Nonaqueous-electrolyte battery and battery assembly
A nonaqueous-electrolyte battery has a positive electrode 3 including a positive active material, a negative electrode 4 including a negative active material having a lithium insertion/release potential higher than 1.0 V (vs. Li/Li + ), and a nonaqueous electrolyte, wherein the nonaqueous electrolyte contains a compound having pyridine groups and a compound having one or more silyl groups.
1. A nonaqueous-electrolyte battery, comprising:
a case,
a positive electrode held in the case,
a negative electrode held in the case and comprising a negative active material which undergoes lithium insertion/release at a potential higher than 1.0 V, and
a nonaqueous electrolyte packed in the case, wherein the nonaqueous electrolyte comprises a nonaqueous solvent and an electrolyte material dissolved in the nonaqueous solvent, wherein the nonaqueous solvent comprises at least one compound (a) selected from the group consisting of poly(2-vinylpyridine) and poly(4-vinylpyridine) and
at least one compound compound (b) is at least one compound selected from the group consisting of tris(trimethylsilyl)phosphate, bis(trimethylsilyl)methyl phosphate, dimethyl trimethylsilyl phosphate and a phosphate comprising at least one functional group represented by the formula (3):
wherein R1 to R3 each independently represent an alkyl group having 1-10 carbon atoms, an alkenyl group having 2-10 carbon atoms, or an aryl group having 6-10 carbon atoms,
wherein a content of the at least one compound (a) is from 0.01% to 3% by weight based on the total weight of the nonaqueous electrolyte, and
wherein a content of the at least one compound (b) is from 0.1% to 20% by weight based on the total weight of the nonaqueous electrolyte.
2. The battery of claim 1 , wherein the negative active material is a lithium-titanium composite oxide.
3. The battery of claim 2 , wherein the lithium-titanium composite oxide has a spinel structure.
4. The battery of claim 1 , wherein the nonaqueous solvent further comprises a solvent prepared by mixing two or more members selected from the group consisting of propylene carbonate, ethylene carbonate, and γ-butyrolactone.
5. The battery of claim 1 , wherein the nonaqueous solvent further comprises γ-butyrolactone.
6. The battery of claim 1 , wherein the positive electrode comprises a lithium-transition metal composite oxide containing manganese.
7. The battery of claim 1 , wherein the positive electrode comprises a lithium-transition metal composite oxide and has an oxide of at least one element selected from the group consisting of Al, Mg, Zr, B, Ti, and Ga on part of the surface of the composite oxide.
8. A battery assembly comprising nonaqueous-electrolyte batteries connected together in an electrically serial or parallel arrangement, wherein each of the nonaqueous-electrolyte batteries is the battery of claim 1 .
9. The assembly of claim 8 , which is equipped with a protective circuit capable of detecting the voltage of each battery.
10. The battery of claim 1 , wherein the content of the at least one compound (a) is from 0.01% to 1% by weight based on the total weight of the nonaqueous electrolyte.
11. The battery of claim 1 , wherein the content of the at least one compound (a) is from 0.03% to 1% by weight based on the total weight of the nonaqueous electrolyte.
12. The battery of claim 1 , wherein the content of the at least one compound (b) is from 0.01% to 10% by weight based on the total weight of the nonaqueous electrolyte.
13. The battery of claim 1 , wherein the content of the at least one compound (b) is from 0.5% to 5% by weight based on the total weight of the nonaqueous electrolyte.