
9 . The process according to claim 1 , wherein the step (a) is carried out at a pressure between about 0.5 atm and about 10.0 atm.
10 . The process of claim 1 , wherein the second catalyst comprises at least one metal oxide supported on HZSM-5, wherein said metal is selected from the group consisting of Zn, Mg, Co, Cr, Cu, Ca, Fe, Ag, Pb, Bi, Ce, Sr, La, Y, Mn, Nb, Ti and mixtures thereof.
11 . The process according to claim 1 , wherein the second catalyst is prepared from a second catalyst precursor, wherein said second catalyst precursor comprises HZSM-5, and at least one of nitrates, sulphates, halides, carbonates, oxalates and acetates of one or more metals selected from the group consisting of Zn, Mg, Co, Cr, Cu, Ca, Fe, Ag, Pb, Bi, Ce, Sr, La, Y, Mn, Nb and Ti.
12 . The process according to claim 11 , wherein the second catalyst precursor comprises HZSM-5, and at least one nitrate of one or more metals selected from the group consisting of Zn, Mg, Cr, Ca, Fe, Ag, Pb, Bi, Ce, Sr, La and Y, and/or at least one of chlorides of metal selected from the group consisting of Co, Cu, Mn, Nb and Ti.
13 . The process according to claim 1 , wherein the step (b) is carried out at a temperature between about 150° C. and about 500° C.
14 . The process according to claim 1 , wherein the step (b) is carried out at a pressure between about 0.5 atm and about 50.0 atm.