Systems and methods for removing finely dispersed particulate matter from a fluid stream
Disclosed herein are systems for removing particulate matter from a fluid, comprising a particle functionalized by attachment of at least one activating group or amine functional group, wherein the modified particle complexes with the particulate matter within the fluid to form a removable complex therein. The particulate matter has preferably been contacted, complexed or reacted with a tethering agent. The system is particularly advantageous to removing particulate matter from a tailing solution.
1. A method of removing particulate matter from a fluid, comprising:
providing an activating material capable of being affixed to the particulate matter wherein the activating material is an anionic polymer;
affixing the activating material to the particulate matter to form an activated particle;
providing anchor particles and providing a tethering material capable of being affixed to the anchor particles, wherein the tethering material is a cationic polymer and the anchor particles larger than the particulate matter;
and adding the tether-bearing anchor particle to the fluid that comprises the activated particle, wherein the tethering material attaches to the activated particle to form a removable complex in the fluid that comprises the particulate matter; and
removing the removable complex from the fluid, thereby removing the particulate matter from the fluid.
2. The method of claim 1 , wherein the removable complex is removed by filtration.
3. The method of claim 1 , wherein the removable complex is removed by centrifugation.
4. The method of claim 1 , wherein the removable complex is removed by gravitational settling.
5. The method of claim 1 , wherein the anchor particle comprises sand indigenous to the geographical area of the method.
6. The method of claim 1 , wherein the tethering material is selected from the group consisting of polyvinylamine, branched polyethylenimine and polydiallyldimethyl ammonium chloride.
7. The method of claim 1 , wherein the particulate matter comprises quartz and/or clay fines.
8. The method of claim 1 , wherein the particles comprise oil sands.
9. The method of claim 1 , wherein the complex is mechanically stable.
10. The method of claim 1 , further comprising the step of constructing a road or dyke with the complex.
11. The method of claim 1 , further comprising the step of reclaiming land with the complex.
12. A method of removing particulate matter from a fluid, comprising
adding an anionic polymer to the fluid, thereby coating the particulate matter with the polymer;
providing modified particles comprising particles functionalized by attachment of at least one amine functional group wherein the particles larger than the particulate matter adding the modified particles to the fluid; and,
dispersing the modified particles within the fluid so that they contact the coated particulate matter to form removable complexes in the fluid, and
removing the removable complexes from the fluid.
13. The method of claim 12 , wherein the removable complexes are removed by filtration.
14. The method of claim 12 , wherein the removable complexes are removed by centrifugation.
15. The method of claim 12 , wherein the removable complexes are removed by gravitational settling.
16. The method of claim 12 , wherein the removable complexes are removed by skimming.
17. The method of claim 12 , wherein the fluid is a tailing solution.
18. The method of claim 17 wherein the particulate matter comprises quartz and/or clay fines.
19. The method of claim 12 , wherein the particles comprise oil sands.
20. The method of claim 12 , wherein the complex is mechanically stable.
21. The method of claim 12 , further comprising the step of constructing a road or dyke with the complex.
22. The method of claim 12 , further comprising the step of reclaiming land with the complex.