Carbon nanotube patterning on a metal substrate
View Patent ↗A CNT electron source, a method of manufacturing a CNT electron source, and a solar cell utilizing a CNT patterned sculptured substrate are disclosed. Embodiments utilize a metal substrate which enables CNTs to be grown directly from the substrate. An inhibitor may be applied to the metal substrate to inhibit growth of CNTs from the metal substrate. The inhibitor may be precisely applied to the metal substrate in any pattern, thereby enabling the positioning of the CNT groupings to be more precisely controlled. The surface roughness of the metal substrate may be varied to control the density of the CNTs within each CNT grouping. Further, an absorber layer and an acceptor layer may be applied to the CNT electron source to form a solar cell, where a voltage potential may be generated between the acceptor layer and the metal substrate in response to sunlight exposure.
1. A method of manufacturing an electron source, said method comprising:
applying an inhibitor to a first plurality of regions of a metal substrate, wherein said inhibitor is operable to inhibit growth of carbon nanotubes in said first plurality of regions of said metal substrate; and
growing carbon nanotubes on said metal substrate in a second plurality of regions separate from said first plurality of regions; wherein said applying an inhibitor further comprises:
applying photoresist to said metal substrate;
exposing a portion of said photoresist to ultraviolet light using a photolithography process, wherein said portion of said photoresist is disposed on said second plurality of regions;
removing unexposed portions of said photoresist disposed on said first plurality of regions of said metal substrate;
applying said inhibitor to said metal substrate and said portion of said photoresist; and
removing said portion of said photoresist and leaving said inhibitor disposed on said first plurality of regions of said metal substrate.
2. The method of claim 1 , wherein said metal substrate comprises a material selected from the group consisting of a metal operable to grow carbon nanotubes and a metal alloy operable to grow carbon nanotubes.
3. The method of claim 1 , wherein said inhibitor comprises a material selected from a group consisting of a non-metal, a polymer, and a metal operable to inhibit the growth of carbon nanotubes.
4. The method of claim 1 , wherein said inhibitor comprises a polymer, and wherein said applying an inhibitor further comprises:
applying a polymer to said metal substrate;
patterning said polymer using a patterned stamp, wherein said patterned stamp comprises features corresponding to said first plurality of regions; and
curing said polymer while said patterned stamp is in place.
5. The method of claim 1 , wherein said applying said inhibitor further comprises applying said inhibitor using a bubble jet printing process.
6. The method of claim 1 further comprising:
disposing an absorber layer on said inhibitor and said carbon nanotubes; and
disposing an acceptor layer on said absorber layer.
7. The method of claim 6 , wherein said disposing said absorber layer and said acceptor layer are performed using a process selected from sputtering and chemical vapor deposition.
8. The method of claim 1 further comprising:
polishing said metal substrate prior to applying said inhibitor, said polishing generating an RMS surface roughness of less than approximately 5 nanometers.
9. The method of claim 6 , further comprising exposing said acceptor layer to a light source in which a voltage potential with respect to said substrate is generated.
10. A method of creating an electron source on a metal substrate, said method comprising:
applying a photoresist to the metal substrate;
selectively exposing portions of the photoresist to a light source thereby forming exposed photoresist portions and unexposed photoresist portions;
removing the unexposed photoresist portions from the metal substrate;
applying a carbon nanotube growth inhibitor to the exposed photoresist portions and metal substrate;
removing the exposed photoresist portions from the metal substrate; and
growing carbon nanotubes on portions of the metal substrate where the carbon nanotube growth inhibitor is not applied.
11. The method of claim 10 , in which the metal substrate comprises a material selected from a group consisting of a metal operable to grow carbon nanotubes and a metal alloy operable to grow carbon nanotubes.
12. The method of claim 10 , in which the inhibitor comprises a material selected from a group consisting of a non-metal, a polymer, and a metal operable to inhibit the growth of carbon nanotubes.
13. The method of claim 10 , further comprising:
disposing an absorber layer on the carbon nanotube growth inhibitor and carbon nanotubes; and
disposing an acceptor layer on said absorber layer.
14. The method of claim 13 , further comprising exposing said acceptor layer to a light source in which a voltage potential with respect to said substrate is generated.